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A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability

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  • Garcia, Gabriel
  • Arriola, Emmanuel
  • Chen, Wei-Hsin
  • De Luna, Mark Daniel

Abstract

Methanol, a liquid hydrogen carrier, can produce high purity hydrogen when required. This review discusses and compares current mainstream production pathways of hydrogen from methanol. Recent research efforts in methanol steam reforming, partial oxidation, autothermal reforming, and methanol decomposition are addressed. Particular attention is paid to catalyst development and reactor technology. Copper-based catalysts are popular due to their high activity and selectivity towards CO2 over CO but are easily deactivated and have low stability. Attempts have been made using different metals like zinc, zirconia, ceria, chromium, and other transition metals. Catalysts with spinel structures can significantly improve activity and performance. Palladium-zinc alloy catalysts also have high selectivity towards H2 and CO2. For reactors, novel structures such as porous copper fiber sintered-felt are prefabricated and pre-coated before employment in microreactors. Monolith structures provide maximum surface area for catalyst coatings and lower pressure drops. Membrane reactors drive reactions forward to produce more H2. Swiss-roll reactors achieve heat recovery and energy saving in reactions. In summary, this comprehensive review of hydrogen production from methanol is conducive to the prospective development of a hydrogen-methanol economy.

Suggested Citation

  • Garcia, Gabriel & Arriola, Emmanuel & Chen, Wei-Hsin & De Luna, Mark Daniel, 2021. "A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability," Energy, Elsevier, vol. 217(C).
    • Handle: RePEc:eee:energy:v:217:y:2021:i:c:s0360544220324919
    DOI: 10.1016/j.energy.2020.119384
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    References listed on IDEAS

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    1. Iulianelli, A. & Ribeirinha, P. & Mendes, A. & Basile, A., 2014. "Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 355-368.
    2. Chen, Wei-Hsin & Shen, Chun-Ting & Lin, Bo-Jhih & Liu, Shih-Chun, 2015. "Hydrogen production from methanol partial oxidation over Pt/Al2O3 catalyst with low Pt content," Energy, Elsevier, vol. 88(C), pages 399-407.
    3. Ouzounidou, Martha & Ipsakis, Dimitris & Voutetakis, Spyros & Papadopoulou, Simira & Seferlis, Panos, 2009. "A combined methanol autothermal steam reforming and PEM fuel cell pilot plant unit: Experimental and simulation studies," Energy, Elsevier, vol. 34(10), pages 1733-1743.
    4. Chen, Wei-Hsin & Shen, Chun-Ting, 2016. "Partial oxidation of methanol over a Pt/Al2O3 catalyst enhanced by sprays," Energy, Elsevier, vol. 106(C), pages 1-12.
    5. Chen, Wei-Hsin & Guo, Yu-Zhi & Chen, Chih-Chun, 2018. "Methanol partial oxidation accompanied by heat recirculation in a Swiss-roll reactor," Applied Energy, Elsevier, vol. 232(C), pages 79-88.
    6. Zakaria, Z. & Kamarudin, S.K., 2016. "Direct conversion technologies of methane to methanol: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 250-261.
    7. Yang, Chi-Jen & Jackson, Robert B., 2012. "China's growing methanol economy and its implications for energy and the environment," Energy Policy, Elsevier, vol. 41(C), pages 878-884.
    8. Chaubey, Rashmi & Sahu, Satanand & James, Olusola O. & Maity, Sudip, 2013. "A review on development of industrial processes and emerging techniques for production of hydrogen from renewable and sustainable sources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 443-462.
    9. Aghbashlo, Mortaza & Tabatabaei, Meisam & Soltanian, Salman & Ghanavati, Hossein, 2019. "Biopower and biofertilizer production from organic municipal solid waste: An exergoenvironmental analysis," Renewable Energy, Elsevier, vol. 143(C), pages 64-76.
    10. Balcombe, Paul & Speirs, Jamie & Johnson, Erin & Martin, Jeanne & Brandon, Nigel & Hawkes, Adam, 2018. "The carbon credentials of hydrogen gas networks and supply chains," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1077-1088.
    11. Wang, Hsueh-Sheng & Huang, Kuo-Yang & Huang, Yuh-Jeen & Su, Yu-Chuan & Tseng, Fan-Gang, 2015. "A low-temperature partial-oxidation-methanol micro reformer with high fuel conversion rate and hydrogen production yield," Applied Energy, Elsevier, vol. 138(C), pages 21-30.
    12. Abdul Ghani, Ahmad & Torabi, Farshid & Ibrahim, Hussameldin, 2018. "Autothermal reforming process for efficient hydrogen production from crude glycerol using nickel supported catalyst: Parametric and statistical analyses," Energy, Elsevier, vol. 144(C), pages 129-145.
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