IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v97y2016icp238-245.html
   My bibliography  Save this article

Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization

Author

Listed:
  • Gao, Pin
  • Zhou, Yiyuan
  • Meng, Fang
  • Zhang, Yihui
  • Liu, Zhenhong
  • Zhang, Wenqi
  • Xue, Gang

Abstract

HTC (hydrothermal carbonization) is a technically-attractive thermal conversion process for biomass to produce solid carbonaceous products at mild conditions. EB (eucalyptus bark) was used as a feedstock for producing hydrochar by HTC. Effect of process conditions on the yield and physicochemical properties of hydrochar was examined by varying carbonization temperature over the range of 220–300 °C and varying residence time over the range of 2–10 h. With increase in temperature, the hydrochar yield decreased slightly from 46.4% at 220 °C to 40.0% at 300 °C. The O/C and H/C atomic ratios reduced from 1.69 and 0.80 to 0.83 and 0.23, respectively, which was mostly related to dehydration, decarboxylation and demethanation reactions. The oxygen containing functional groups decreased with increasing temperature. HHV (higher heating value) of hydrochar was in the range of 20.2–29.2 MJ/kg. Thermogravimetric analysis showed that hydrochar products obtained at temperature over 220 °C exhibited almost the same thermal behaviors. In comparison, the influence of residence time on the yield, physicochemical properties and thermal behavior of hydrochar was marginal.

