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Adsorption of carbon dioxide by sodium hydroxide-modified granular coconut shell activated carbon in a fixed bed

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  • Tan, Y.L.
  • Islam, Md. Azharul
  • Asif, M.
  • Hameed, B.H.

Abstract

In the present work, commercial coconut shell activated carbon was impregnated with alkaline NaOH to investigate the efficiency of modified activated carbon for CO2 adsorption in a fixed-bed column adsorption system. The modification parameters, such as the NaOH concentration (24–48%) and dwelling time (1–4 h), were also investigated. The results showed that a 32% NaOH concentration with a 3 h dwelling time provided the best CO2 adsorption capacity. Later, the modified activated carbon was characterized by nitrogen adsorption–desorption, scanning electron microscopy and Fourier transform infrared spectroscopy. The effects of the CO2 % in the feed, the adsorption temperature, the feed flow rate and the amount of adsorbent in the column were investigated in the adsorption experiments. The maximum CO2 adsorption capacity in this study was 27.10 mg/g at 35 °C. This study also suggests that NaOH-modified activated carbon is a state-of-the-art adsorbent for CO2 adsorption.

Suggested Citation

  • Tan, Y.L. & Islam, Md. Azharul & Asif, M. & Hameed, B.H., 2014. "Adsorption of carbon dioxide by sodium hydroxide-modified granular coconut shell activated carbon in a fixed bed," Energy, Elsevier, vol. 77(C), pages 926-931.
    • Handle: RePEc:eee:energy:v:77:y:2014:i:c:p:926-931
    DOI: 10.1016/j.energy.2014.09.079
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    2. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2017. "Reusable nitrogen-doped mesoporous carbon adsorbent for carbon dioxide adsorption in fixed-bed," Energy, Elsevier, vol. 138(C), pages 776-784.
    3. Ahad Ghaemi & Amir Hossein Behroozi, 2020. "Comparison of hydroxide‐based adsorbents of Mg(OH)2 and Ca(OH)2 for CO2 capture: utilization of response surface methodology, kinetic, and isotherm modeling," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(5), pages 948-964, October.
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    5. He Gao & Shaohua Wang & Miaomiao Hao & Wei Shao & Shuhui Zhang & Lei Zhang & Xiaohan Ren, 2023. "CO 2 Adsorption Performance of Activated Coke Prepared from Biomass and Coal," Energies, MDPI, vol. 16(9), pages 1-21, May.
    6. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2017. "Recent advances in functionalized composite solid materials for carbon dioxide capture," Energy, Elsevier, vol. 124(C), pages 461-480.

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