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Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells

Author

Listed:
  • Uma Devi, A.
  • Muthumeenal, A.
  • Sabarathinam, R.M.
  • Nagendran, A.

Abstract

Sulfonated poly (vinylidene fluoride-co-hexafluoropropylene) (SPVdF-co-HFP)/sulfonated poly (ether sulfone) (SPES) blend polymer electrolyte membranes (PEMs) were fabricated effectively as an alternative PEM for direct methanol fuel cell (DMFC) applications. In order to prepare PEMs with improved proton conductivity PVdF-co-HFP and PES were preferred and sulfonated using chlorosulfonic acid and sulfuric acid respectively. The presence of sulfonic acid groups were confirmed by FT-IR spectroscopy. TGA results showed that SPVdF-co-HFP/SPES blend membranes were superior than control one. Atomic force microscopy images of the blend PEMs clearly showed that the surface roughness and nodule size are increased. The influential characteristics of the PEMs, such as, water uptake, swelling ratio, ion-exchange capacity, proton conductivity, methanol crossover, selectivity ratio were characterized with respect to the control membrane. Though, the tensile strength and elongation at break slightly decreases by the addition of hydrophilic SPES, the water uptake and proton conductivity of SPVdF-co-HFP/SPES blend membranes were increased and found to be higher than that of the pure SPVdF-co-HFP. Selectivity ratio of the prepared blend PEMs were in the range of 1.709 × 104 to 2.193 × 104 S cm−3 s which is much higher than that of Nafion 117 (0.214 × 104 S cm−3s) membrane.

Suggested Citation

  • Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    • Handle: RePEc:eee:renene:v:102:y:2017:i:pa:p:258-265
    DOI: 10.1016/j.renene.2016.10.060
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    References listed on IDEAS

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    1. Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.
    2. Kumar, Piyush & Dutta, Kingshuk & Das, Suparna & Kundu, Patit Paban, 2014. "Membrane prepared by incorporation of crosslinked sulfonated polystyrene in the blend of PVdF-co-HFP/Nafion: A preliminary evaluation for application in DMFC," Applied Energy, Elsevier, vol. 123(C), pages 66-74.
    3. Kumar, Vikash & Nandy, Arpita & Das, Suparna & Salahuddin, M. & Kundu, Patit P., 2015. "Performance assessment of partially sulfonated PVdF-co-HFP as polymer electrolyte membranes in single chambered microbial fuel cells," Applied Energy, Elsevier, vol. 137(C), pages 310-321.
    4. Neelakandan, S. & Kanagaraj, P. & Nagendran, A. & Rana, D. & Matsuura, T. & Muthumeenal, A., 2015. "Enhancing proton conduction of sulfonated poly (phenylene ether ether sulfone) membrane by charged surface modifying macromolecules for H2/O2 fuel cells," Renewable Energy, Elsevier, vol. 78(C), pages 306-313.
    5. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    6. Dutta, Kingshuk & Das, Suparna & Kumar, Piyush & Kundu, Patit Paban, 2014. "Polymer electrolyte membrane with high selectivity ratio for direct methanol fuel cells: A preliminary study based on blends of partially sulfonated polymers polyaniline and PVdF-co-HFP," Applied Energy, Elsevier, vol. 118(C), pages 183-191.
    7. Das, Suparna & Kumar, Piyush & Dutta, Kingshuk & Kundu, Patit Paban, 2014. "Partial sulfonation of PVdF-co-HFP: A preliminary study and characterization for application in direct methanol fuel cell," Applied Energy, Elsevier, vol. 113(C), pages 169-177.
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    1. Simari, C. & Lo Vecchio, C. & Baglio, V. & Nicotera, I., 2020. "Sulfonated polyethersulfone/polyetheretherketone blend as high performing and cost-effective electrolyte membrane for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 159(C), pages 336-345.
    2. Chen, Xueye & Li, Tiechuan & Shen, Jienan & Hu, Zengliang, 2017. "From structures, packaging to application: A system-level review for micro direct methanol fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 669-678.
    3. Zhou, Jing & Cao, Jiamu & Zhang, Yufeng & Liu, Junfeng & Chen, Junyu & Li, Mingxue & Wang, Weiqi & Liu, Xiaowei, 2021. "Overcoming undesired fuel crossover: Goals of methanol-resistant modification of polymer electrolyte membranes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    4. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.

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