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Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells

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  • Ingabire, Providence Buregeya
  • Pan, Xueting
  • Haragirimana, Alphonse
  • Li, Na
  • Hu, Zhaoxia
  • Chen, Shouwen

Abstract

A series of quaternary aminated poly(arylene ether sulfone) (QPAES) nanocomposite membranes (QPAES-TiO2/g-C3N4) were fabricated by a double-component nanocomposite system of titanium dioxide/graphitic carbon nitride (TiO2/g-C3N4) and the polymer. TiO2 nanoparticles were firstly functionalized with the highly ion-conductive groups of g-C3N4 to synthesize TiO2/g-C3N4 nanocomposites. Their fundamental properties including water absorbing-swelling behavior, thermo-mechanical property, chemical stability, ion conductivity and fuel cell performance were investigated. The QPAES-TiO2/g-C3N4 membrane containing 0.45 wt% TiO2/g-C3N4 revealed considerable enhancements in ion conductivity, chemical stability and fuel cell performance. It absorbed water as high as 88.7% but expanded less than 13% in the membrane in-plane direction, and showed hydroxide conductivity of 43.8 mS/cm at 80 °C, besides, in a H2/O2 fuel cell, its maximum power density arrived at 64.3 mW/cm2 under a current density of 131.2 mA/cm2 at 80 °C. This work demonstrated that membrane with the proper content of TiO2/g-C3N4 nanocomposites could be a promising candidate for fuel cell applications.

Suggested Citation

  • Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
    • Handle: RePEc:eee:renene:v:152:y:2020:i:c:p:590-600
    DOI: 10.1016/j.renene.2020.01.072
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