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Optimization, Transesterification and Analytical Study of Rhus typhina Non-Edible Seed Oil as Biodiesel Production

Author

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  • Inam Ullah Khan

    (Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, College of Chemistry, Nankai University, Tianjin 300071, China)

  • Zhenhua Yan

    (Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, College of Chemistry, Nankai University, Tianjin 300071, China)

  • Jun Chen

    (Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, College of Chemistry, Nankai University, Tianjin 300071, China)

Abstract

Production of biodiesel from non-edible oils is one of the effective methods to reduce production costs and alleviate the obstacle of traditional raw material supply. Rhus typhina L . (RT) is a promising non-edible plant because it grows fast and has abundant seeds. But previously reported oil content of RT was only 9.7% and 12%. Further research into improving the biodiesel production of RT seed oil is urgently needed. Here we obtained the biodiesel production of RT with a maximum oil content of 22% with a low free fatty acid content of 1.0%. The fatty acid methyl ester (FAMEs) of the RT seed oil was produced by a standard optimized protocol use KOH as a catalyst with the highest yield of 93.4% ( w / w ). The quality and purity of RT FAMEs, as well as the physio-chemical characterizations of the biodiesel products, were investigated and compared with the international standard of ASTM D6751 and EN 14214. The values of fuel properties are comparable with mineral diesel and environmentally friendly. Overall, the proposed RT seed oil could be a potential source of raw materials for producing high-quality biodiesel after the optimization and transesterification.

Suggested Citation

  • Inam Ullah Khan & Zhenhua Yan & Jun Chen, 2019. "Optimization, Transesterification and Analytical Study of Rhus typhina Non-Edible Seed Oil as Biodiesel Production," Energies, MDPI, vol. 12(22), pages 1-21, November.
  • Handle: RePEc:gam:jeners:v:12:y:2019:i:22:p:4290-:d:285703
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    References listed on IDEAS

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    1. Lu, Pengmei & Yuan, Zhenhong & Li, Lianhua & Wang, Zhongming & Luo, Wen, 2010. "Biodiesel from different oil using fixed-bed and plug-flow reactors," Renewable Energy, Elsevier, vol. 35(1), pages 283-287.
    2. Sharma, Y.C. & Singh, B., 2009. "Development of biodiesel: Current scenario," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1646-1651, August.
    3. Eevera, T. & Rajendran, K. & Saradha, S., 2009. "Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental conditions," Renewable Energy, Elsevier, vol. 34(3), pages 762-765.
    4. Ruan, Cheng-Jiang & Xing, Wei-He & Teixeira da Silva, Jaime A., 2012. "Potential of five plants growing on unproductive agricultural lands as biodiesel resources," Renewable Energy, Elsevier, vol. 41(C), pages 191-199.
    5. Haiwen Song & Kelly Sison Quinton & Zhijun Peng & Hua Zhao & Nicos Ladommatos, 2016. "Effects of Oxygen Content of Fuels on Combustion and Emissions of Diesel Engines," Energies, MDPI, vol. 9(1), pages 1-12, January.
    6. Kafuku, G. & Mbarawa, M., 2010. "Alkaline catalyzed biodiesel production from moringa oleifera oil with optimized production parameters," Applied Energy, Elsevier, vol. 87(8), pages 2561-2565, August.
    7. Mwangi, John Kennedy & Lee, Wen-Jhy & Chang, Yu-Cheng & Chen, Chia-Yang & Wang, Lin-Chi, 2015. "An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines," Applied Energy, Elsevier, vol. 159(C), pages 214-236.
    8. Gülşen, Ece & Olivetti, Elsa & Freire, Fausto & Dias, Luis & Kirchain, Randolph, 2014. "Impact of feedstock diversification on the cost-effectiveness of biodiesel," Applied Energy, Elsevier, vol. 126(C), pages 281-296.
    9. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
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    Cited by:

    1. Liang Zhou & Jingang Yao & Zhaoxia Ren & Zhenqiang Yu & Hongzhen Cai, 2020. "Development of Magnetic Multi-Shelled Hollow Catalyst for Biodiesel Production," Energies, MDPI, vol. 13(11), pages 1-14, June.
    2. Inam Ullah Khan & Zhenhua Yan & Jun Chen, 2020. "Production and Characterization of Biodiesel Derived from a Novel Source Koelreuteria paniculata Seed Oil," Energies, MDPI, vol. 13(4), pages 1-15, February.
    3. Maryam Tanveer Akhtar & Mushtaq Ahmad & Maliha Asma & Mamoona Munir & Muhammad Zafar & Shazia Sultana & M. A. Mujtaba & Abdullah Mohamed & Md Abul Kalam, 2022. "Efficient Production of Wild and Non-Edible Brassica juncea (L.) Czern. Seed Oil into High-Quality Biodiesel via Novel, Green and Recyclable NiSO 4 Nano-Catalyst," Sustainability, MDPI, vol. 14(16), pages 1-26, August.
    4. Hoang Chinh Nguyen & Fu-Ming Wang & Kim Khue Dinh & Thanh Truc Pham & Horng-Yi Juan & Nguyen Phuong Nguyen & Hwai Chyuan Ong & Chia-Hung Su, 2020. "Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study," Energies, MDPI, vol. 13(9), pages 1-15, May.

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