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Camellia sinensis leaf-assisted green synthesis of SO3H-functionalized ZnS/biochar nanocatalyst for highly selective solketal production and improved reusability in methylene blue dye adsorption

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  • Yadav, Nidhi
  • Yadav, Gaurav
  • Ahmaruzzaman, Md.

Abstract

This study reports the successful synthesis of an acid-functionalized ZnS/Biochar (ZBC-SO3H) nanocatalyst through a co-precipitation method utilizing Camellia sinensis leaf extract. The ZBC-SO3H nanocatalyst was employed for the microwave-assisted acetalization reaction of glycerol with acetone for selective solketal synthesis (biofuel derivative). Through systematic optimization of multiple reaction parameters, the most favorable conditions for solketal synthesis were identified. The ideal reaction conditions involved an 8:1 M ratio of acetone to glycerol (AC to GL), a 6 wt% catalyst loading, an 8-min reaction time, and a temperature of 60 °C. A significantly high surface area of 326.21 m2/g for the ZBC-SO3H nanocatalyst demonstrates its exceptional potential for catalytic applications. In addition, the plausible reaction pathway for selective solketal synthesis was suggested. The catalyst was reusable up to 6 reaction runs in the solketal synthesis, which remarks the high stability of the ZBC-SO3H. Further, the reusability of the ZBC-SO3H (remaining catalyst after 6 runs) was examined in the adsorption of methylene blue (MB) dye. This groundbreaking study showcases the exceptional performance of the ZBC-SO3H nanocatalyst in selective solketal production and its remarkable reusability in the adsorption of methylene blue dye. The outstanding results underscore the novelty and significance of this research endeavor.

Suggested Citation

  • Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2024. "Camellia sinensis leaf-assisted green synthesis of SO3H-functionalized ZnS/biochar nanocatalyst for highly selective solketal production and improved reusability in methylene blue dye adsorption," Renewable Energy, Elsevier, vol. 224(C).
    • Handle: RePEc:eee:renene:v:224:y:2024:i:c:s0960148124002416
    DOI: 10.1016/j.renene.2024.120176
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    1. Nanda, Malaya R. & Zhang, Yongsheng & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Xu, Chunbao (Charles), 2016. "Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1022-1031.
    2. Zailan, Zarifah & Tahir, Muhammad & Jusoh, Mazura & Zakaria, Zaki Yamani, 2021. "A review of sulfonic group bearing porous carbon catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 175(C), pages 430-452.
    3. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2023. "Fabrication of surface-modified dual waste-derived biochar for biodiesel production by microwave-assisted esterification of oleic acid: Optimization, kinetics, and mechanistic studies," Renewable Energy, Elsevier, vol. 218(C).
    4. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    5. Kumar, Komal & Pathak, Shailesh & Upadhyayula, Sreedevi, 2021. "Acetalization of 5-hydroxymethyl furfural into biofuel additive cyclic acetal using protic ionic liquid catalyst- A thermodynamic and kinetic analysis," Renewable Energy, Elsevier, vol. 167(C), pages 282-293.
    6. Aghbashlo, Mortaza & Tabatabaei, Meisam & Rastegari, Hajar & Ghaziaskar, Hassan S. & Roodbar Shojaei, Taha, 2018. "On the exergetic optimization of solketalacetin synthesis as a green fuel additive through ketalization of glycerol-derived monoacetin with acetone," Renewable Energy, Elsevier, vol. 126(C), pages 242-253.
    7. Samudrala, Shanthi Priya & Kandasamy, Shalini & Bhattacharya, Sankar, 2020. "One-pot synthesis of bio-fuel additives from glycerol and benzyl alcohol: Mesoporous MCM-41 supported iron (III) chloride as a highly efficient tandem catalyst," Renewable Energy, Elsevier, vol. 156(C), pages 883-892.
    8. Tang, Zo-Ee & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Ong, Hwai-Chyuan, 2020. "Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 91-102.
    9. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
    10. Vannucci, Julián A. & Gatti, Martín N. & Cardaci, Nicolas & Nichio, Nora N., 2022. "Economic feasibility of a solketal production process from glycerol at small industrial scale," Renewable Energy, Elsevier, vol. 190(C), pages 540-547.
    11. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    12. Ribeiro, Mariana B. & Cavalcante, Raquel M. & Young, André F., 2022. "Simulation and economic evaluation of fuel additives production from glycerol," Renewable Energy, Elsevier, vol. 181(C), pages 1081-1099.
    13. Li, Ronghe & Wei, Zhong & Li, Hongli & Yin, Zhili & Wang, Ziqing, 2022. "Selective esterification of glycerol with acetic acid to green fuel bio-additive over a lignosulfonate-based renewable solid acid," Renewable Energy, Elsevier, vol. 201(P2), pages 125-134.
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