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Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production

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  • Gomes, João F.P.
  • Puna, Jaime F.B.
  • Gonçalves, Lissa M.
  • Bordado, João C.M.

Abstract

This paper, reports experimental work on the use of new heterogeneous solid basic catalysts for biodiesel production: double oxides of Mg and Al, produced by calcination, at high temperature, of MgAl lamellar structures, the hydrotalcites (HT). The most suitable catalyst system studied are hydrotalcite Mg:Al 2:1 calcinated at 507 °C and 700 °C, leading to higher values of FAME also in the second reaction stage. One of the prepared catalysts resulted in 97.1% Fatty acids methyl esters (FAME) in the 1st reaction step, 92.2% FAME in the 2nd reaction step and 34% FAME in the 3rd reaction step. The biodiesel obtained in the transesterification reaction showed composition and quality parameters within the limits specified by the European Standard EN 14214. 2.5% wt catalyst/oil and a molar ratio methanol:oil of 9:1 or 12:1 at 60–65 °C and 4 h of reaction time are the best operating conditions achieved in this study. This study showed the potential of Mg/Al hydrotalcites as heterogeneous catalysts for biodiesel production.

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  • Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:12:p:6770-6778
    DOI: 10.1016/j.energy.2011.10.024
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    1. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
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    13. Tesfa, B. & Mishra, R. & Zhang, C. & Gu, F. & Ball, A.D., 2013. "Combustion and performance characteristics of CI (compression ignition) engine running with biodiesel," Energy, Elsevier, vol. 51(C), pages 101-115.
    14. Aghbashlo, Mortaza & Hosseinpour, Soleiman & Tabatabaei, Meisam & Dadak, Ali, 2017. "Fuzzy modeling and optimization of the synthesis of biodiesel from waste cooking oil (WCO) by a low power, high frequency piezo-ultrasonic reactor," Energy, Elsevier, vol. 132(C), pages 65-78.
    15. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
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