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Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production

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  • Gomes, João F.P.
  • Puna, Jaime F.B.
  • Gonçalves, Lissa M.
  • Bordado, João C.M.

Abstract

This paper, reports experimental work on the use of new heterogeneous solid basic catalysts for biodiesel production: double oxides of Mg and Al, produced by calcination, at high temperature, of MgAl lamellar structures, the hydrotalcites (HT). The most suitable catalyst system studied are hydrotalcite Mg:Al 2:1 calcinated at 507 °C and 700 °C, leading to higher values of FAME also in the second reaction stage. One of the prepared catalysts resulted in 97.1% Fatty acids methyl esters (FAME) in the 1st reaction step, 92.2% FAME in the 2nd reaction step and 34% FAME in the 3rd reaction step. The biodiesel obtained in the transesterification reaction showed composition and quality parameters within the limits specified by the European Standard EN 14214. 2.5% wt catalyst/oil and a molar ratio methanol:oil of 9:1 or 12:1 at 60–65 °C and 4 h of reaction time are the best operating conditions achieved in this study. This study showed the potential of Mg/Al hydrotalcites as heterogeneous catalysts for biodiesel production.

Suggested Citation

  • Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:12:p:6770-6778
    DOI: 10.1016/j.energy.2011.10.024
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    1. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
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    7. Soares Dias, Ana Paula & Bernardo, Joana & Felizardo, Pedro & Neiva Correia, Maria Joana, 2012. "Biodiesel production over thermal activated cerium modified Mg-Al hydrotalcites," Energy, Elsevier, vol. 41(1), pages 344-353.
    8. Tesfa, B. & Mishra, R. & Zhang, C. & Gu, F. & Ball, A.D., 2013. "Combustion and performance characteristics of CI (compression ignition) engine running with biodiesel," Energy, Elsevier, vol. 51(C), pages 101-115.
    9. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    10. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    11. S. Ozkan & J. F. Puna & J. F. Gomes & T. Cabrita & J. V. Palmeira & M. T. Santos, 2019. "Preliminary Study on the Use of Biodiesel Obtained from Waste Vegetable Oils for Blending with Hydrotreated Kerosene Fossil Fuel Using Calcium Oxide (CaO) from Natural Waste Materials as Heterogeneous," Energies, MDPI, vol. 12(22), pages 1-19, November.
    12. Ko, Chun-Han & Yeh, Kai-Wun & Wang, Ya-Nang & Wu, Chien-Hou & Chang, Fang-Chih & Cheng, Ming-Hsun & Liou, Chia-Shin, 2012. "Impact of methanol addition strategy on enzymatic transesterification of jatropha oil for biodiesel processing," Energy, Elsevier, vol. 48(1), pages 375-379.
    13. Yan, Kai & Chen, Aicheng, 2013. "Efficient hydrogenation of biomass-derived furfural and levulinic acid on the facilely synthesized noble-metal-free Cu–Cr catalyst," Energy, Elsevier, vol. 58(C), pages 357-363.
    14. Frolich, Karel & Vávra, Aleš & Kocík, Jaroslav & Hájek, Martin & Jílková, Alena, 2019. "The long-term catalytic performance of mixed oxides in fixed-bed reactors in transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1259-1267.
    15. Aghbashlo, Mortaza & Hosseinpour, Soleiman & Tabatabaei, Meisam & Dadak, Ali, 2017. "Fuzzy modeling and optimization of the synthesis of biodiesel from waste cooking oil (WCO) by a low power, high frequency piezo-ultrasonic reactor," Energy, Elsevier, vol. 132(C), pages 65-78.
    16. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    17. Borah, Manash Jyoti & Devi, Anuchaya & Saikia, Raktim Abha & Deka, Dhanapati, 2018. "Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite," Energy, Elsevier, vol. 158(C), pages 881-889.

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