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Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell

Author

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  • Xu, Guoxiao
  • Wu, Zhiguang
  • Wei, Zenglv
  • Zhang, Wenjie
  • Wu, Junli
  • Li, Ying
  • Li, Jing
  • Qu, Konggang
  • Cai, Weiwei

Abstract

Based on the swelling-filling modification strategy, Nafion/silica composite membrane is facilely fabricated by non-destructively filling silica nano-particles into the Nafion framework. High temperature proton conductive performance of modified Nafion membrane is significantly enhanced due to the synergistic effect of maintaining the ordered nanophase-separated structure in Nafion and excellent water retention capacity of the silica fillers. Proton conductivity of the composite membrane is therefore raised to 33 mS/cm at 110 °C and 60% RH, which is enhanced by ca. 30% compared with the pristine Nafion. Taking account into the improved mechanical and oxidative stabilities attributed to the hydrogen bonding interaction between silica nano-particles and Nafion chains, high temperature fuel cell performance is measured and found to be remarkably improved by 37% at low humidity by considering the power density.

Suggested Citation

  • Xu, Guoxiao & Wu, Zhiguang & Wei, Zenglv & Zhang, Wenjie & Wu, Junli & Li, Ying & Li, Jing & Qu, Konggang & Cai, Weiwei, 2020. "Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 935-939.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:935-939
    DOI: 10.1016/j.renene.2020.02.056
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    References listed on IDEAS

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    1. Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
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    Cited by:

    1. Tawalbeh, Muhammad & Al-Othman, Amani & Ka'ki, Ahmad & Farooq, Afifa & Alkasrawi, Malek, 2022. "Lignin/zirconium phosphate/ionic liquids-based proton conducting membranes for high-temperature PEM fuel cells applications," Energy, Elsevier, vol. 260(C).
    2. Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    3. Ouyang, Tiancheng & Lu, Jie & Xu, Peihang & Hu, Xiaoyi & Chen, Jingxian, 2022. "High-efficiency fuel utilization innovation in microfluidic fuel cells: From liquid-feed to vapor-feed," Energy, Elsevier, vol. 240(C).
    4. Hooshyari, Khadijeh & Heydari, Samira & Beydaghi, Hossein & Rajabi, Hamid Reza, 2022. "New nanocomposite membranes based on sulfonated poly (phthalazinone ether ketone) and Fe3O4@SiO2@ resorcinol–aldehyde–SO3H for PEMFCs," Renewable Energy, Elsevier, vol. 186(C), pages 115-125.
    5. Hou, Junbo & Yang, Min & Zhang, Junliang, 2020. "Active and passive fuel recirculation for solid oxide and proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 155(C), pages 1355-1371.
    6. Ouyang, Tiancheng & Chen, Jingxian & Liu, Wenjun & Xu, Peihang & Lu, Jie & Zhao, Zhongkai, 2022. "A comprehensive evaluation for microfluidic fuel cells from anti-vibration viewpoint using phase field theory," Renewable Energy, Elsevier, vol. 189(C), pages 676-693.

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