IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v158y2020icp91-102.html
   My bibliography  Save this article

Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production

Author

Listed:
  • Tang, Zo-Ee
  • Lim, Steven
  • Pang, Yean-Ling
  • Shuit, Siew-Hoong
  • Ong, Hwai-Chyuan

Abstract

This study evaluated the utilisation of biomass wastes as catalyst supports by comparing the catalytic performance of papaya seed, empty fruit bunch (EFB) and corncob biomass waste derived carbon based acid catalysts applied for biodiesel production through esterification reaction of palm fatty acid distillate (PFAD) and methanol. Arylation of 4-benzenediazonium sulfonate synthesis method was able to sulfonate the catalyst support efficiently. The activated carbon (AC) synthesised possessed high porosity with surface area ranged between 639.68 and 972.66 m2/g. The effect of catalyst synthesising condition including carbonisation temperature (600–1000 °C), sulfonation time (0.5–2.5 h) and sulfanilic acid to AC weight ratio (3:1–13:1) towards the FAME yield and free fatty acid (FFA) conversion were evaluated. At the optimum catalyst synthesis conditions, corncob waste derived sulfonated AC catalyst exhibited the highest FAME yield and FFA conversion of 72.09% and 93.49%, respectively. Reusability study showed that corncob waste derived sulfonated AC catalyst was able to achieve relatively high FAME yield at the first two reaction cycles. The esterification reaction followed the irreversible pseudo-homogeneous reaction model. The high catalytic efficiency of the catalyst had shown its high potential to fit into the cost-effective and sustainable framework for biodiesel production.

