IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v176y2021icp262-268.html
   My bibliography  Save this article

The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol

Author

Listed:
  • Vávra, Aleš
  • Hájek, Martin
  • Kocián, David

Abstract

The paper describes the properties of glycerol produced by transesterification, especially the ester content in the glycerol phase (ester losses) including the distribution of esters according to higher fatty acids. Glycerol, produced by transesterification of oil as a side product – the polar glycerol phase, is an important chemical raw material. The decreasing of ester losses is important because it (i) increases the ester yield and especially (ii) decreases the cost of glycerol purification. The transesterification of oils (rapeseed, olive, palm, sunflower and Camelina Sativa) with various distributions of fatty acids was carried out by methanol, ethanol and butanol including different transesterification stopping. The losses of ethyl and butyl esters are much higher than losses of methyl ester (approximately 2–3x). The distribution of ethyl and butyl esters in the glycerol phase is the same as in the ester phase, whereas distribution of methyl ester is different and depends on the way of transesterification stopping. The reason is the different polarity of methyl esters, which depends on the type of fatty acid. The polarity increases with increasing of double bonds, i.e. the most soluble is methyl ester of linolenic acid in the glycerol phase.

Suggested Citation

  • Vávra, Aleš & Hájek, Martin & Kocián, David, 2021. "The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol," Renewable Energy, Elsevier, vol. 176(C), pages 262-268.
    • Handle: RePEc:eee:renene:v:176:y:2021:i:c:p:262-268
    DOI: 10.1016/j.renene.2021.05.050
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121007266
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.05.050?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jindapon, Wayu & Ruengyoo, Supapan & Kuchonthara, Prapan & Ngamcharussrivichai, Chawalit & Vitidsant, Tharapong, 2020. "Continuous production of fatty acid methyl esters and high-purity glycerol over a dolomite-derived extrudate catalyst in a countercurrent-flow trickle-bed reactor," Renewable Energy, Elsevier, vol. 157(C), pages 626-636.
    2. Anuar, Mohd Razealy & Abdullah, Ahmad Zuhairi, 2016. "Challenges in biodiesel industry with regards to feedstock, environmental, social and sustainability issues: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 208-223.
    3. Jiménez, Roberto X. & Young, André F. & Fernandes, Heloisa L.S., 2020. "Propylene glycol from glycerol: Process evaluation and break-even price determination," Renewable Energy, Elsevier, vol. 158(C), pages 181-191.
    4. Issariyakul, Titipong & Dalai, Ajay K., 2014. "Biodiesel from vegetable oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 446-471.
    5. Carraretto, C. & Macor, A. & Mirandola, A. & Stoppato, A. & Tonon, S., 2004. "Biodiesel as alternative fuel: Experimental analysis and energetic evaluations," Energy, Elsevier, vol. 29(12), pages 2195-2211.
    6. Rahman, Md. Shafiqur & Xu, Chunbao (Charles) & Ma, Kesen & Guo, Haipeng & Qin, Wensheng, 2017. "Utilization of by-product glycerol from bio-diesel plants as feedstock for 2,3-butanediol accumulation and biosynthesis genes response of Klebsiella variicola SW3," Renewable Energy, Elsevier, vol. 114(PB), pages 1272-1280.
    7. Sendzikiene, Egle & Sinkuniene, Dovile & Kazanceva, Irina & Kazancev, Kiril, 2016. "Optimization of low quality rapeseed oil transesterification with butanol by applying the response surface methodology," Renewable Energy, Elsevier, vol. 87(P1), pages 266-272.
    8. Likozar, Blaž & Levec, Janez, 2014. "Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics ," Applied Energy, Elsevier, vol. 123(C), pages 108-120.
    9. Binhayeeding, Narisa & Klomklao, Sappasith & Prasertsan, Poonsuk & Sangkharak, Kanokphorn, 2020. "Improvement of biodiesel production using waste cooking oil and applying single and mixed immobilised lipases on polyhydroxyalkanoate," Renewable Energy, Elsevier, vol. 162(C), pages 1819-1827.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Hájek, Martin & Kocián, David & Douda, Miroslav, 2023. "Statistical evaluation of the epoxidation of esters from vegetable oils and optimization of reaction conditions," Renewable Energy, Elsevier, vol. 213(C), pages 157-164.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    2. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    3. Mofijur, M. & Rasul, M.G. & Hyde, J. & Azad, A.K. & Mamat, R. & Bhuiya, M.M.K., 2016. "Role of biofuel and their binary (diesel–biodiesel) and ternary (ethanol–biodiesel–diesel) blends on internal combustion engines emission reduction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 265-278.
