IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v78y2014icp63-71.html
   My bibliography  Save this article

Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst

Author

Listed:
  • Teo, Siow Hwa
  • Islam, Aminul
  • Yusaf, Talal
  • Taufiq-Yap, Yun Hin

Abstract

Biodiesel is an environmental friendly liquid fuel similar to conventional diesel in combustion properties. It has received international attention in recent times, as that biodiesel is renewable, non-toxic and safe to store. In this study, high grade biodiesel was produced from microalgae (Nannochloropsis oculata) derived lipids via transesterification reaction with methanol in the presence of heterogeneous Ca(OCH3)2 (calcium methoxide) catalyst. The biodiesel was produced with high yield; (92%) at 60 °C compared to the highest yield reported as 22% with the use of a Mg–Zr catalyst. The product exhibited excellent performances. The catalyst was characterized by TG/DTA (thermogravimetric-differential thermal analyses), XRD (X-ray diffraction), BET (Brunauer – Emmett – Teller), FTIR (Fourier transform infrared), SEM-EDX (scanning electron microscopy-energy dispersive spectrometer) and TEM (transmission electron microscopy) analysis. The effect of different reaction parameters including reaction time, methanol/oil molar ratio and catalyst dosage on the yield of FAME (fatty acid methyl ester) was studied. Interestingly, the catalyst can be reused five times successively without affecting the biodiesel yield. Biodiesel produced from microalgae oil consists of high levels of polyunsaturated fatty acids, making it highly suitable as winter grade biodiesel.