Suggested Citation

  • Tang, Zo-Ee & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Ong, Hwai-Chyuan, 2020. "Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 91-102.
    • Handle: RePEc:eee:renene:v:158:y:2020:i:c:p:91-102
    DOI: 10.1016/j.renene.2020.05.119
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120308235
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.05.119?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Xie, Haijiao, 2023. "Reduced surface sulphonic acid concentration Alleviates carbon-based solid acid catalysts deactivation in biodiesel production," Energy, Elsevier, vol. 271(C).
    2. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2023. "Fabrication of surface-modified dual waste-derived biochar for biodiesel production by microwave-assisted esterification of oleic acid: Optimization, kinetics, and mechanistic studies," Renewable Energy, Elsevier, vol. 218(C).
    3. Teimouri, Zahra & Abatzoglou, Nicolas & Dalai, Ajay K., 2023. "Design of a renewable catalyst support derived from biomass with optimized textural features for fischer tropsch synthesis," Renewable Energy, Elsevier, vol. 202(C), pages 1096-1109.
    4. Bingxin Zhang & Xiaona Wang & Weiqi Tang & Chuanfu Wu & Qunhui Wang & Xiaohong Sun, 2023. "Carbon-Based Solid Acid Catalyzed Esterification of Soybean Saponin-Acidified Oil with Methanol Vapor for Biodiesel Synthesis," Sustainability, MDPI, vol. 15(18), pages 1-15, September.
    5. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    6. Li, Hui & Wang, Junchi & Ma, Xiaoling & Wang, Yangyang & Li, Guoning & Guo, Min & Cui, Ping & Lu, Wanpeng & Zhou, Shoujun & Yu, Mingzhi, 2021. "Carbonized MIL−100(Fe) used as support for recyclable solid acid synthesis for biodiesel production," Renewable Energy, Elsevier, vol. 179(C), pages 1191-1203.
    7. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
    8. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    9. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2024. "Camellia sinensis leaf-assisted green synthesis of SO3H-functionalized ZnS/biochar nanocatalyst for highly selective solketal production and improved reusability in methylene blue dye adsorption," Renewable Energy, Elsevier, vol. 224(C).
    10. Saikia, Kankana & Das, Arpita & Sema, Atoholi H. & Basumatary, Sanjay & Shaemningwar Moyon, N. & Mathimani, Thangavel & Rokhum, Samuel Lalthazuala, 2024. "Response surface optimization, kinetics, thermodynamics, and life cycle cost analysis of biodiesel production from Jatropha curcas oil using biomass-based functional activated carbon catalyst," Renewable Energy, Elsevier, vol. 229(C).
    11. Leesing, Ratanaporn & Siwina, Siraprapha & Fiala, Khanittha, 2021. "Yeast-based biodiesel production using sulfonated carbon-based solid acid catalyst by an integrated biorefinery of durian peel waste," Renewable Energy, Elsevier, vol. 171(C), pages 647-657.
    12. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2024. "Azadirachta indica leaf extract-derived NiS@Functionalized biochar catalyst: Efficient acetalization and enhanced reusability in photodegradation of tinidazole," Renewable Energy, Elsevier, vol. 229(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Jinfan & Ao, Zhifeng & Wu, Hao & Zhang, Sufeng & Chi, Concong & Hou, Chen & Qian, Liwei, 2020. "Waste paper-derived magnetic carbon composite: A novel eco-friendly solid acid for the synthesis of n-butyl levulinate from furfuryl alcohol," Renewable Energy, Elsevier, vol. 146(C), pages 477-483.
    2. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    3. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Cheung, Siu Ming & Chen, Xiankun, 2023. "Esterification efficiency improvement of carbon-based solid acid catalysts induced by biomass pretreatments: Intrinsic mechanism," Energy, Elsevier, vol. 263(PB).
    4. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
    5. Bureros, Glorie Mae A. & Tanjay, April A. & Cuizon, Dan Elmer S. & Go, Alchris W. & Cabatingan, Luis K. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Cacao shell-derived solid acid catalyst for esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 138(C), pages 489-501.
    6. Mendaros, Czarina M. & Go, Alchris W. & Nietes, Winston Jose T. & Gollem, Babe Eden Joy O. & Cabatingan, Luis K., 2020. "Direct sulfonation of cacao shell to synthesize a solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 152(C), pages 320-330.
    7. Rocha, Pablo D. & Oliveira, Leandro S. & Franca, Adriana S., 2019. "Sulfonated activated carbon from corn cobs as heterogeneous catalysts for biodiesel production using microwave-assisted transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1710-1716.
    8. El yaakouby, Ichraq & Rhrissi, Ilyass & Abouliatim, Youness & Hlaibi, Miloudi & Kamil, Noureddine, 2023. "Moroccan sardine scales as a novel and renewable source of heterogeneous catalyst for biodiesel production using palm fatty acid distillate," Renewable Energy, Elsevier, vol. 217(C).
    9. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
    10. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    11. Sangar, Shatesh Kumar & Syazwani, Osman Nur & Farabi, M.S. Ahmad & Razali, S.M. & Shobhana, Gnanasekhar & Teo, Siow Hwa & Taufiq-Yap, Yun Hin, 2019. "Effective biodiesel synthesis from palm fatty acid distillate (PFAD) using carbon-based solid acid catalyst derived glycerol," Renewable Energy, Elsevier, vol. 142(C), pages 658-667.
    12. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.
    13. Ananya Satapathy & Kankana Saikia & Samuel Lalthazuala Rokhum, 2023. "Biodiesel Production Using a Banana Peel Extract-Mediated Highly Basic Heterogeneous Nanocatalyst," Sustainability, MDPI, vol. 15(14), pages 1-21, July.
    14. Thushari, Indika & Babel, Sandhya & Samart, Chanatip, 2019. "Biodiesel production in an autoclave reactor using waste palm oil and coconut coir husk derived catalyst," Renewable Energy, Elsevier, vol. 134(C), pages 125-134.
    15. Zailan, Zarifah & Tahir, Muhammad & Jusoh, Mazura & Zakaria, Zaki Yamani, 2021. "A review of sulfonic group bearing porous carbon catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 175(C), pages 430-452.
    16. Flores, Ken P. & Omega, Jan Laurence O. & Cabatingan, Luis K. & Go, Alchris W. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Simultaneously carbonized and sulfonated sugarcane bagasse as solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 130(C), pages 510-523.
    17. Quijote, Kristelle L. & Go, Alchris Woo & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Gunarto, Chintya & Zullaikah, Siti, 2023. "Non-isothermal in-situ (trans)esterification of lipids in pre-functionalized and lipid-dense post-hydrolysis spent coffee grounds with subcritical methanol at low subcritical condition," Renewable Energy, Elsevier, vol. 206(C), pages 111-124.
    18. Go, Alchris Woo & Quijote, Kristelle L. & Alivio, Roxanne Kathlyn O. & Ju, Yi-Hsu & Gunarto, Chintya & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Yuliana, Maria, 2022. "Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol," Renewable Energy, Elsevier, vol. 189(C), pages 13-24.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:158:y:2020:i:c:p:91-102. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.