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Effect of pyrolysis temperature on bamboo char combustion: Reactivity, kinetics and thermodynamics

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  • Tong, Wei
  • Cai, Zelong
  • Liu, Qingcai
  • Ren, Shan
  • Kong, Ming

Abstract

The combustion behavior of bamboo char (BC) under pyrolysis temperatures (673–1173 K) is studied by non-isothermal thermogravimetric analysis. Results show pyrolysis temperature lowers the ignition and burnout performance of biochar. The combustion reactivity firstly increases and then decreases, and BC-973 is the best. Kinetic models of Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose calculate the activation energy (E), integral master-plots method determines reaction equation is the reaction order that when the heating rate is less than 12 K/min, reaction orders firstly decrease and then increase with pyrolysis temperature, and reaction orders are around 1 for 24 K/min. Thermodynamic parameters (ΔH, ΔS and ΔG) are calculated, and the prediction equations about E, ΔH, ΔS and ΔG are proposed. Meanwhile, activation energy under first order reaction and experimental equation are compared, results show that average E values under first order reaction are greater in 773–973 K, and the rest of pyrolysis temperatures are adverse.

Suggested Citation

  • Tong, Wei & Cai, Zelong & Liu, Qingcai & Ren, Shan & Kong, Ming, 2020. "Effect of pyrolysis temperature on bamboo char combustion: Reactivity, kinetics and thermodynamics," Energy, Elsevier, vol. 211(C).
    • Handle: RePEc:eee:energy:v:211:y:2020:i:c:s0360544220318430
    DOI: 10.1016/j.energy.2020.118736
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    References listed on IDEAS

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    1. Wang, Guangwei & Zhang, Jianliang & Shao, Jiugang & Liu, Zhengjian & Wang, Haiyang & Li, Xinyu & Zhang, Pengcheng & Geng, Weiwei & Zhang, Guohua, 2016. "Experimental and modeling studies on CO2 gasification of biomass chars," Energy, Elsevier, vol. 114(C), pages 143-154.
    2. Qambrani, Naveed Ahmed & Rahman, Md. Mukhlesur & Won, Seunggun & Shim, Soomin & Ra, Changsix, 2017. "Biochar properties and eco-friendly applications for climate change mitigation, waste management, and wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 255-273.
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    1. Al-Rumaihi, Aisha & Shahbaz, Muhammad & Mckay, Gordon & Mackey, Hamish & Al-Ansari, Tareq, 2022. "A review of pyrolysis technologies and feedstock: A blending approach for plastic and biomass towards optimum biochar yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Zhang, Yuanbo & Zhang, Yutao & Li, Yaqing & Shi, Xueqiang & Che, Bo, 2022. "Determination of ignition temperature and kinetics and thermodynamics analysis of high-volatile coal based on differential derivative thermogravimetry," Energy, Elsevier, vol. 240(C).
    3. Cardarelli, Alessandro & Pinzi, Sara & Barbanera, Marco, 2022. "Effect of torrefaction temperature on spent coffee grounds thermal behaviour and kinetics," Renewable Energy, Elsevier, vol. 185(C), pages 704-716.
    4. Zhang, Zhiyi & Li, Yingkai & Luo, Laipeng & Yellezuome, Dominic & Rahman, Md Maksudur & Zou, Jianfeng & Hu, Hangli & Cai, Junmeng, 2023. "Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis," Renewable Energy, Elsevier, vol. 202(C), pages 154-171.

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