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Thermal characterization of oil palm fiber and eucalyptus in torrefaction

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  • Chen, Wei-Hsin
  • Kuo, Po-Chih
  • Liu, Shih-Hsien
  • Wu, Wei

Abstract

Thermal behavior of biomass in torrefaction plays an important role in the operation of pretreatment. To understand the endothermic and/or exothermic characteristics of biomass in the course of torrefaction, an experimental system is conducted and two kinds of biomass (oil palm fiber and eucalyptus) are investigated. The results indicate that the thermal behavior is significantly influenced by the lignocellulosic composition in biomass and the torrefaction temperature. The thermal decomposition of hemicellulose is the dominant mechanism for oil palm fiber torrefied at 200 and 250 °C, whereas the thermal degradation of cellulose is crucial when the biomass is torrefied at 300 °C. Therefore, the heat of reaction of oil palm fiber increases with increasing torrefaction temperature. The torrefaction of eucalyptus is always endothermic, as a consequence of high cellulose contained in the biomass. It is less endothermic when the torrefaction temperature increases, presumably due to the char formation from cellulose thermal degradation and the exothermic lignin decomposition. As a whole, the values of the heat of reaction of the two samples are between −3.50 and 2.23 MJ/kg. The obtained results have provided a useful insight into the control of torrefaction operation and the design of torrefaction reactor.

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  • Chen, Wei-Hsin & Kuo, Po-Chih & Liu, Shih-Hsien & Wu, Wei, 2014. "Thermal characterization of oil palm fiber and eucalyptus in torrefaction," Energy, Elsevier, vol. 71(C), pages 40-48.
    • Handle: RePEc:eee:energy:v:71:y:2014:i:c:p:40-48
    DOI: 10.1016/j.energy.2014.03.117
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    1. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    2. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    3. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    4. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2006. "More efficient biomass gasification via torrefaction," Energy, Elsevier, vol. 31(15), pages 3458-3470.
    5. Pentananunt, Ranu & Rahman, A.N.M.Mizanur & Bhattacharya, S.C., 1990. "Upgrading of biomass by means of torrefaction," Energy, Elsevier, vol. 15(12), pages 1175-1179.
    6. Chen, Wei-Hsin & Hsu, Huan-Chun & Lu, Ke-Miao & Lee, Wen-Jhy & Lin, Ta-Chang, 2011. "Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass," Energy, Elsevier, vol. 36(5), pages 3012-3021.
    7. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Isothermal torrefaction kinetics of hemicellulose, cellulose, lignin and xylan using thermogravimetric analysis," Energy, Elsevier, vol. 36(11), pages 6451-6460.
    8. Chen, Wei-Hsin & Kuo, Po-Chih, 2010. "A study on torrefaction of various biomass materials and its impact on lignocellulosic structure simulated by a thermogravimetry," Energy, Elsevier, vol. 35(6), pages 2580-2586.
    9. Chen, Wei-Hsin & Lu, Ke-Miao & Tsai, Chi-Ming, 2012. "An experimental analysis on property and structure variations of agricultural wastes undergoing torrefaction," Applied Energy, Elsevier, vol. 100(C), pages 318-325.
    10. Li, Jun & Brzdekiewicz, Artur & Yang, Weihong & Blasiak, Wlodzimierz, 2012. "Co-firing based on biomass torrefaction in a pulverized coal boiler with aim of 100% fuel switching," Applied Energy, Elsevier, vol. 99(C), pages 344-354.
    11. Uslu, Ayla & Faaij, André P.C. & Bergman, P.C.A., 2008. "Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation," Energy, Elsevier, vol. 33(8), pages 1206-1223.
    12. Li, Hui & Liu, Xinhua & Legros, Robert & Bi, Xiaotao T. & Jim Lim, C. & Sokhansanj, Shahab, 2012. "Pelletization of torrefied sawdust and properties of torrefied pellets," Applied Energy, Elsevier, vol. 93(C), pages 680-685.
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