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Microwave assisted biodiesel production using sulfonic acid-functionalized metal-organic frameworks UiO-66 as a heterogeneous catalyst

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  • Gouda, Shiva Prasad
  • Ngaosuwan, Kanokwan
  • Assabumrungrat, Suttichai
  • Selvaraj, Manickam
  • Halder, Gopinath
  • Rokhum, Samuel Lalthazuala

Abstract

Room temperature sulfonated UiO-66 (UiO-66-SO3H) was demonstrated to be an excellent catalyst in conversion of oleic acid, a commonly used test substrate for biodiesel synthesis, to methyl oleate under microwave irradiation. Owing to the high sulfonic acid density (1.25 mmol g−1) and surface area (735 m2 g−1), the catalyst showed excellent conversion of oleic acid to methyl oleate at 98.30 ± 0.8% under the optimized reaction of methanol to oleic acid ratio of 20: 1, catalyst loading of 8 wt %, reaction temperature of 100 °C and reaction time of 1 h in microwave irradiation. The morphology and chemical composition of the UiO-66-SO3H catalyst were exhaustively characterized using XRD, XPS, BET, SEM and TGA. In addition, the synthesized methyl oleate was characterized by GC-MS, 1H and 13C NMR. The catalyst reusability was investigated up to 5 successive cycles affording a high 82.12 ± 0.6% conversion of oleic acid to methyl oleate on the 5th catalytic cycle.

Suggested Citation

  • Gouda, Shiva Prasad & Ngaosuwan, Kanokwan & Assabumrungrat, Suttichai & Selvaraj, Manickam & Halder, Gopinath & Rokhum, Samuel Lalthazuala, 2022. "Microwave assisted biodiesel production using sulfonic acid-functionalized metal-organic frameworks UiO-66 as a heterogeneous catalyst," Renewable Energy, Elsevier, vol. 197(C), pages 161-169.
    • Handle: RePEc:eee:renene:v:197:y:2022:i:c:p:161-169
    DOI: 10.1016/j.renene.2022.07.061
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    2. Yu, Dongmin & Duan, Chuanxu & Gu, Bing, 2023. "UiO-66-NH2@MnFe2O4 as a novel and retrievable MOF nanocatalyst for biodiesel synthesis from utilized edible oil in a microwave reactor: RSM design and CI engine studies," Renewable Energy, Elsevier, vol. 219(P1).
    3. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    4. Ming-Chien Hsiao & Peir-Horng Liao & Kuo-Chou Yang & Nguyen Vu Lan & Shuhn-Shyurng Hou, 2022. "Enhanced Biodiesel Synthesis via a Homogenizer-Assisted Two-Stage Conversion Process Using Waste Edible Oil as Feedstock," Energies, MDPI, vol. 15(23), pages 1-15, November.

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