IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v175y2023ics1364032123000400.html
   My bibliography  Save this article

Steam reforming of ethanol by non-noble metal catalysts

Author

Listed:
  • Deng, Yimin
  • Li, Shuo
  • Appels, Lise
  • Zhang, Huili
  • Sweygers, Nick
  • Baeyens, Jan
  • Dewil, Raf

Abstract

Catalytic steam reforming of ethanol (CSRE) is an attractive mode of producing hydrogen as an environmentally-friendly energy carrier. Ethanol can be produced from first-generation fermenting of cheap carbohydrates (e.g. non-food cassava and agricultural residues), and second-generation fermenting of biomass. The catalytic conversion of ethanol requires an appropriate catalyst, operating temperature, and reaction time. Supported noble metal catalysts were previously used. The present work uses novel non-noble catalysts. The most efficient catalysts were impregnated in α-Al2O3 and fully characterized. The catalytic experiments were conducted between 500 °C and 600 °C in either electrically-heated fixed bed reactors, or in a solar-heated fluidized bed reactor. The main reaction products were H2 (approximately 5.5 mol H2/mol ethanol), CO, CO2 and CH4. Deactivation of the Co/α-Al2O3 catalyst was not observed. Negligible amounts of acetone and acetaldehyde were detected. A maximum hydrogen yield of over 95% was achieved. Pilot-scale investigations were started.

