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Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol

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  • Muthumeenal, A.
  • Pethaiah, S. Sundar
  • Nagendran, A.

Abstract

A polymer electrolyte membrane for hydrogen production through methanol electrolysis was prepared by converting poly ether sulfone (PES) into ionomer via sulfonation and fashioned into membrane. The physical and electrochemical properties of the prepared membrane and a single cell using the fabricated membrane are examined using various characterization techniques, such as, FTIR spectrometry, scanning electron microscopy, thermogravimetric analysis, tensile strength measurement, ion exchange capacity, electrochemical impedance spectroscopy and polarization studies. A current density of 0.802 A/cm2 was obtained at a cell voltage of 1.2 V at 80 °C with the sulfonated polyethersulfone (SPES) based membrane electrode assembly (MEA) under suitable fabrication conditions. The energy requirements for hydrogen production are also compared with conventional water electrolysis. The observational results suggest that SPES membrane could be an option to costly perfluorosulfonate membranes in methanol electrolysis for hydrogen production.

Suggested Citation

  • Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.
    • Handle: RePEc:eee:renene:v:91:y:2016:i:c:p:75-82
    DOI: 10.1016/j.renene.2016.01.042
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    References listed on IDEAS

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    1. Neelakandan, S. & Kanagaraj, P. & Nagendran, A. & Rana, D. & Matsuura, T. & Muthumeenal, A., 2015. "Enhancing proton conduction of sulfonated poly (phenylene ether ether sulfone) membrane by charged surface modifying macromolecules for H2/O2 fuel cells," Renewable Energy, Elsevier, vol. 78(C), pages 306-313.
    2. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    3. M. S. Dresselhaus & I. L. Thomas, 2001. "Alternative energy technologies," Nature, Nature, vol. 414(6861), pages 332-337, November.
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    1. Gutiérrez-Martín, F. & Calcerrada, A.B. & de Lucas-Consuegra, A. & Dorado, F., 2020. "Hydrogen storage for off-grid power supply based on solar PV and electrochemical reforming of ethanol-water solutions," Renewable Energy, Elsevier, vol. 147(P1), pages 639-649.
    2. Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    3. Sanjay Kumar Kar & Akhoury Sudhir Kumar Sinha & Sidhartha Harichandan & Rohit Bansal & Marriyappan Sivagnanam Balathanigaimani, 2023. "Hydrogen economy in India: A status review," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(1), January.
    4. Ju, HyungKuk & Badwal, Sukhvinder & Giddey, Sarbjit, 2018. "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production," Applied Energy, Elsevier, vol. 231(C), pages 502-533.
    5. Zhou, Jing & Cao, Jiamu & Zhang, Yufeng & Liu, Junfeng & Chen, Junyu & Li, Mingxue & Wang, Weiqi & Liu, Xiaowei, 2021. "Overcoming undesired fuel crossover: Goals of methanol-resistant modification of polymer electrolyte membranes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    6. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.

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