IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v189y2022icp13-24.html
   My bibliography  Save this article

Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol

Author

Listed:
  • Go, Alchris Woo
  • Quijote, Kristelle L.
  • Alivio, Roxanne Kathlyn O.
  • Ju, Yi-Hsu
  • Gunarto, Chintya
  • Angkawijaya, Artik Elisa
  • Santoso, Shella Permatasari
  • Yuliana, Maria

Abstract

In-situ (trans)esterification (ISTE) of lipids in post-hydrolyzed rice bran (PHRB) with methanol under subcritical conditions has proven to be a suitable feedstock for fatty acid methyl ester (FAME) production. The lipids from PHRB had a fatty acid profile which was primarily composed of oleic (39 wt%) and linoleic (36 wt%) acids, and could potentially result in biodiesel with favorable properties. The PHRBs which were lipid-dense (31.35 and 48.98 wt% on a dry basis) and pre-functionalized (0.55 and 1.21 mmol H+/g dry and lipid-free PHRB), were successfully processed non-isothermally from 30 to 150 °C at high reactor loading of 85% and a solvent-to-solid ratio (SSR) of 4–6 mL/g dry PHRB, which resulted in yields of 26.48 and 35.11 g/100 g dry PHRB, equivalent to a conversion of ∼90% of the fatty acids. Due to the acquired acid sites in the collected PHRB, no additional catalyst was required. Elemental analysis and FT-IR spectroscopy were carried out to test the presence of sulfur and sulfonic sites in the PHRB residues. Furthermore, the recovered solids still exhibited substantial acid sites which were tested for activity through the esterification of oleic acid in methanol and were reused up to 7 cycles.