Suggested Citation

  • Teo, Siow Hwa & Islam, Aminul & Yusaf, Talal & Taufiq-Yap, Yun Hin, 2014. "Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst," Energy, Elsevier, vol. 78(C), pages 63-71.
    • Handle: RePEc:eee:energy:v:78:y:2014:i:c:p:63-71
    DOI: 10.1016/j.energy.2014.07.045
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214008676
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.07.045?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    2. Yusaf, Talal & Al-Juboori, Raed A., 2014. "Alternative methods of microorganism disruption for agricultural applications," Applied Energy, Elsevier, vol. 114(C), pages 909-923.
    3. Mat Yasin, M.H. & Yusaf, Talal & Mamat, R. & Fitri Yusop, A., 2014. "Characterization of a diesel engine operating with a small proportion of methanol as a fuel additive in biodiesel blend," Applied Energy, Elsevier, vol. 114(C), pages 865-873.
    4. Islam, Aminul & Taufiq-Yap, Yun Hui & Chu, Chi-Ming & Ravindra, Pogaku & Chan, Eng-Seng, 2013. "Transesterification of palm oil using KF and NaNO3 catalysts supported on spherical millimetric γ-Al2O3," Renewable Energy, Elsevier, vol. 59(C), pages 23-29.
    5. Huang, GuanHua & Chen, Feng & Wei, Dong & Zhang, XueWu & Chen, Gu, 2010. "Biodiesel production by microalgal biotechnology," Applied Energy, Elsevier, vol. 87(1), pages 38-46, January.
    6. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gohain, Minakshi & Laskar, Khairujjaman & Paul, Atanu Kumar & Daimary, Niran & Maharana, Mrutyunjay & Goswami, Imon Kalyan & Hazarika, Anil & Bora, Utpal & Deka, Dhanapati, 2020. "Carica papaya stem: A source of versatile heterogeneous catalyst for biodiesel production and C–C bond formation," Renewable Energy, Elsevier, vol. 147(P1), pages 541-555.
    2. Guldhe, Abhishek & Moura, Carla V.R. & Singh, Poonam & Rawat, Ismail & Moura, Edmilson M. & Sharma, Yogesh & Bux, Faizal, 2017. "Conversion of microalgal lipids to biodiesel using chromium-aluminum mixed oxide as a heterogeneous solid acid catalyst," Renewable Energy, Elsevier, vol. 105(C), pages 175-182.
    3. Teo, Siow Hwa & Islam, Aminul & Mansir, Nasar & Shamsuddin, Mohd Razali & Joseph, Collin G. & Goto, Motonobu & Taufiq-Yap, Yun Hin, 2022. "Sustainable biofuel production approach: Critical methanol green transesterification by efficient and stable heterogeneous catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    4. Zhang, Xiaolei & Yan, Song & Tyagi, Rajeshwar Dayal & Drogui, Patrick & Surampalli, Rao Y., 2016. "Ultrasonication aided biodiesel production from one-step and two-step transesterification of sludge derived lipid," Energy, Elsevier, vol. 94(C), pages 401-408.
    5. Emilia Neag & Zamfira Stupar & S. Andrada Maicaneanu & Cecilia Roman, 2023. "Advances in Biodiesel Production from Microalgae," Energies, MDPI, vol. 16(3), pages 1-18, January.
    6. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    7. Ming-Chien Hsiao & Shuhn-Shyurng Hou & Jui-Yang Kuo & Pei-Hsuan Hsieh, 2018. "Optimized Conversion of Waste Cooking Oil to Biodiesel Using Calcium Methoxide as Catalyst under Homogenizer System Conditions," Energies, MDPI, vol. 11(10), pages 1-12, October.
    8. Ling, Jiayin & Nip, Saiwa & de Toledo, Renata Alves & Tian, Yuan & Shim, Hojae, 2016. "Evaluation of specific lipid production and nutrients removal from wastewater by Rhodosporidium toruloides and biodiesel production from wet biomass via microwave irradiation," Energy, Elsevier, vol. 108(C), pages 185-194.
    9. Singh, Poonam & Kumari, Sheena & Guldhe, Abhishek & Misra, Rohit & Rawat, Ismail & Bux, Faizal, 2016. "Trends and novel strategies for enhancing lipid accumulation and quality in microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1-16.
    10. Cuevas-Castillo, Gabriela A. & Navarro-Pineda, Freddy S. & Baz Rodríguez, Sergio A. & Sacramento Rivero, Julio C., 2020. "Advances on the processing of microalgal biomass for energy-driven biorefineries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 125(C).
    11. Niu, Shengli & Zhou, Yan & Li, Hui & Lu, Chunmei & Liu, Li, 2015. "An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation," Energy, Elsevier, vol. 89(C), pages 982-989.
    12. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    13. Ling, Jiayin & Tian, Yuan & de Toledo, Renata Alves & Shim, Hojae, 2017. "Cost reduction for the lipid production from distillery and domestic mixed wastewater by Rhodosporidium toruloides via the reutilization of spent seed culture medium," Energy, Elsevier, vol. 136(C), pages 135-141.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. S. M. Ashrafur Rahman & I. M. Rizwanul Fattah & Hwai Chyuan Ong & M. F. M. A. Zamri, 2021. "State-of-the-Art of Strategies to Reduce Exhaust Emissions from Diesel Engine Vehicles," Energies, MDPI, vol. 14(6), pages 1-24, March.