    4. Işik, Mehmet Zerrakki & Aydin, Hüseyin, 2019. "Investigation on the effects of gasoline reactivity controlled compression ignition application in a diesel generator in high loads using safflower biodiesel blends," Renewable Energy, Elsevier, vol. 133(C), pages 177-189.
    5. Ali, Chaudhry Haider & Qureshi, Abdul Sattar & Mbadinga, Serge Maurice & Liu, Jin-Feng & Yang, Shi-Zhong & Mu, Bo-Zhong, 2017. "Biodiesel production from waste cooking oil using onsite produced purified lipase from Pseudomonas aeruginosa FW_SH-1: Central composite design approach," Renewable Energy, Elsevier, vol. 109(C), pages 93-100.
    6. Ismail, Tamer M. & Lu, Ding & Ramzy, Khaled & Abd El-Salam, M. & Yu, Guangsuo & Elkady, M.A., 2019. "Experimental and theoretical investigation on the performance of a biodiesel-powered engine from plant seeds in Egypt," Energy, Elsevier, vol. 189(C).
    7. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    8. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sharma, Meeta & Malhotra, R.K., 2009. "Influence of metal contaminants on oxidation stability of Jatropha biodiesel," Energy, Elsevier, vol. 34(9), pages 1271-1275.
    9. Tsai, Wen-Tien & Lin, Chih-Chung & Yeh, Ching-Wei, 2007. "An analysis of biodiesel fuel from waste edible oil in Taiwan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(5), pages 838-857, June.
    10. Lee, Wen-Jhy & Liu, Yi-Cheng & Mwangi, Francis Kimani & Chen, Wei-Hsin & Lin, Sheng-Lun & Fukushima, Yasuhiro & Liao, Chao-Ning & Wang, Lin-Chi, 2011. "Assessment of energy performance and air pollutant emissions in a diesel engine generator fueled with water-containing ethanol–biodiesel–diesel blend of fuels," Energy, Elsevier, vol. 36(9), pages 5591-5599.
    11. Haseeb, A.S.M.A. & Jun, T.S. & Fazal, M.A. & Masjuki, H.H., 2011. "Degradation of physical properties of different elastomers upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(3), pages 1814-1819.
    12. Bonaiuto, M. & Mosca, O. & Milani, A. & Ariccio, S. & Dessi, F. & Fornara, F., 2024. "Beliefs about technological and contextual features drive biofuels’ social acceptance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    13. Li, Chong & Ye, Mingzhi & Liu, Bo & Shang, Yanlei & Ning, Hongbo & Shi, Jinchun & Luo, Sheng-Nian, 2023. "Shock tube experiments and kinetic modeling of ignition of unsaturated C5 methyl esters," Energy, Elsevier, vol. 284(C).
    14. Aytav, Emre & Kocar, Günnur, 2013. "Biodiesel from the perspective of Turkey: Past, present and future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 335-350.
    15. Kang, Sae Byul & Kim, Jong Jin & Im, Yong Hoon, 2013. "An experimental investigation of a direct burning of crude Jatropha oil (CJO) and pitch in a commercial boiler system," Renewable Energy, Elsevier, vol. 54(C), pages 8-12.
    16. Mia Gotovuša & Ivan Pucko & Marko Racar & Fabio Faraguna, 2022. "Biodiesel Produced from Propanol and Longer Chain Alcohols—Synthesis and Properties," Energies, MDPI, vol. 15(14), pages 1-21, July.
    17. Makasson R. Cland & Offong O. Aniekan & Muhammad A. Tahir & Ogbaka T. David, 2020. "Production of Biodiesel from Groundnut Crude Oil," International Journal of Research and Innovation in Applied Science, International Journal of Research and Innovation in Applied Science (IJRIAS), vol. 5(8), pages 133-136, August.
    18. Chang, Yu-Cheng & Lee, Wen-Jhy & Wu, Tser Son & Wu, Chang-Yu & Chen, Shui-Jen, 2014. "Use of water containing acetone–butanol–ethanol for NOx-PM (nitrogen oxide-particulate matter) trade-off in the diesel engine fueled with biodiesel," Energy, Elsevier, vol. 64(C), pages 678-687.
    19. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Nizami, Abdul-Sattar & Sultana, Shazia & Zafar, Muhammad & Rehan, Mohammad & Srinivasan, Gokul Raghavendra & Ali, Arshid Mahmood & Al, 2021. "Biodiesel production from novel non-edible caper (Capparis spinosa L.) seeds oil employing Cu–Ni doped ZrO2 catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    20. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:176:y:2021:i:c:p:262-268. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.