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Acidic chitosan membrane as an efficient catalyst for biodiesel production from oleic acid

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  • Saengprachum, Nisakorn
  • Cai, Dongren
  • Li, Mantian
  • Li, Ling
  • Lin, Xiaocheng
  • Qiu, Ting

Abstract

Via the crosslinking of chitosan and sulfosuccinic acid (SSA), the acidic chitosan membrane (ACM) was prepared for biodiesel production from esterification of oleic acid and methanol. ATR-FTIR, TGA, XRD, SEM and EDX were applied to characterize the prepared ACM. The acidic site density and swelling capacity of the prepared ACM were investigated. The ACM possessed the 4.62 mmol/g of acidic site density, which was just a little less than 4.76 mmol/g of Amberlyst-15, meanwhile, ACM was proven to be much higher than Amberlyst-15 in swelling capacity. Under the same reaction, the 98.76% of conversion can be obtained while the Amberlyst-15 only reached 44.30%. The optimization of process variables was conducted by the combination of single factor experiment and Box-Behnken design (BBD) response surface methodology. The catalytic activity of ACM in different esterification of fatty acids and alcohols was also investigated. And the catalytic mechanism of esterification catalyzed by ACM was clarified. Based on the catalytic mechanism, the kinetic model was established to describe the esterification and obtain relevant kinetic parameters (Ea+, Ea−, A+ and A-), meanwhile, the kinetic results were compared to the same reaction with different catalysts in detail. Besides, the reusability of the prepared ACM was studied.

Suggested Citation

  • Saengprachum, Nisakorn & Cai, Dongren & Li, Mantian & Li, Ling & Lin, Xiaocheng & Qiu, Ting, 2019. "Acidic chitosan membrane as an efficient catalyst for biodiesel production from oleic acid," Renewable Energy, Elsevier, vol. 143(C), pages 1488-1499.
    • Handle: RePEc:eee:renene:v:143:y:2019:i:c:p:1488-1499
    DOI: 10.1016/j.renene.2019.05.101
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    References listed on IDEAS

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    1. Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field," Renewable Energy, Elsevier, vol. 34(3), pages 766-768.
    2. Wang, Yi-Tong & Yang, Xing-Xia & Xu, Jie & Wang, Hong-Li & Wang, Zi-Bing & Zhang, Lei & Wang, Shao-Long & Liang, Jing-Long, 2019. "Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst," Renewable Energy, Elsevier, vol. 139(C), pages 688-695.
    3. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
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    1. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    2. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    3. Cai, Dongren & Zhan, Guowu & Xiao, Jingran & Zhou, Shu-Feng & Qiu, Ting, 2021. "Design and synthesis of novel amphipathic ionic liquids for biodiesel production from soapberry oil," Renewable Energy, Elsevier, vol. 168(C), pages 779-790.

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