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Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production

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  • Tang, Zo-Ee
  • Lim, Steven
  • Pang, Yean-Ling
  • Shuit, Siew-Hoong
  • Ong, Hwai-Chyuan

Abstract

This study evaluated the utilisation of biomass wastes as catalyst supports by comparing the catalytic performance of papaya seed, empty fruit bunch (EFB) and corncob biomass waste derived carbon based acid catalysts applied for biodiesel production through esterification reaction of palm fatty acid distillate (PFAD) and methanol. Arylation of 4-benzenediazonium sulfonate synthesis method was able to sulfonate the catalyst support efficiently. The activated carbon (AC) synthesised possessed high porosity with surface area ranged between 639.68 and 972.66 m2/g. The effect of catalyst synthesising condition including carbonisation temperature (600–1000 °C), sulfonation time (0.5–2.5 h) and sulfanilic acid to AC weight ratio (3:1–13:1) towards the FAME yield and free fatty acid (FFA) conversion were evaluated. At the optimum catalyst synthesis conditions, corncob waste derived sulfonated AC catalyst exhibited the highest FAME yield and FFA conversion of 72.09% and 93.49%, respectively. Reusability study showed that corncob waste derived sulfonated AC catalyst was able to achieve relatively high FAME yield at the first two reaction cycles. The esterification reaction followed the irreversible pseudo-homogeneous reaction model. The high catalytic efficiency of the catalyst had shown its high potential to fit into the cost-effective and sustainable framework for biodiesel production.

Suggested Citation

  • Tang, Zo-Ee & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Ong, Hwai-Chyuan, 2020. "Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 91-102.
    • Handle: RePEc:eee:renene:v:158:y:2020:i:c:p:91-102
    DOI: 10.1016/j.renene.2020.05.119
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    References listed on IDEAS

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    1. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
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    2. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
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    6. Bingxin Zhang & Xiaona Wang & Weiqi Tang & Chuanfu Wu & Qunhui Wang & Xiaohong Sun, 2023. "Carbon-Based Solid Acid Catalyzed Esterification of Soybean Saponin-Acidified Oil with Methanol Vapor for Biodiesel Synthesis," Sustainability, MDPI, vol. 15(18), pages 1-15, September.
    7. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    8. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2024. "Camellia sinensis leaf-assisted green synthesis of SO3H-functionalized ZnS/biochar nanocatalyst for highly selective solketal production and improved reusability in methylene blue dye adsorption," Renewable Energy, Elsevier, vol. 224(C).
    9. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    10. Leesing, Ratanaporn & Siwina, Siraprapha & Fiala, Khanittha, 2021. "Yeast-based biodiesel production using sulfonated carbon-based solid acid catalyst by an integrated biorefinery of durian peel waste," Renewable Energy, Elsevier, vol. 171(C), pages 647-657.

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