    2. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    3. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    4. Ling, Jiayin & Nip, Saiwa & de Toledo, Renata Alves & Tian, Yuan & Shim, Hojae, 2016. "Evaluation of specific lipid production and nutrients removal from wastewater by Rhodosporidium toruloides and biodiesel production from wet biomass via microwave irradiation," Energy, Elsevier, vol. 108(C), pages 185-194.
    5. Rahman, S.M. Ashrafur & Masjuki, H.H. & Kalam, M.A. & Abedin, M.J. & Sanjid, A. & Rahman, Md. Mofijur, 2014. "Assessing idling effects on a compression ignition engine fueled with Jatropha and Palm biodiesel blends," Renewable Energy, Elsevier, vol. 68(C), pages 644-650.
    6. Emine E Çakırca & Gizem N Tekin & Oğuzhan İlgen & Ayşe N Akın, 2019. "Catalytic activity of CaO-based catalyst in transesterification of microalgae oil with methanol," Energy & Environment, , vol. 30(1), pages 176-187, February.
    7. Behnam Tabatabai & Afua Adusei & Alok Kumar Shrivastava & Prashant Kumar Singh & Viji Sitther, 2020. "Nitrogen Deprivation in Fremyella diplosiphon Augments Lipid Production without Affecting Growth," Energies, MDPI, vol. 13(21), pages 1-12, November.
    8. Veiga, Paula Moraes & Luna, Aderval Severino & de Figueiredo Portilho, Marcio & de Oliveira Veloso, Cláudia & Henriques, Cristiane Assumpção, 2014. "Zn,Al-catalysts for heterogeneous biodiesel production: Basicity and process optimization," Energy, Elsevier, vol. 75(C), pages 453-462.
    9. Wu, Hong & Li, Yuanyuan & Chen, Lei & Zong, Minhua, 2011. "Production of microbial oil with high oleic acid content by Trichosporon capitatum," Applied Energy, Elsevier, vol. 88(1), pages 138-142, January.
    10. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    11. Yuanxing Huang & Shengnan Qin & Daofang Zhang & Liang Li & Yan Mu, 2016. "Evaluation of Cell Disruption of Chlorella Vulgaris by Pressure-Assisted Ozonation and Ultrasonication," Energies, MDPI, vol. 9(3), pages 1-11, March.
    12. Zhou, Yingdong & Chen, Yaguang & Li, Mingyu & Hu, Changwei, 2020. "Production of high-quality biofuel via ethanol liquefaction of pretreated natural microalgae," Renewable Energy, Elsevier, vol. 147(P1), pages 293-301.
    13. Yesilyurt, Murat Kadir & Eryilmaz, Tanzer & Arslan, Mevlüt, 2018. "A comparative analysis of the engine performance, exhaust emissions and combustion behaviors of a compression ignition engine fuelled with biodiesel/diesel/1-butanol (C4 alcohol) and biodiesel/diesel/," Energy, Elsevier, vol. 165(PB), pages 1332-1351.
    14. Patel, Akash & Gami, Bharat & Patel, Pankaj & Patel, Beena, 2017. "Microalgae: Antiquity to era of integrated technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 535-547.
    15. Jaiyen, Siyada & Naree, Thikumporn & Ngamcharussrivichai, Chawalit, 2015. "Comparative study of natural dolomitic rock and waste mixed seashells as heterogeneous catalysts for the methanolysis of palm oil to biodiesel," Renewable Energy, Elsevier, vol. 74(C), pages 433-440.
    16. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    17. Cremonez, Paulo André & Feroldi, Michael & de Araújo, Amanda Viana & Negreiros Borges, Maykon & Weiser Meier, Thompson & Feiden, Armin & Gustavo Teleken, Joel, 2015. "Biofuels in Brazilian aviation: Current scenario and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1063-1072.
    18. Awad, Omar I. & Ali, Obed M. & Mamat, Rizalman & Abdullah, A.A. & Najafi, G. & Kamarulzaman, M.K. & Yusri, I.M. & Noor, M.M., 2017. "Using fusel oil as a blend in gasoline to improve SI engine efficiencies: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 1232-1242.
    19. Ramachandran, K. & Suganya, T. & Nagendra Gandhi, N. & Renganathan, S., 2013. "Recent developments for biodiesel production by ultrasonic assist transesterification using different heterogeneous catalyst: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 410-418.
    20. Feng, Hongqing & Chen, Xiaofan & Sun, Liangliang & Ma, Ruixiu & Zhang, Xiuxia & Zhu, Lijun & Yang, Chaohe, 2023. "The effect of methanol/diesel fuel blends with co-solvent on diesel engine combustion based on experiment and exergy analysis," Energy, Elsevier, vol. 282(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:78:y:2014:i:c:p:63-71. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.