Suggested Citation

  • Go, Alchris Woo & Quijote, Kristelle L. & Alivio, Roxanne Kathlyn O. & Ju, Yi-Hsu & Gunarto, Chintya & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Yuliana, Maria, 2022. "Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol," Renewable Energy, Elsevier, vol. 189(C), pages 13-24.
    • Handle: RePEc:eee:renene:v:189:y:2022:i:c:p:13-24
    DOI: 10.1016/j.renene.2022.02.089
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122002385
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.02.089?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Masteri-Farahani, Majid & Hosseini, Mahdiyeh-Sadat & Forouzeshfar, Newsha, 2020. "Propyl-SO3H functionalized graphene oxide as multipurpose solid acid catalyst for biodiesel synthesis and acid-catalyzed esterification and acetalization reactions," Renewable Energy, Elsevier, vol. 151(C), pages 1092-1101.
    2. Flores, Ken P. & Omega, Jan Laurence O. & Cabatingan, Luis K. & Go, Alchris W. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Simultaneously carbonized and sulfonated sugarcane bagasse as solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 130(C), pages 510-523.
    3. Zullaikah, Siti & Rahkadima, Yulia T. & Ju, Yi-Hsu, 2017. "A non-catalytic in situ process to produce biodiesel from a rice milling by-product using a subcritical water-methanol mixture," Renewable Energy, Elsevier, vol. 111(C), pages 764-770.
    4. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    5. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Cheung, Siu Ming & Chen, Xiankun, 2023. "Esterification efficiency improvement of carbon-based solid acid catalysts induced by biomass pretreatments: Intrinsic mechanism," Energy, Elsevier, vol. 263(PB).
    2. Mendaros, Czarina M. & Go, Alchris W. & Nietes, Winston Jose T. & Gollem, Babe Eden Joy O. & Cabatingan, Luis K., 2020. "Direct sulfonation of cacao shell to synthesize a solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 152(C), pages 320-330.
    3. Rocha, Pablo D. & Oliveira, Leandro S. & Franca, Adriana S., 2019. "Sulfonated activated carbon from corn cobs as heterogeneous catalysts for biodiesel production using microwave-assisted transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1710-1716.
    4. Quijote, Kristelle L. & Go, Alchris Woo & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Gunarto, Chintya & Zullaikah, Siti, 2023. "Non-isothermal in-situ (trans)esterification of lipids in pre-functionalized and lipid-dense post-hydrolysis spent coffee grounds with subcritical methanol at low subcritical condition," Renewable Energy, Elsevier, vol. 206(C), pages 111-124.
    5. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Xie, Haijiao, 2023. "Reduced surface sulphonic acid concentration Alleviates carbon-based solid acid catalysts deactivation in biodiesel production," Energy, Elsevier, vol. 271(C).
    6. Yang, Jinfan & Ao, Zhifeng & Wu, Hao & Zhang, Sufeng & Chi, Concong & Hou, Chen & Qian, Liwei, 2020. "Waste paper-derived magnetic carbon composite: A novel eco-friendly solid acid for the synthesis of n-butyl levulinate from furfuryl alcohol," Renewable Energy, Elsevier, vol. 146(C), pages 477-483.
    7. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    8. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
    9. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    10. Lani, Nurul Saadiah & Ngadi, Norzita & Haron, Saharudin & Mohammed Inuwa, Ibrahim & Anako Opotu, Lawal, 2024. "The catalytic effect of calcium oxide and magnetite loading on magnetically supported calcium oxide-zeolite catalyst for biodiesel production from used cooking oil," Renewable Energy, Elsevier, vol. 222(C).
    11. Wang, Yi-Tong & Yang, Xing-Xia & Xu, Jie & Wang, Hong-Li & Wang, Zi-Bing & Zhang, Lei & Wang, Shao-Long & Liang, Jing-Long, 2019. "Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst," Renewable Energy, Elsevier, vol. 139(C), pages 688-695.
    12. Gouda, Shiva Prasad & Ngaosuwan, Kanokwan & Assabumrungrat, Suttichai & Selvaraj, Manickam & Halder, Gopinath & Rokhum, Samuel Lalthazuala, 2022. "Microwave assisted biodiesel production using sulfonic acid-functionalized metal-organic frameworks UiO-66 as a heterogeneous catalyst," Renewable Energy, Elsevier, vol. 197(C), pages 161-169.
    13. Khan, Ihtisham Wali & Naeem, Abdul & Farooq, Muhammad & Mahmood, Tahira & Ahmad, Bashir & Hamayun, Muhammad & Ahmad, Zahoor & Saeed, Tooba, 2020. "Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay," Renewable Energy, Elsevier, vol. 155(C), pages 181-188.
    14. Li, Hui & Wang, Junchi & Ma, Xiaoling & Wang, Yangyang & Li, Guoning & Guo, Min & Cui, Ping & Lu, Wanpeng & Zhou, Shoujun & Yu, Mingzhi, 2021. "Carbonized MIL−100(Fe) used as support for recyclable solid acid synthesis for biodiesel production," Renewable Energy, Elsevier, vol. 179(C), pages 1191-1203.
    15. Sulaiman Al Yahya & Tahir Iqbal & Muhammad Mubashar Omar & Munir Ahmad, 2021. "Techno-Economic Analysis of Fast Pyrolysis of Date Palm Waste for Adoption in Saudi Arabia," Energies, MDPI, vol. 14(19), pages 1-12, September.
    16. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    17. Sangar, Shatesh Kumar & Syazwani, Osman Nur & Farabi, M.S. Ahmad & Razali, S.M. & Shobhana, Gnanasekhar & Teo, Siow Hwa & Taufiq-Yap, Yun Hin, 2019. "Effective biodiesel synthesis from palm fatty acid distillate (PFAD) using carbon-based solid acid catalyst derived glycerol," Renewable Energy, Elsevier, vol. 142(C), pages 658-667.
    18. Koytsoumpa, E.I. & Magiri – Skouloudi, D. & Karellas, S. & Kakaras, E., 2021. "Bioenergy with carbon capture and utilization: A review on the potential deployment towards a European circular bioeconomy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    19. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
    20. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:189:y:2022:i:c:p:13-24. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.