IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v153y2022ics1364032121010248.html
   My bibliography  Save this article

Prospecting pecan nutshell pyrolysis as a source of bioenergy and bio-based chemicals using multicomponent kinetic modeling, thermodynamic parameters estimation, and Py-GC/MS analysis

Author

Listed:
  • Mumbach, Guilherme Davi
  • Alves, José Luiz Francisco
  • da Silva, Jean Constantino Gomes
  • Domenico, Michele Di
  • Arias, Santiago
  • Pacheco, Jose Geraldo A.
  • Marangoni, Cintia
  • Machado, Ricardo Antonio Francisco
  • Bolzan, Ariovaldo

Abstract

This work reports the first detailed investigation of the physicochemical properties of the pecan nutshell waste (PNS) and its suitability for pyrolytic conversion into bioenergy and bio-based chemicals based on the kinetic triplet, thermodynamic parameters, and Py-GC/MS analysis. The pyrolysis behavior of PNS was assessed using a thermogravimetric analyzer at five heating rate programs under an oxygen-free atmosphere. The Asym2Sig deconvolution function showed that pyrolysis of PNS might be successfully modeled as three parallel devolatilization events (R2 > 99%), which are categorized as the devolatilization of hemicellulose (DE-HC), devolatilization of cellulose (DE-CL), and devolatilization of lignin (DE-LG). The activation energy was obtained for each devolatilization event by concurrent use of four isoconversional methods (Friedman, Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Starink), with average values in the range of 100.3–109.0 kJ mol−1 for DE-HC, 124.3–135.3 kJ mol−1 for DE-CL, and 357.1–398.9 kJ mol−1 for DE-LG. Calculations using the compensation effect method indicated pre-exponential factor values of 5.50 × 108 min−1 for DE-HC, 1.32 × 109 min−1 for DE-CL, and 4.86 × 1018 min−1 for DE-LG. It is inferred that the DE-CL corresponds to a geometrical contraction reaction model while the DE-HC and DE-LG follow order-based reaction models. Finally, the summative kinetic interpretation was successfully obtained based on multiple kinetic triplets, providing a useful mathematical tool able to describe the pyrolysis behavior of PNS. From the thermodynamic viewpoint, PNS has significant potential for application as raw material for bioenergy production. Also, the condensable fraction of the volatile products derived from pecan nutshell pyrolysis is a potential source of valuable bio-based chemicals.

