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Highly efficient synthesis of dimethyl ether directly from biomass-derived gas over Li-modified Cu-ZnO-Al2O3/HZSM-5 hybrid catalyst

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  • Zuo, Hongmei
  • Mao, Dongsen
  • Guo, Xiaoming
  • Yu, Jun

Abstract

A series of CuO-ZnO-Al2O3-Li2O catalysts with various Al2O3/Li2O mass ratios were prepared by co-precipitation method and characterized by several techniques such as XRD, N2 adsorption, SEM/EDX, reactive N2O adsorption, XPS/XAES, H2-TPR, H2-TPD, and CO-TPD. The results revealed that the specific surface area (SBET), dispersity of Cu species, metallic Cu surface area (SCu) and adsorption capacity for reactants (H2 and CO) were increased by the addition of suitable amount of Li2O to the CuO-ZnO-Al2O3 catalyst, thus enhancing the catalytic activity of the hybrid catalyst composed of CuO-ZnO-Al2O3 and HZSM-5 for the direct synthesis of dimethyl ether from biomass-derived gas. Furthermore, the addition of Li2O significantly improved the stability of CuO-ZnO-Al2O3 catalyst due to the effective inhibition of the crystallization of Cu and ZnO.

Suggested Citation

  • Zuo, Hongmei & Mao, Dongsen & Guo, Xiaoming & Yu, Jun, 2018. "Highly efficient synthesis of dimethyl ether directly from biomass-derived gas over Li-modified Cu-ZnO-Al2O3/HZSM-5 hybrid catalyst," Renewable Energy, Elsevier, vol. 116(PA), pages 38-47.
    • Handle: RePEc:eee:renene:v:116:y:2018:i:pa:p:38-47
    DOI: 10.1016/j.renene.2017.09.041
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    References listed on IDEAS

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    1. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
    2. Li, Yuping & Wang, Tiejun & Yin, Xiuli & Wu, Chuangzhi & Ma, Longlong & Li, Haibin & Lv, Yongxing & Sun, Li, 2010. "100t/a-Scale demonstration of direct dimethyl ether synthesis from corncob-derived syngas," Renewable Energy, Elsevier, vol. 35(3), pages 583-587.
    3. Chen, Wei-Hsin & Lin, Bo-Jhih & Lee, How-Ming & Huang, Men-Han, 2012. "One-step synthesis of dimethyl ether from the gas mixture containing CO2 with high space velocity," Applied Energy, Elsevier, vol. 98(C), pages 92-101.
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    Cited by:

    1. Joanna Sobczak & Izabela Wysocka & Stanisław Murgrabia & Andrzej Rogala, 2022. "A Review on Deactivation and Regeneration of Catalysts for Dimethyl Ether Synthesis," Energies, MDPI, vol. 15(15), pages 1-39, July.

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