IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v81y2015icp501-510.html
   My bibliography  Save this article

Simulation of mass transfer in a passive direct methanol fuel cell cathode with perforated current collector

Author

Listed:
  • Xue, Yan Qing
  • Guo, Hang
  • Shang, Hui Hui
  • Ye, Fang
  • Ma, Chong Fang

Abstract

The current collector offers passages for mass transport and is one of the key components of the passive direct methanol fuel cell (DMFC). The effect of perforated current collector design on mass transport is studied based on a three-dimensional (3D), unsteady-state, two-phase mass transport model of a passive DMFC cathode. The model is implemented via the mixture multiphase model, which solves the continuity and momentum equations for the mixture and the volume fraction equation for the secondary phases. Numerical results indicate that the distributions of oxygen in both cathode catalyst layer (CCL) and cathode diffusion layer (CDL) are non-uniform because of the effect of the perforated current collector plate (CCP) structure. Liquid water produced by an electrochemical reaction in the CCL accumulates significantly at the bottom. Clearly, the distribution of liquid water in the cathode catalyst and diffusion layers is affected by gravity. The size of the circular holes and the distance between them are taken into account to investigate the effect of the CCP structure. Small uniformly arrayed circular holes in the entire active area of CCP are advantageous to the transfer of gas and liquid water in the cathode side of a passive DMFC.

Suggested Citation

  • Xue, Yan Qing & Guo, Hang & Shang, Hui Hui & Ye, Fang & Ma, Chong Fang, 2015. "Simulation of mass transfer in a passive direct methanol fuel cell cathode with perforated current collector," Energy, Elsevier, vol. 81(C), pages 501-510.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:501-510
    DOI: 10.1016/j.energy.2014.12.063
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214014418
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.12.063?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Tafaoli-Masoule, M. & Bahrami, A. & Elsayed, E.M., 2014. "Optimum design parameters and operating condition for maximum power of a direct methanol fuel cell using analytical model and genetic algorithm," Energy, Elsevier, vol. 70(C), pages 643-652.
    2. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    3. Wang, Luwen & Zhang, Yufeng & An, Zijian & Huang, Siteng & Zhou, Zhiping & Liu, Xiaowei, 2013. "Non-isothermal modeling of a small passive direct methanol fuel cell in vertical operation with anode natural convection effect," Energy, Elsevier, vol. 58(C), pages 283-295.
    4. Li, Xianglin & Faghri, Amir, 2011. "Local entropy generation analysis on passive high-concentration DMFCs (direct methanol fuel cell) with different cell structures," Energy, Elsevier, vol. 36(1), pages 403-414.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    2. Yuan, Zhenyu & Zhang, Manna & Zuo, Kaiyuan & Ren, Yongqiang, 2018. "The effect of gravity on inner transport and cell performance in passive micro direct methanol fuel cell," Energy, Elsevier, vol. 150(C), pages 28-37.
    3. Vasile, Nicolò S. & Doherty, Ronan & Monteverde Videla, Alessandro H.A. & Specchia, Stefania, 2016. "3D multi-physics modeling of a gas diffusion electrode for oxygen reduction reaction for electrochemical energy conversion in PEM fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 435-450.
    4. Chen, Xueye & Li, Tiechuan & Shen, Jienan & Hu, Zengliang, 2017. "From structures, packaging to application: A system-level review for micro direct methanol fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 669-678.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    2. Fang, Shuo & Zhang, Yufeng & Zou, Yuezhang & Sang, Shengtian & Liu, Xiaowei, 2017. "Structural design and analysis of a passive DMFC supplied with concentrated methanol solution," Energy, Elsevier, vol. 128(C), pages 50-61.
    3. Yuan, Zhenyu & Zhang, Manna & Zuo, Kaiyuan & Ren, Yongqiang, 2018. "The effect of gravity on inner transport and cell performance in passive micro direct methanol fuel cell," Energy, Elsevier, vol. 150(C), pages 28-37.
    4. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    5. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng, 2015. "A self-adaptive supply method of micro direct methanol fuel cell," Energy, Elsevier, vol. 91(C), pages 1064-1069.
    6. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng & Zhang, Xiwei, 2015. "The optimization of air-breathing micro direct methanol fuel cell using response surface method," Energy, Elsevier, vol. 80(C), pages 340-349.
    7. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Sang, Shengtian & Liu, Xiaowei, 2016. "Systemic modeling and analysis of DMFC stack for behavior prediction in system-level application," Energy, Elsevier, vol. 112(C), pages 1015-1023.
    8. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    9. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng & Wang, Shikai & Xu, Tingnian, 2015. "Mass transport optimization in the anode diffusion layer of a micro direct methanol fuel cell," Energy, Elsevier, vol. 93(P1), pages 599-605.
    10. Yang, Shipin & Chellali, Ryad & Lu, Xiaohua & Li, Lijuan & Bo, Cuimei, 2016. "Modeling and optimization for proton exchange membrane fuel cell stack using aging and challenging P systems based optimization algorithm," Energy, Elsevier, vol. 109(C), pages 569-577.
    11. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.
    12. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    13. Wang, Luwen & Yuan, Zhaoxia & Wen, Fei & Cheng, Yuhua & Zhang, Yufeng & Wang, Gaofeng, 2018. "A bipolar passive DMFC stack for portable applications," Energy, Elsevier, vol. 144(C), pages 587-593.
    14. Yuan, Zhenyu & Yang, Jie & Ye, Ning & Li, Zipeng & Sun, Yuge & Shen, Hongyuan, 2015. "Analysis of the capillary-force-based μDMFC (micro direct methanol fuel cell) supplied with pure methanol," Energy, Elsevier, vol. 89(C), pages 858-863.
    15. Yuan, Zhenyu & Fu, Wenting & Zhao, Yang & Li, Zipeng & Zhang, Yufeng & Liu, Xiaowei, 2013. "Investigation of μDMFC (micro direct methanol fuel cell) with self-adaptive flow rate," Energy, Elsevier, vol. 55(C), pages 1152-1158.
    16. Yuan, Zhenyu & Yang, Jie & Li, Zipeng & Sun, Yuge & Ye, Ning & Shen, Hongyuan, 2015. "Analysis of CO2 transmission in a micro direct methanol fuel cell," Energy, Elsevier, vol. 83(C), pages 496-502.
    17. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    18. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    19. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    20. Fofana, Daouda & Natarajan, Sadesh Kumar & Hamelin, Jean & Benard, Pierre, 2014. "Low platinum, high limiting current density of the PEMFC (proton exchange membrane fuel cell) based on multilayer cathode catalyst approach," Energy, Elsevier, vol. 64(C), pages 398-403.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:81:y:2015:i:c:p:501-510. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.