Suggested Citation

  • Deng, Yimin & Li, Shuo & Appels, Lise & Zhang, Huili & Sweygers, Nick & Baeyens, Jan & Dewil, Raf, 2023. "Steam reforming of ethanol by non-noble metal catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    • Handle: RePEc:eee:rensus:v:175:y:2023:i:c:s1364032123000400
    DOI: 10.1016/j.rser.2023.113184
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032123000400
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2023.113184?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Agrafiotis, Christos & von Storch, Henrik & Roeb, Martin & Sattler, Christian, 2014. "Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 656-682.
    2. Shuo Li & Huili Zhang & Jiapei Nie & Raf Dewil & Jan Baeyens & Yimin Deng, 2021. "The Direct Reduction of Iron Ore with Hydrogen," Sustainability, MDPI, vol. 13(16), pages 1-15, August.
    3. Hou, Tengfei & Zhang, Shaoyin & Chen, Yongdong & Wang, Dazhi & Cai, Weijie, 2015. "Hydrogen production from ethanol reforming: Catalysts and reaction mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 132-148.
    4. Sharma, Yogesh Chandra & Kumar, Ashutosh & Prasad, Ram & Upadhyay, Siddh Nath, 2017. "Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 89-103.
    5. Qian Kang & Tianwei Tan, 2016. "Exergy and CO 2 Analyses as Key Tools for the Evaluation of Bio-Ethanol Production," Sustainability, MDPI, vol. 8(1), pages 1-11, January.
    6. Zhang, H.L. & Baeyens, J. & Degrève, J. & Cacères, G., 2013. "Concentrated solar power plants: Review and design methodology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 466-481.
    7. Jia Liu & Shuo Li & Raf Dewil & Maarten Vanierschot & Jan Baeyens & Yimin Deng, 2022. "Water Splitting by MnO x /Na 2 CO 3 Reversible Redox Reactions," Sustainability, MDPI, vol. 14(13), pages 1-15, June.
    8. Li, Shuo & Baeyens, Jan & Dewil, Raf & Appels, Lise & Zhang, Huili & Deng, Yimin, 2021. "Advances in rigid porous high temperature filters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    9. Vincenzo Palma & Concetta Ruocco & Eugenio Meloni & Antonio Ricca, 2017. "Influence of Catalytic Formulation and Operative Conditions on Coke Deposition over CeO 2 -SiO 2 Based Catalysts for Ethanol Reforming," Energies, MDPI, vol. 10(7), pages 1-13, July.
    10. Zhang, Huili & Benoit, Hadrien & Perez-Lopèz, Inmaculada & Flamant, Gilles & Tan, Tianwei & Baeyens, Jan, 2017. "High-efficiency solar power towers using particle suspensions as heat carrier in the receiver and in the thermal energy storage," Renewable Energy, Elsevier, vol. 111(C), pages 438-446.
    11. Deng, Yimin & Dewil, Raf & Appels, Lise & Li, Shuo & Baeyens, Jan & Degrève, Jan & Wang, Guirong, 2021. "Thermo-chemical water splitting: Selection of priority reversible redox reactions by multi-attribute decision making," Renewable Energy, Elsevier, vol. 170(C), pages 800-810.
    12. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cheng, Guishi & Luo, Ercheng & Zhao, Ying & Yang, Yihao & Chen, Binbin & Cai, Youcheng & Wang, Xiaoqiang & Dong, Changqing, 2023. "Analysis and prediction of green hydrogen production potential by photovoltaic-powered water electrolysis using machine learning in China," Energy, Elsevier, vol. 284(C).
    2. Olabi, Valentina & Jouhara, Hussam, 2024. "An assessment of current hydrogen supply chains in the Gulf Cooperation Council (GCC)," Energy, Elsevier, vol. 299(C).
    3. Szostok, Agnieszka & Stanek, Wojciech, 2023. "Thermo-ecological analysis of the power system based on renewable energy sources integrated with energy storage system," Renewable Energy, Elsevier, vol. 216(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hong, Sanghyun & Kim, Eunsung & Jeong, Saerok, 2023. "Evaluating the sustainability of the hydrogen economy using multi-criteria decision-making analysis in Korea," Renewable Energy, Elsevier, vol. 204(C), pages 485-492.
    2. Sun, Xue & Li, Xiaofei & Zeng, Jingxin & Song, Qiang & Yang, Zhen & Duan, Yuanyuan, 2023. "Energy and exergy analysis of a novel solar-hydrogen production system with S–I thermochemical cycle," Energy, Elsevier, vol. 283(C).
    3. Khamlich, Imane & Zeng, Kuo & Flamant, Gilles & Baeyens, Jan & Zou, Chongzhe & Li, Jun & Yang, Xinyi & He, Xiao & Liu, Qingchuan & Yang, Haiping & Yang, Qing & Chen, Hanping, 2021. "Technical and economic assessment of thermal energy storage in concentrated solar power plants within a spot electricity market," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Eugenio Meloni & Marco Martino & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Vincenzo Palma, 2022. "The Route from Green H 2 Production through Bioethanol Reforming to CO 2 Catalytic Conversion: A Review," Energies, MDPI, vol. 15(7), pages 1-36, March.
    5. Zhang, Huili & Kong, Weibin & Tan, Tianwei & Baeyens, Jan, 2017. "High-efficiency concentrated solar power plants need appropriate materials for high-temperature heat capture, conveying and storage," Energy, Elsevier, vol. 139(C), pages 52-64.
    6. Wang, Yishuang & Liang, Defang & Wang, Chunsheng & Chen, Mingqiang & Tang, Zhiyuan & Hu, Jiaxin & Yang, Zhonglian & Zhang, Han & Wang, Jun & Liu, Shaomin, 2020. "Influence of calcination temperature of Ni/Attapulgite on hydrogen production by steam reforming ethanol," Renewable Energy, Elsevier, vol. 160(C), pages 597-611.
    7. Reyes-Belmonte, M.A. & Sebastián, A. & Spelling, J. & Romero, M. & González-Aguilar, J., 2019. "Annual performance of subcritical Rankine cycle coupled to an innovative particle receiver solar power plant," Renewable Energy, Elsevier, vol. 130(C), pages 786-795.
    8. Bukhary, Saria & Ahmad, Sajjad & Batista, Jacimaria, 2018. "Analyzing land and water requirements for solar deployment in the Southwestern United States," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3288-3305.
    9. Jiang, Kaijun & Du, Xiaoze & Zhang, Qiang & Kong, Yanqiang & Xu, Chao & Ju, Xing, 2021. "Review on gas-solid fluidized bed particle solar receivers applied in concentrated solar applications: Materials, configurations and methodologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    10. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    11. Ekaterina Matus & Olga Sukhova & Ilyas Ismagilov & Mikhail Kerzhentsev & Olga Stonkus & Zinfer Ismagilov, 2021. "Hydrogen Production through Autothermal Reforming of Ethanol: Enhancement of Ni Catalyst Performance via Promotion," Energies, MDPI, vol. 14(16), pages 1-16, August.
    12. Miguel J. Prieto & Juan Á. Martínez & Rogelio Peón & Lourdes Á. Barcia & Fernando Nuño, 2017. "On the Convenience of Using Simulation Models to Optimize the Control Strategy of Molten-Salt Heat Storage Systems in Solar Thermal Power Plants," Energies, MDPI, vol. 10(7), pages 1-17, July.
    13. Okoroigwe, Edmund & Madhlopa, Amos, 2016. "An integrated combined cycle system driven by a solar tower: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 337-350.
    14. Fu, Qianmei & Ding, Jing & Lao, Jiewei & Wang, Weilong & Lu, Jianfeng, 2019. "Thermal-hydraulic performance of printed circuit heat exchanger with supercritical carbon dioxide airfoil fin passage and molten salt straight passage," Applied Energy, Elsevier, vol. 247(C), pages 594-604.
    15. Yang, Honglun & Wang, Qiliang & Huang, Xiaona & Li, Jing & Pei, Gang, 2018. "Performance study and comparative analysis of traditional and double-selective-coated parabolic trough receivers," Energy, Elsevier, vol. 145(C), pages 206-216.
    16. Yang, Song & Wang, Jun & Lund, Peter D. & Jiang, Chuan & Liu, Deli, 2018. "Assessing the impact of optical errors in a novel 2-stage dish concentrator using Monte-Carlo ray-tracing simulation," Renewable Energy, Elsevier, vol. 123(C), pages 603-615.
    17. Mostafavi Tehrani, S. Saeed & Taylor, Robert A., 2016. "Off-design simulation and performance of molten salt cavity receivers in solar tower plants under realistic operational modes and control strategies," Applied Energy, Elsevier, vol. 179(C), pages 698-715.
    18. Bai, Wengang & Li, Hongzhi & Zhang, Xuwei & Qiao, Yongqiang & Zhang, Chun & Gao, Wei & Yao, Mingyu, 2022. "Thermodynamic analysis of CO2–SF6 mixture working fluid supercritical Brayton cycle used for solar power plants," Energy, Elsevier, vol. 261(PB).
    19. Delise, T. & Tizzoni, A.C. & Menale, C. & Telling, M.T.F. & Bubbico, R. & Crescenzi, T. & Corsaro, N. & Sau, S. & Licoccia, S., 2020. "Technical and economic analysis of a CSP plant presenting a low freezing ternary mixture as storage and transfer fluid," Applied Energy, Elsevier, vol. 265(C).
    20. Satinover, Scott J. & Schell, Dan & Borole, Abhijeet P., 2020. "Achieving high hydrogen productivities of 20 L/L-day via microbial electrolysis of corn stover fermentation products," Applied Energy, Elsevier, vol. 259(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:175:y:2023:i:c:s1364032123000400. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.