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Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils

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  • Karavalakis, Georgios
  • Anastopoulos, Georgios
  • Stournas, Stamos

Abstract

New catalysts and environmentally benign processes may lead to methyl ester production with improved properties at competitive costs. In this study, transesterification of waste frying oil to biodiesel using tetramethylguanidine as a strong base catalyst was conducted. The influence of catalyst concentration and of certain physicochemical properties of waste frying oil was investigated. Experiments were also performed on a semi-refined cottonseed oil for comparison purposes. Experimental results showed that methyl ester conversion was dependent on the type of oil, catalyst concentration and reaction time.

Suggested Citation

  • Karavalakis, Georgios & Anastopoulos, Georgios & Stournas, Stamos, 2011. "Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils," Applied Energy, Elsevier, vol. 88(11), pages 3645-3650.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:11:p:3645-3650
    DOI: 10.1016/j.apenergy.2011.03.050
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    2. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    3. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    4. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    5. Praveena, V. & Martin, Leenus Jesu & Matijošius, Jonas & Aloui, Fethi & Pugazhendhi, Arivalagan & Varuvel, Edwin Geo, 2024. "A systematic review on biofuel production and utilization from algae and waste feedstocks– a circular economy approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    6. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    7. Racar, Marko & Šoljić Jerbić, Ivana & Glasovac, Zoran & Jukić, Ante, 2023. "Guanidine catalysts for biodiesel production: Activity, process modelling and optimization," Renewable Energy, Elsevier, vol. 202(C), pages 1046-1053.
    8. Racar, Marko & Faraguna, Fabio & Glasovac, Zoran & Jukić, Ante, 2020. "Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2374-2379.
    9. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.

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