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MOF-derived Co nanoparticle on nitrogen-rich carbon for fatty acid hydrotreatment into green diesel

Author

Listed:
  • Du, Yuchan
  • Wang, Fei
  • Xia, Xueying
  • Zhu, Hao
  • Zhang, Zeng
  • You, Chaoqun
  • Jiang, Xiaoxiang
  • Jiang, Jianchun
  • Li, Changzhu

Abstract

The green diesel from lipid hydrotreatment can replace directly the fossil diesel. In order to solve the problem of Co agglomeration, Co nanoparticle on nitrogen-rich carbon (Co-NP/NC) was synthesized by using the Co-MOF as precursor. After tuning the method of Co-MOF preparation and the subsequent pyrolysis temperature, the preparation parameters of Co-NP/NC were optimized. At 220 °C, the oleic acid hydrotreatment over Co-NP/NC-1:20-400 catalyst attained 99.6% conversion and 99.6% alkane yield, much higher than that over traditional Co/AC (76.8% conversion and 14.9% total alkane yield). The apparent activation energy of octadecanol hydrotreatment over Co-NP/NC-1:20-500 was much lower than Co/AC (148.86 vs. 204.01 kJ/mol), further revealing the high catalytic performance of Co-NP/NC catalyst. From the characterizations of Co-NP/NC series catalysts, the highly dispersed Co nanoparticles with 4.37 nm, abundant pyridine nitrogen and pyrrole nitrogen as well as the layered morphology providing sufficient active area contributed the decent activity in lipid deoxygenation.

Suggested Citation

  • Du, Yuchan & Wang, Fei & Xia, Xueying & Zhu, Hao & Zhang, Zeng & You, Chaoqun & Jiang, Xiaoxiang & Jiang, Jianchun & Li, Changzhu, 2022. "MOF-derived Co nanoparticle on nitrogen-rich carbon for fatty acid hydrotreatment into green diesel," Renewable Energy, Elsevier, vol. 198(C), pages 246-253.
    • Handle: RePEc:eee:renene:v:198:y:2022:i:c:p:246-253
    DOI: 10.1016/j.renene.2022.08.019
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    References listed on IDEAS

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    1. del Río, Juan I. & Pérez, William & Cardeño, Fernando & Marín, James & Rios, Luis A., 2021. "Pre-hydrogenation stage as a strategy to improve the continuous production of a diesel-like biofuel from palm oil," Renewable Energy, Elsevier, vol. 168(C), pages 505-515.
    2. Wei Jin & Laura Pastor-Pérez & Juan J. Villora-Pico & Mercedes M. Pastor-Blas & Antonio Sepúlveda-Escribano & Sai Gu & Nikolaos D. Charisiou & Kyriakos Papageridis & Maria A. Goula & Tomas R. Reina, 2019. "Catalytic Conversion of Palm Oil to Bio-Hydrogenated Diesel over Novel N-Doped Activated Carbon Supported Pt Nanoparticles," Energies, MDPI, vol. 13(1), pages 1-15, December.
    3. Hongloi, Nitchakul & Prapainainar, Paweena & Seubsai, Anusorn & Sudsakorn, Kandis & Prapainainar, Chaiwat, 2019. "Nickel catalyst with different supports for green diesel production," Energy, Elsevier, vol. 182(C), pages 306-320.
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    1. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    2. Luo, Hui & Yang, Huimin & Deng, Wenan & Li, Chuan & Du, Feng & Li, Shufeng, 2023. "Slurry-phase hydrotreating of waste oil to bio-hydrogenated diesel using in situ oil-soluble MoS2 nanoparticles," Renewable Energy, Elsevier, vol. 219(P2).

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