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Novel Proton Exchange Membranes Based on Sulfonated Poly(acrylonitrile- co -glycidyl methacrylate)/Poly(vinyl chloride) Composite

Author

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  • Eman A. El Desouky

    (Textile Technology Program, Faculty of Industrial and Energy Technology, Borg EL-Alarb Technological University, New Borg El-Arab City 21934, Alexandria, Egypt
    Department of Chemistry, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • Emad A. Soliman

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-CITY), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Hessa H. Al-Rasheed

    (Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia)

  • Ayman El-Faham

    (Department of Chemistry, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • M. A. Abu-Saied

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-CITY), New Borg El-Arab City 21934, Alexandria, Egypt)

Abstract

In this study, novel proton exchange membranes (PEMs) based on a composite of sulfonated polyacrylonitrile (SPAN), sulfonated polyglycidyl methacrylate (SPGMA), or sulfonated poly(acrylonitrile-co-glycidyl methacrylate) (SP(AN- co -GMA))/polyvinyl chloride (PVC) were developed to be used for direct methanol fuel cells (DMFCs). After polymerization and sulfonation of the prepared polymers, the polyelectrolyte membranes were prepared by the casting and solvent evaporation technique for sulfonated homo- or co-polymers with polyvinyl chloride (PVC) composites. The resulting membranes were characterized by Fourier infrared and Raman spectral analyses, X-ray diffractometry, and scanning electron microscopy. The findings of this study reveal that both the thermal stability and ion exchange capacity of the composite membranes based on sulfonated copolymers were higher than that of their corresponding composites based on sulfonated homopolymers. In this context, the weight loss percentage of the prepared composite polyelectrolyte membranes did not exceed 12% of their initial weights. The IEC of all the composite membranes ranged from 0.18 to 0.48 meq/g. Thus, the IEC value increased with the increasing proportion of the glycidyl methacrylate comonomer. Moreover, the prepared PEMs based on SP(AN- co -GMA)/PVC composites showed lower methanol permeability (8.7 × 10 −7 cm 2 /s) than that of the Nafion membranes (3.39 × 10 −6 cm 2 /s). Therefore, these prepared PEMs are a good candidate for DMFCs applications.

Suggested Citation

  • Eman A. El Desouky & Emad A. Soliman & Hessa H. Al-Rasheed & Ayman El-Faham & M. A. Abu-Saied, 2023. "Novel Proton Exchange Membranes Based on Sulfonated Poly(acrylonitrile- co -glycidyl methacrylate)/Poly(vinyl chloride) Composite," Sustainability, MDPI, vol. 15(14), pages 1-24, July.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:14:p:11166-:d:1196309
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    References listed on IDEAS

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    1. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    2. Kai Song & Yu Lan & Xian Zhang & Jinhai Jiang & Chuanyu Sun & Guang Yang & Fengshuo Yang & Hao Lan, 2023. "A Review on Interoperability of Wireless Charging Systems for Electric Vehicles," Energies, MDPI, vol. 16(4), pages 1-22, February.
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