Suggested Citation

  • Gao, Pin & Zhou, Yiyuan & Meng, Fang & Zhang, Yihui & Liu, Zhenhong & Zhang, Wenqi & Xue, Gang, 2016. "Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization," Energy, Elsevier, vol. 97(C), pages 238-245.
    • Handle: RePEc:eee:energy:v:97:y:2016:i:c:p:238-245
    DOI: 10.1016/j.energy.2015.12.123
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215017685
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.12.123?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gao, Ying & Wang, Xian-Hua & Yang, Hai-Ping & Chen, Han-Ping, 2012. "Characterization of products from hydrothermal treatments of cellulose," Energy, Elsevier, vol. 42(1), pages 457-465.
    2. Gao, Ying & Wang, Xianhua & Wang, Jun & Li, Xiangpeng & Cheng, Jianjun & Yang, Haiping & Chen, Hanping, 2013. "Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth," Energy, Elsevier, vol. 58(C), pages 376-383.
    3. Chen, Wei-Hsin & Kuo, Po-Chih, 2010. "A study on torrefaction of various biomass materials and its impact on lignocellulosic structure simulated by a thermogravimetry," Energy, Elsevier, vol. 35(6), pages 2580-2586.
    4. Rashidi, Nor Adilla & Yusup, Suzana & Hameed, Bassim H., 2013. "Kinetic studies on carbon dioxide capture using lignocellulosic based activated carbon," Energy, Elsevier, vol. 61(C), pages 440-446.
    5. He, Chao & Giannis, Apostolos & Wang, Jing-Yuan, 2013. "Conversion of sewage sludge to clean solid fuel using hydrothermal carbonization: Hydrochar fuel characteristics and combustion behavior," Applied Energy, Elsevier, vol. 111(C), pages 257-266.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Tengfei & Zhai, Yunbo & Zhu, Yun & Li, Caiting & Zeng, Guangming, 2018. "A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 223-247.
    2. Imtiaz Anando, Ahmed & Ehsan, M Monjurul & Karim, Md Rezwanul & Bhuiyan, Arafat A. & Ahiduzzaman, Md & Karim, Azharul, 2023. "Thermochemical pretreatments to improve the fuel properties of rice husk: A review," Renewable Energy, Elsevier, vol. 215(C).
    3. Tiago Teribele & Maria Elizabeth Gemaque Costa & Conceição de Maria Sales da Silva & Lia Martins Pereira & Lucas Pinto Bernar & Douglas Alberto Rocha de Castro & Fernanda Paula da Costa Assunção & Mar, 2023. "Hydrothermal Carbonization of Corn Stover: Structural Evolution of Hydro-Char and Degradation Kinetics," Energies, MDPI, vol. 16(7), pages 1-22, April.
    4. Ibrahim Shaba Mohammed & Risu Na & Keisuke Kushima & Naoto Shimizu, 2020. "Investigating the Effect of Processing Parameters on the Products of Hydrothermal Carbonization of Corn Stover," Sustainability, MDPI, vol. 12(12), pages 1-21, June.
    5. Siti Zaharah Roslan & Siti Fairuz Zainudin & Alijah Mohd Aris & Khor Bee Chin & Mohibah Musa & Ahmad Rafizan Mohamad Daud & Syed Shatir A. Syed Hassan, 2023. "Hydrothermal Carbonization of Sewage Sludge into Solid Biofuel: Influences of Process Conditions on the Energetic Properties of Hydrochar," Energies, MDPI, vol. 16(5), pages 1-16, March.
    6. Mau, Vivian & Gross, Amit, 2018. "Energy conversion and gas emissions from production and combustion of poultry-litter-derived hydrochar and biochar," Applied Energy, Elsevier, vol. 213(C), pages 510-519.
    7. Nepu Saha & Akbar Saba & Pretom Saha & Kyle McGaughy & Diana Franqui-Villanueva & William J. Orts & William M. Hart-Cooper & M. Toufiq Reza, 2019. "Hydrothermal Carbonization of Various Paper Mill Sludges: An Observation of Solid Fuel Properties," Energies, MDPI, vol. 12(5), pages 1-18, March.
    8. Wang, Guangwei & Zhang, Jianliang & Lee, Jui-Yuan & Mao, Xiaoming & Ye, Lian & Xu, Wanren & Ning, Xiaojun & Zhang, Nan & Teng, Haipeng & Wang, Chuan, 2020. "Hydrothermal carbonization of maize straw for hydrochar production and its injection for blast furnace," Applied Energy, Elsevier, vol. 266(C).
    9. Gao, Ying & Yu, Bo & Wang, Xianhua & Yuan, Qiaoxia & Yang, Haiping & Chen, Hanping & Zhang, Shihong, 2015. "Orthogonal test design to optimize products and to characterize heavy oil via biomass hydrothermal treatment," Energy, Elsevier, vol. 88(C), pages 139-148.
    10. Gao, Ying & Liu, Yinghui & Zhu, Guangkuo & Xu, Jiayu & xu, Hui & Yuan, Qiaoxia & Zhu, Yuezhao & Sarma, Jyotirmoy & Wang, Yinfeng & Wang, Jing & Ji, Lian, 2018. "Microwave-assisted hydrothermal carbonization of dairy manure: Chemical and structural properties of the products," Energy, Elsevier, vol. 165(PB), pages 662-672.
    11. Zhang, Chaoyue & Ma, Xiaoqian & Chen, Xinfei & Tian, Yunlong & Zhou, Yi & Lu, Xiaoluan & Huang, Tao, 2020. "Conversion of water hyacinth to value-added fuel via hydrothermal carbonization," Energy, Elsevier, vol. 197(C).
    12. Álvarez-Murillo, A. & Sabio, E. & Ledesma, B. & Román, S. & González-García, C.M., 2016. "Generation of biofuel from hydrothermal carbonization of cellulose. Kinetics modelling," Energy, Elsevier, vol. 94(C), pages 600-608.
    13. Ma, Peiyong & Yang, Jing & Xing, Xianjun & Weihrich, Sebastian & Fan, Fangyu & Zhang, Xianwen, 2017. "Isoconversional kinetics and characteristics of combustion on hydrothermally treated biomass," Renewable Energy, Elsevier, vol. 114(PB), pages 1069-1076.
    14. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba-Rec, Izabela & Szymańska-Chargot, Monika, 2020. "Upgrading of green waste into carbon-rich solid biofuel by hydrothermal carbonization: The effect of process parameters on hydrochar derived from acacia," Energy, Elsevier, vol. 202(C).
    15. Azzaz, Ahmed Amine & Khiari, Besma & Jellali, Salah & Ghimbeu, Camélia Matei & Jeguirim, Mejdi, 2020. "Hydrochars production, characterization and application for wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    16. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    17. Xiao, Zhihua & Yuan, Xingzhong & Jiang, Longbo & Chen, Xiaohong & Li, Hui & Zeng, Guangming & Leng, Lijian & Wang, Hou & Huang, Huajun, 2015. "Energy recovery and secondary pollutant emission from the combustion of co-pelletized fuel from municipal sewage sludge and wood sawdust," Energy, Elsevier, vol. 91(C), pages 441-450.
    18. Dilvin Cebi & Melih Soner Celiktas & Hasan Sarptas, 2022. "A Review on Sewage Sludge Valorization via Hydrothermal Carbonization and Applications for Circular Economy," Circular Economy and Sustainability, Springer, vol. 2(4), pages 1345-1367, December.
    19. Peng Liu & Panpan Lang & Ailing Lu & Yanling Li & Xueqin Li & Tanglei Sun & Yantao Yang & Hui Li & Tingzhou Lei, 2022. "Effect of Evolution of Carbon Structure during Torrefaction in Woody Biomass on Thermal Degradation," IJERPH, MDPI, vol. 19(24), pages 1-11, December.
    20. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:97:y:2016:i:c:p:238-245. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.