Suggested Citation

  • Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Arias, Santiago & Pacheco, Jose Geraldo A. & Marangoni, Cintia & Machado, Ricardo Anton, 2022. "Prospecting pecan nutshell pyrolysis as a source of bioenergy and bio-based chemicals using multicomponent kinetic modeling, thermodynamic parameters estimation, and Py-GC/MS analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    • Handle: RePEc:eee:rensus:v:153:y:2022:i:c:s1364032121010248
    DOI: 10.1016/j.rser.2021.111753
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032121010248
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2021.111753?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Badshah, Syed Lal & Shah, Zahir & Francisco Alves, José Luiz & Gomes da Silva, Jean Constantino & Iqbal, Arshad, 2021. "Pyrolysis of the freshwater macroalgae Spirogyra crassa: Evaluating its bioenergy potential using kinetic triplet and thermodynamic parameters," Renewable Energy, Elsevier, vol. 179(C), pages 1169-1178.
    2. Moine, Ely cheikh & Groune, Khalihena & El Hamidi, Adnane & Khachani, Mariam & Halim, Mohammed & Arsalane, Said, 2016. "Multistep process kinetics of the non-isothermal pyrolysis of Moroccan Rif oil shale," Energy, Elsevier, vol. 115(P1), pages 931-941.
    3. Xu, Li & Li, Shengcai & Sun, Wanghu & Ma, Xin & Cao, Shuchao, 2020. "Combustion behaviors and characteristic parameters determination of sassafras wood under different heating conditions," Energy, Elsevier, vol. 203(C).
    4. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Pin & Li, Chong & Xu, Dong & Yellezuome, Dominic & Wang, Jiong & Cai, Junmeng, 2023. "Insight into kinetics and thermodynamics of distillers’ dried grains with solubles (DDGS) combustion using an approach simultaneously determining frequency factor and reaction model," Renewable Energy, Elsevier, vol. 219(P2).
    2. Kung, Chih-Chun & Fei, Chengcheng J. & McCarl, Bruce A. & Fan, Xinxin, 2022. "A review of biopower and mitigation potential of competing pyrolysis methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    3. Nishu, & Li, Chong & Yellezuome, Dominic & Li, Yingkai & Liu, Ronghou, 2023. "Catalytic pyrolysis of rice straw for high yield of aromatics over modified ZSM-5 catalysts and its kinetics," Renewable Energy, Elsevier, vol. 209(C), pages 569-580.
    4. Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Marangoni, Cintia & Machado, Ricardo Antonio Francisco & Bolzan, Ariovaldo, 2022. "Investigation on prospective bioenergy from pyrolysis of butia seed waste using TGA-FTIR: Assessment of kinetic triplet, thermodynamic parameters and evolved volatiles," Renewable Energy, Elsevier, vol. 191(C), pages 238-250.
    5. Marcus P. B. Martins & Carla E. Hori & Marcos A. S. Barrozo & Luiz G. M. Vieira, 2022. "Solar Pyrolysis of Spirulina platensis Assisted by Fresnel Lens Using Hydrocalumite-Type Precursors," Energies, MDPI, vol. 15(20), pages 1-19, October.
    6. Nishu, & Tang, Songbiao & Mei, Wenjie & Yang, Juntao & Wang, Zhongming & Yang, Gaixiu, 2024. "Effect of anaerobic digestion pretreatment on pyrolysis of distillers’ grain: Product distribution, kinetics and thermodynamics analysis," Renewable Energy, Elsevier, vol. 221(C).
    7. Zhang, Zhiyi & Li, Yingkai & Luo, Laipeng & Yellezuome, Dominic & Rahman, Md Maksudur & Zou, Jianfeng & Hu, Hangli & Cai, Junmeng, 2023. "Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis," Renewable Energy, Elsevier, vol. 202(C), pages 154-171.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Mumbach, Guilherme Davi & de Sena, Rennio Felix & Machado, Ricardo Antonio Francisco & Marangoni, Cintia, 2022. "Prospection of catole coconut (Syagrus cearensis) as a new bioenergy feedstock: Insights from physicochemical characterization, pyrolysis kinetics, and thermodynamics parameters," Renewable Energy, Elsevier, vol. 181(C), pages 207-218.
    2. Sergio Suárez & Jose Guillermo Rosas & Marta Elena Sánchez & Roberto López & Natalia Gómez & Jorge Cara-Jiménez, 2019. "Parametrization of a Modified Friedman Kinetic Method to Assess Vine Wood Pyrolysis Using Thermogravimetric Analysis," Energies, MDPI, vol. 12(13), pages 1-14, July.
