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Preparation and application of sodium borohydride composites for portable hydrogen production

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  • Chen, Y.
  • Kim, H.

Abstract

Novel composites consisting of cobalt–boron (CoB) catalyst and sodium borohydride (NaBH4) implantation in polymers (polyethylene glycol (PEG) or sodium alginate) were prepared for portable hydrogen production. The CoB catalyst was synthesized by the reduction of cobalt salt in NaBH4 solution followed by heat treatment in nitrogen atmosphere. The catalyst was embedded in PEG gel or alginate beads and NaBH4 was directly added in PEG–dimethylformamide (DMF) gel and adsorbed in alginate beads. It is noted that the composites prepared are stable in dry air and can be easily used for hydrogen production. A rate of hydrogen production of 750mlmin−1g−1 was reached when simply putting the composites into pure water. The humidified pure hydrogen can be used conveniently for fuel cells.

Suggested Citation

  • Chen, Y. & Kim, H., 2010. "Preparation and application of sodium borohydride composites for portable hydrogen production," Energy, Elsevier, vol. 35(2), pages 960-963.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:2:p:960-963
    DOI: 10.1016/j.energy.2009.06.053
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    References listed on IDEAS

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    1. Barelli, L. & Bidini, G. & Gallorini, F. & Servili, S., 2008. "Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review," Energy, Elsevier, vol. 33(4), pages 554-570.
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    1. Arthur, Ernest Evans & Li, Fang & Momade, Francis W.Y. & Kim, Hern, 2014. "Catalytic hydrolysis of ammonia borane for hydrogen generation using cobalt nanocluster catalyst supported on polydopamine functionalized multiwalled carbon nanotube," Energy, Elsevier, vol. 76(C), pages 822-829.
    2. Chinnappan, Amutha & Kang, Hyuck-Chul & Kim, Hern, 2011. "Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 36(2), pages 755-759.
    3. Amini-Manesh, Navid & Basu, Saptarshi & Kumar, Ranganathan, 2011. "Modeling of a reacting nanofilm on a composite substrate," Energy, Elsevier, vol. 36(3), pages 1688-1697.
    4. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    5. Kumar, Sandeep & Dhilip Kumar, T.J., 2020. "Hydrogen trapping potential of Ca decorated metal-graphyne framework," Energy, Elsevier, vol. 199(C).
    6. Oh, Taek Hyun & Gang, Byeong Gyu & Kim, Hyuntak & Kwon, Sejin, 2015. "Sodium borohydride hydrogen generator using Co–P/Ni foam catalysts for 200 W proton exchange membrane fuel cell system," Energy, Elsevier, vol. 90(P1), pages 1163-1170.
    7. Weng, Baicheng & Wu, Zhu & Li, Zhilin & Yang, Hui, 2012. "Hydrogen generation from hydrolysis of MNH2BH3 and NH3BH3/MH (M=Li, Na) for fuel cells based unmanned submarine vehicles application," Energy, Elsevier, vol. 38(1), pages 205-211.
    8. Ma, Li-Juan & Wang, Jianfeng & Han, Min & Jia, Jianfeng & Wu, Hai-Shun & Zhang, Xiang, 2019. "Adsorption of multiple H2 molecules on the complex TiC6H6: An unusual combination of chemisorption and physisorption," Energy, Elsevier, vol. 171(C), pages 315-325.
    9. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    10. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    11. Shen, Xiaochen & Wang, Qing & Wu, Qingquan & Guo, Siqi & Zhang, Zhengyan & Sun, Ziyang & Liu, Baishu & Wang, Zhibin & Zhao, Bin & Ding, Weiping, 2015. "CoB supported on Ag-activated TiO2 as a highly active catalyst for hydrolysis of alkaline NaBH4 solution," Energy, Elsevier, vol. 90(P1), pages 464-474.
    12. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    13. Li, Qiming & Chen, Yingbo & Lee, Dong Joo & Li, Fang & Kim, Hern, 2012. "Preparation of Y-zeolite/CoCl2 doped PVDF composite nanofiber and its application in hydrogen production," Energy, Elsevier, vol. 38(1), pages 144-150.
    14. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.

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    More about this item

    Keywords

    Composite; Catalyst; NaBH4; Hydrogen production; CoB;
    All these keywords.

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