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Kinetic studies on carbon dioxide capture using lignocellulosic based activated carbon

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  • Rashidi, Nor Adilla
  • Yusup, Suzana
  • Hameed, Bassim H.

Abstract

CO2 (Carbon dioxide) emissions are one of the greenhouse gases that cause global warming. The power generation industry is one of the main emitters of CO2, and the emissions are expected to increase in the coming years as there seems to be no abatement in the consumption of fossil fuels for the production of electricity. Thus, there is a need for CO2 adsorption technologies to mitigate the emissions. However, there are several disadvantages associated with the current adsorption technologies. One of the issues is corrosion and the need for specialized equipment. Therefore, alternative and more sustainable materials are sought after to improve the viability of the adsorption technology. In this study, several types of agricultural wastes were used as activated carbon precursors for CO2 adsorption process in a TGA (thermogravimetric analyser). The adsorption was also modelled through a pseudo-first order and second order model, Elovich's kinetic model, and an intra-particle diffusion model. From the correlation coefficient, it was found that pseudo-second order model was well-fitted with the kinetic data. In addition, activation energy below than 42 kJ/mol confirmed that the physisorption process occurred.

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  • Rashidi, Nor Adilla & Yusup, Suzana & Hameed, Bassim H., 2013. "Kinetic studies on carbon dioxide capture using lignocellulosic based activated carbon," Energy, Elsevier, vol. 61(C), pages 440-446.
    • Handle: RePEc:eee:energy:v:61:y:2013:i:c:p:440-446
    DOI: 10.1016/j.energy.2013.08.050
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    Cited by:

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    2. Mulu, Elshaday & M'Arimi, Milton M. & Ramkat, Rose C., 2021. "A review of recent developments in application of low cost natural materials in purification and upgrade of biogas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Benedetti, Vittoria & Patuzzi, Francesco & Baratieri, Marco, 2018. "Characterization of char from biomass gasification and its similarities with activated carbon in adsorption applications," Applied Energy, Elsevier, vol. 227(C), pages 92-99.
    4. Huang, Yu-Fong & Chiueh, Pei-Te & Shih, Chun-Hao & Lo, Shang-Lien & Sun, Liping & Zhong, Yuan & Qiu, Chunsheng, 2015. "Microwave pyrolysis of rice straw to produce biochar as an adsorbent for CO2 capture," Energy, Elsevier, vol. 84(C), pages 75-82.
    5. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2015. "CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents," Applied Energy, Elsevier, vol. 140(C), pages 297-303.
    6. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    7. Gao, Pin & Zhou, Yiyuan & Meng, Fang & Zhang, Yihui & Liu, Zhenhong & Zhang, Wenqi & Xue, Gang, 2016. "Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization," Energy, Elsevier, vol. 97(C), pages 238-245.
    8. Vinod Kumar Singh & E. Anil Kumar, 2017. "Measurement of CO 2 adsorption kinetics on activated carbons suitable for gas storage systems," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(1), pages 182-201, February.
    9. Heo, Young-Jung & Park, Soo-Jin, 2015. "A role of steam activation on CO2 capture and separation of narrow microporous carbons produced from cellulose fibers," Energy, Elsevier, vol. 91(C), pages 142-150.

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    Keywords

    Activated carbon; Adsorption; CO2 capture;
    All these keywords.

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