    3. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    4. Hossam A. Gabbar & Muhammad Sajjad Ahmad, 2024. "Integrated Waste-to-Energy Process Optimization for Municipal Solid Waste," Energies, MDPI, vol. 17(2), pages 1-20, January.
    5. Devasahayam, Sheila & Albijanic, Boris, 2024. "Predicting hydrogen production from co-gasification of biomass and plastics using tree based machine learning algorithms," Renewable Energy, Elsevier, vol. 222(C).
    6. Alam, Mahboob & Bhavanam, Anjireddy & Jana, Ashirbad & Viroja, Jaimin kumar S. & Peela, Nageswara Rao, 2020. "Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 149(C), pages 1133-1145.
    7. Chen, Yu-Kai & Lin, Cheng-Han & Wang, Wei-Cheng, 2020. "The conversion of biomass into renewable jet fuel," Energy, Elsevier, vol. 201(C).
    8. Peter N. Ciesielski & M. Brennan Pecha & Vivek S. Bharadwaj & Calvin Mukarakate & G. Jeremy Leong & Branden Kappes & Michael F. Crowley & Seonah Kim & Thomas D. Foust & Mark R. Nimlos, 2018. "Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 7(4), July.
    9. Dong, Shengfei & Liu, Ziyu & Yang, Xiaoyi, 2024. "Exploration of hydrothermal liquefaction of multiple algae to improve bio-crude quality and carbohydrate utilization," Applied Energy, Elsevier, vol. 361(C).
    10. Xie, Yingpu & Zeng, Kuo & Flamant, Gilles & Yang, Haiping & Liu, Nian & He, Xiao & Yang, Xinyi & Nzihou, Ange & Chen, Hanping, 2019. "Solar pyrolysis of cotton stalk in molten salt for bio-fuel production," Energy, Elsevier, vol. 179(C), pages 1124-1132.
    11. Huang, Dexin & Song, Gongxiang & Li, Ruochen & Han, Hengda & He, Limo & Jiang, Long & Wang, Yi & Su, Sheng & Hu, Song & Xiang, Jun, 2023. "Evolution mechanisms of bio-oil from conventional and nitrogen-rich biomass during photo-thermal pyrolysis," Energy, Elsevier, vol. 282(C).
    12. Zhenghui Xu & Xiang Xiao & Ping Fang & Lyumeng Ye & Jianhang Huang & Haiwen Wu & Zijun Tang & Dongyao Chen, 2020. "Comparison of Combustion and Pyrolysis Behavior of the Peanut Shells in Air and N 2 : Kinetics, Thermodynamics and Gas Emissions," Sustainability, MDPI, vol. 12(2), pages 1-14, January.
    13. Magdalena Matusiak & Radosław Ślęzak & Stanisław Ledakowicz, 2020. "Thermogravimetric Kinetics of Selected Energy Crops Pyrolysis," Energies, MDPI, vol. 13(15), pages 1-15, August.
    14. Gouws, S.M. & Carrier, M. & Bunt, J.R. & Neomagus, H.W.J.P., 2021. "Co-pyrolysis of coal and raw/torrefied biomass: A review on chemistry, kinetics and implementation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    15. Kim, Heeyoon & Yu, Seunghan & Ra, Howon & Yoon, Sungmin & Ryu, Changkook, 2023. "Prediction of pyrolysis kinetics for torrefied biomass based on raw biomass properties and torrefaction severity," Energy, Elsevier, vol. 278(C).
    16. Li, Longzhi & Cai, Dongqiang & Zhang, Lianjie & Zhang, Yue & Zhao, Zhiyang & Zhang, Zhonglei & Sun, Jifu & Tan, Yongdong & Zou, Guifu, 2023. "Synergistic effects during pyrolysis of binary mixtures of biomass components using microwave-assisted heating coupled with iron base tip-metal," Renewable Energy, Elsevier, vol. 203(C), pages 312-322.
    17. Bai, Xiaopeng & Wang, Guanghui & Zhu, Zheng & Cai, Chen & Wang, Zhiqin & Wang, Decheng, 2020. "Investigation of improving the yields and qualities of pyrolysis products with combination rod-milled and torrefaction pretreatment," Renewable Energy, Elsevier, vol. 151(C), pages 446-453.
    18. Francesco Miccio, 2022. "Thermoelectric Micro-Scale Generation by Carbonaceous Devices," Energies, MDPI, vol. 15(21), pages 1-10, October.
    19. Wen, Shaoting & Yan, Youping & Liu, Jingyong & Buyukada, Musa & Evrendilek, Fatih, 2019. "Pyrolysis performance, kinetic, thermodynamic, product and joint optimization analyses of incense sticks in N2 and CO2 atmospheres," Renewable Energy, Elsevier, vol. 141(C), pages 814-827.
    20. Wei Guo & Zhendong Wang & Youhong Sun & Xiaoshu Lü & Yuan Wang & Sunhua Deng & Qiang Li, 2020. "Effects of Packer Locations on Downhole Electric Heater Performance: Experimental Test and Economic Analysis," Energies, MDPI, vol. 13(2), pages 1-17, January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:153:y:2022:i:c:s1364032121010248. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.