IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v206y2023icp111-124.html
   My bibliography  Save this article

Non-isothermal in-situ (trans)esterification of lipids in pre-functionalized and lipid-dense post-hydrolysis spent coffee grounds with subcritical methanol at low subcritical condition

Author

Listed:
  • Quijote, Kristelle L.
  • Go, Alchris Woo
  • Angkawijaya, Artik Elisa
  • Santoso, Shella Permatasari
  • Gunarto, Chintya
  • Zullaikah, Siti

Abstract

Pre-functionalized lipid-dense post-hydrolyzed spent coffee grounds (PHSCG) were used as feedstock for fatty acid methyl ester (FAME) production. The lipids in PHSCG were converted to FAME via non-isothermal in-situ (trans)esterification (ISTE). The conversion was achieved with methanol under subcritical conditions. This study investigates the influence of reactor loading (RL), solvent-to-solid ratio (SSR), temperature, and holding time. High FAME yield of ∼21 g/100g PHSCG can be achieved in about 1 h. Both extractable and bound fatty acids (FA) were converted to FAME. The apparent conversion (∼107%) or yield may exceed the expected extractable FA when using pre-functionalized and lipid-dense PHSCG without needing an additional catalyst. Under favorable conditions of 85% RL, 6 mL/g SSR, and reacted non-isothermally to 125 °C (∼0.8 MPa), a minimum conversion of ∼98% could be achieved depending on the PHSCG's characteristics. The residual acid sites in the post-ISTE residues recovered after ISTE still exhibited catalytic activity when used as a catalyst during the esterification of oleic acid with methanol. The catalytic activity of the residues was evaluated by reusing them for up to 7 cycles. Elemental analysis and FT-IR peak identification supported the presence of sulfonic acid sites providing the catalytic activity of PHSCG and its residues.

Suggested Citation

  • Quijote, Kristelle L. & Go, Alchris Woo & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Gunarto, Chintya & Zullaikah, Siti, 2023. "Non-isothermal in-situ (trans)esterification of lipids in pre-functionalized and lipid-dense post-hydrolysis spent coffee grounds with subcritical methanol at low subcritical condition," Renewable Energy, Elsevier, vol. 206(C), pages 111-124.
    • Handle: RePEc:eee:renene:v:206:y:2023:i:c:p:111-124
    DOI: 10.1016/j.renene.2023.02.045
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123001891
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.02.045?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    2. Xiong, Yi-Wei & Go, Alchris Woo & Alivio, Roxanne Kathlyn O. & Santoso, Shella Permatasari & Angkawijaya, Artik Elisa & Soetaredjo, Felycia Edi & Agapay, Ramelito C., 2022. "Non-isothermal (trans)esterification of linoleic acid and soybean oil deodorizer distillate with methanol under subcritical conditions," Renewable Energy, Elsevier, vol. 197(C), pages 528-544.
    3. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Go, Alchris Woo & Quijote, Kristelle L. & Alivio, Roxanne Kathlyn O. & Ju, Yi-Hsu & Gunarto, Chintya & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Yuliana, Maria, 2022. "Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol," Renewable Energy, Elsevier, vol. 189(C), pages 13-24.
    2. Yang, Jinfan & Ao, Zhifeng & Wu, Hao & Zhang, Sufeng & Chi, Concong & Hou, Chen & Qian, Liwei, 2020. "Waste paper-derived magnetic carbon composite: A novel eco-friendly solid acid for the synthesis of n-butyl levulinate from furfuryl alcohol," Renewable Energy, Elsevier, vol. 146(C), pages 477-483.
    3. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    4. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
    5. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    6. Sulaiman Al Yahya & Tahir Iqbal & Muhammad Mubashar Omar & Munir Ahmad, 2021. "Techno-Economic Analysis of Fast Pyrolysis of Date Palm Waste for Adoption in Saudi Arabia," Energies, MDPI, vol. 14(19), pages 1-12, September.
    7. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    8. Sangar, Shatesh Kumar & Syazwani, Osman Nur & Farabi, M.S. Ahmad & Razali, S.M. & Shobhana, Gnanasekhar & Teo, Siow Hwa & Taufiq-Yap, Yun Hin, 2019. "Effective biodiesel synthesis from palm fatty acid distillate (PFAD) using carbon-based solid acid catalyst derived glycerol," Renewable Energy, Elsevier, vol. 142(C), pages 658-667.
    9. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Cheung, Siu Ming & Chen, Xiankun, 2023. "Esterification efficiency improvement of carbon-based solid acid catalysts induced by biomass pretreatments: Intrinsic mechanism," Energy, Elsevier, vol. 263(PB).
    10. Koytsoumpa, E.I. & Magiri – Skouloudi, D. & Karellas, S. & Kakaras, E., 2021. "Bioenergy with carbon capture and utilization: A review on the potential deployment towards a European circular bioeconomy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    11. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
    12. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.
    13. Nayak, Milap G. & Vyas, Amish P., 2019. "Optimization of microwave-assisted biodiesel production from Papaya oil using response surface methodology," Renewable Energy, Elsevier, vol. 138(C), pages 18-28.
    14. Bahadorian, Amirmahdi & Sadrameli, Seyed Mojtaba & Pahlavanzadeh, Hassan & Ilani Kashkouli, Mohammad Nabi, 2023. "Optimization study of linseed biodiesel production via in-situ transesterification and slow pyrolysis of obtained linseed residue," Renewable Energy, Elsevier, vol. 203(C), pages 10-19.
    15. Ananya Satapathy & Kankana Saikia & Samuel Lalthazuala Rokhum, 2023. "Biodiesel Production Using a Banana Peel Extract-Mediated Highly Basic Heterogeneous Nanocatalyst," Sustainability, MDPI, vol. 15(14), pages 1-21, July.
    16. Zimmerman, William B. & Kokoo, Rungrote, 2018. "Esterification for biodiesel production with a phantom catalyst: Bubble mediated reactive distillation," Applied Energy, Elsevier, vol. 221(C), pages 28-40.
    17. Bureros, Glorie Mae A. & Tanjay, April A. & Cuizon, Dan Elmer S. & Go, Alchris W. & Cabatingan, Luis K. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Cacao shell-derived solid acid catalyst for esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 138(C), pages 489-501.
    18. Felix, Charles & Ubando, Aristotle & Madrazo, Cynthia & Gue, Ivan Henderson & Sutanto, Sylviana & Tran-Nguyen, Phuong Lan & Go, Alchris Woo & Ju, Yi-Hsu & Culaba, Alvin & Chang, Jo-Shu & Chen, Wei-Hsi, 2019. "Non-catalytic in-situ (trans) esterification of lipids in wet microalgae Chlorella vulgaris under subcritical conditions for the synthesis of fatty acid methyl esters," Applied Energy, Elsevier, vol. 248(C), pages 526-537.
    19. Mendaros, Czarina M. & Go, Alchris W. & Nietes, Winston Jose T. & Gollem, Babe Eden Joy O. & Cabatingan, Luis K., 2020. "Direct sulfonation of cacao shell to synthesize a solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 152(C), pages 320-330.
    20. Te, Kezia Gaile D. & Go, Alchris Woo & Wang, Hanneh Jonna D. & Guevarra, Reinell G. & Cabatingan, Luis K. & Tabañag, Ian Dominic F. & Angkawijaya, Artik Elisa & Ju, Yi-Hsu, 2020. "Extraction of lipids from post-hydrolysis copra cake with hexane as solvent: Kinetic and equilibrium data," Renewable Energy, Elsevier, vol. 158(C), pages 311-323.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:206:y:2023:i:c:p:111-124. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.