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Combination of acid washing and torrefaction on Co-production of syngas and phenoli-riched bio-oil via low-temperature catalytic pyrolysis

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  • Su, Yinhai
  • Zhang, Shuping
  • Liu, Lingqin
  • Xu, Dan
  • Qi, Penggang
  • Xiong, Yuanquan

Abstract

This study was targeted on investigating the facilitations of the combined pretreatment of acid washing and torrefaction on the co-production of syngas and phenols-rich bio-oil. Comparison of raw and modified samples indicated that combined pretreatments not only effectively removed the bulk of alkali and alkaline earth metals but also improved the fuel properties by decomposing unstable hemicellulose. Then, via the catalytic reforming of activated carbon catalyst, CO-rich syngas and phenols-rich bio-oil were obtained simultaneously. The optimal products was acquired from the acid-washed sample which torrefied at 240 °C (labeled as AT240). This syngas contained the maximal CO concentration of 61.86%, and its yield reached 174.34 mL/g. In bio-oil, relative content of phenolic compounds was 91.44%, in which the phenol occupied 71.72%. Quantitative analysis revealed the quantity of phenol in AT240 was 1.74 times of raw bio-oil. Furthermore, mechanism of combined pretreatment on catalytic co-production of syngas and phenols was proposed and discussed in this paper

Suggested Citation

  • Su, Yinhai & Zhang, Shuping & Liu, Lingqin & Xu, Dan & Qi, Penggang & Xiong, Yuanquan, 2020. "Combination of acid washing and torrefaction on Co-production of syngas and phenoli-riched bio-oil via low-temperature catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    • Handle: RePEc:eee:energy:v:210:y:2020:i:c:s0360544220317412
    DOI: 10.1016/j.energy.2020.118633
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    1. Safar, Michal & Lin, Bo-Jhih & Chen, Wei-Hsin & Langauer, David & Chang, Jo-Shu & Raclavska, H. & Pétrissans, Anélie & Rousset, Patrick & Pétrissans, Mathieu, 2019. "Catalytic effects of potassium on biomass pyrolysis, combustion and torrefaction," Applied Energy, Elsevier, vol. 235(C), pages 346-355.
    2. Chen, Wei & Fang, Yang & Li, Kaixu & Chen, Zhiqun & Xia, Mingwei & Gong, Meng & Chen, Yingquan & Yang, Haiping & Tu, Xin & Chen, Hanping, 2020. "Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products," Applied Energy, Elsevier, vol. 260(C).
    3. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    4. Yang, Zixu & Lei, Hanwu & Zhang, Yayun & Qian, Kezhen & Villota, Elmar & Qian, Moriko & Yadavalli, Gayatri & Sun, Hua, 2018. "Production of renewable alkyl-phenols from catalytic pyrolysis of Douglas fir sawdust over biomass-derived activated carbons," Applied Energy, Elsevier, vol. 220(C), pages 426-436.
    5. Wang, Wenliang & Li, Xinping & Ye, Dan & Cai, LiPing & Shi, Sheldon Q., 2018. "Catalytic pyrolysis of larch sawdust for phenol-rich bio-oil using different catalysts," Renewable Energy, Elsevier, vol. 121(C), pages 146-152.
    6. Chen, Wei-Hsin & Hsu, Huan-Chun & Lu, Ke-Miao & Lee, Wen-Jhy & Lin, Ta-Chang, 2011. "Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass," Energy, Elsevier, vol. 36(5), pages 3012-3021.
    7. Zhang, Shuping & Su, Yinhai & Xu, Dan & Zhu, Shuguang & Zhang, Houlei & Liu, Xinzhi, 2018. "Effects of torrefaction and organic-acid leaching pretreatment on the pyrolysis behavior of rice husk," Energy, