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Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review

Author

Listed:
  • Sethu Sundar Pethaiah

    (Gashubin Engineering Pte Ltd., 8 New Industrial Road, Singapore 536200, Singapore)

  • Kishor Kumar Sadasivuni

    (Center for Advanced Materials, Qatar University, P.O. Box 2713, Doha 2713, Qatar)

  • Arunkumar Jayakumar

    (SRM Institute of Science and Technology, SRM Nagar, Kattankulathur 603203, India)

  • Deepalekshmi Ponnamma

    (Center for Advanced Materials, Qatar University, P.O. Box 2713, Doha 2713, Qatar)

  • Chandra Sekhar Tiwary

    (Materials Science and Engineering, Indian Institute of Technology, Gandhinagar, Gujarat 38235, India)

  • Gangadharan Sasikumar

    (Sustainable Solutionz, Chennai 600017, India)

Abstract

Hydrogen (H 2 ) has attained significant benefits as an energy carrier due to its gross calorific value (GCV) and inherently clean operation. Thus, hydrogen as a fuel can lead to global sustainability. Conventional H 2 production is predominantly through fossil fuels, and electrolysis is now identified to be most promising for H 2 generation. This review describes the recent state of the art and challenges on ultra-pure H 2 production through methanol electrolysis that incorporate polymer electrolyte membrane (PEM). It also discusses about the methanol electrochemical reforming catalysts as well as the impact of this process via PEM. The efficiency of H 2 production depends on the different components of the PEM fuel cells, which are bipolar plates, current collector, and membrane electrode assembly. The efficiency also changes with the nature and type of the fuel, fuel/oxygen ratio, pressure, temperature, humidity, cell potential, and interfacial electronic level interaction between the redox levels of electrolyte and band gap edges of the semiconductor membranes. Diverse operating conditions such as concentration of methanol, cell temperature, catalyst loading, membrane thickness, and cell voltage that affect the performance are critically addressed. Comparison of various methanol electrolyzer systems are performed to validate the significance of methanol economy to match the future sustainable energy demands.

Suggested Citation

  • Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:5879-:d:443070
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    References listed on IDEAS

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    1. Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.
    2. Brian C. H. Steele & Angelika Heinzel, 2001. "Materials for fuel-cell technologies," Nature, Nature, vol. 414(6861), pages 345-352, November.
    3. Xu, Guoxiao & Wu, Zhiguang & Wei, Zenglv & Zhang, Wenjie & Wu, Junli & Li, Ying & Li, Jing & Qu, Konggang & Cai, Weiwei, 2020. "Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 935-939.
    4. Tang, Yong & Yuan, Wei & Pan, Minqiang & Li, Zongtao & Chen, Guoqing & Li, Yong, 2010. "Experimental investigation of dynamic performance and transient responses of a kW-class PEM fuel cell stack under various load changes," Applied Energy, Elsevier, vol. 87(4), pages 1410-1417, April.
    5. Susastriawan, A.A.P. & Saptoadi, Harwin & Purnomo,, 2017. "Small-scale downdraft gasifiers for biomass gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 989-1003.
    6. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
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    2. Maria Portarapillo & Almerinda Di Benedetto, 2021. "Risk Assessment of the Large-Scale Hydrogen Storage in Salt Caverns," Energies, MDPI, vol. 14(10), pages 1-12, May.
    3. Minsoo Choi & Wongwan Jung & Sanghyuk Lee & Taehwan Joung & Daejun Chang, 2021. "Thermal Efficiency and Economics of a Boil-Off Hydrogen Re-Liquefaction System Considering the Energy Efficiency Design Index for Liquid Hydrogen Carriers," Energies, MDPI, vol. 14(15), pages 1-23, July.
    4. Maciej Chalusiak & Weronika Nawrot & Szymon Buchaniec & Grzegorz Brus, 2021. "Swarm Intelligence-Based Methodology for Scanning Electron Microscope Image Segmentation of Solid Oxide Fuel Cell Anode," Energies, MDPI, vol. 14(11), pages 1-17, May.
    5. Daniel Garraín & Santacruz Banacloche & Paloma Ferreira-Aparicio & Antonio Martínez-Chaparro & Yolanda Lechón, 2021. "Sustainability Indicators for the Manufacturing and Use of a Fuel Cell Prototype and Hydrogen Storage for Portable Uses," Energies, MDPI, vol. 14(20), pages 1-15, October.
    6. Xiaoyu Meng & Yinan Lv & Jihong Wen & Xiaojing Li & Luman Peng & Chuanbo Cong & Haimu Ye & Qiong Zhou, 2022. "In Situ Growth of COF on PAN Nanofibers to Improve Proton Conductivity and Dimensional Stability in Proton Exchange Membranes," Energies, MDPI, vol. 15(9), pages 1-12, May.
    7. Aubaid Ullah & Nur Awanis Hashim & Mohamad Fairus Rabuni & Mohd Usman Mohd Junaidi, 2023. "A Review on Methanol as a Clean Energy Carrier: Roles of Zeolite in Improving Production Efficiency," Energies, MDPI, vol. 16(3), pages 1-35, February.
    8. Jarosław Gryz & Krzysztof Król & Anna Witkowska & Mariusz Ruszel, 2021. "Mobile Nuclear-Hydrogen Synergy in NATO Operations," Energies, MDPI, vol. 14(23), pages 1-12, November.
    9. Davide Clematis & Daria Bellotti & Massimo Rivarolo & Loredana Magistri & Antonio Barbucci, 2023. "Hydrogen Carriers: Scientific Limits and Challenges for the Supply Chain, and Key Factors for Techno-Economic Analysis," Energies, MDPI, vol. 16(16), pages 1-31, August.
    10. Dorota Brzezińska, 2021. "Hydrogen Dispersion and Ventilation Effects in Enclosures under Different Release Conditions," Energies, MDPI, vol. 14(13), pages 1-11, July.
    11. Aleksandr Kulikov & Aleksey Loskutov & Andrey Kurkin & Andrey Dar’enkov & Andrey Kozelkov & Valery Vanyaev & Andrey Shahov & Andrey Shalukho & Rustam Bedretdinov & Ivan Lipuzhin & Evgeny Kryukov, 2021. "Development and Operation Modes of Hydrogen Fuel Cell Generation System for Remote Consumers’ Power Supply," Sustainability, MDPI, vol. 13(16), pages 1-21, August.

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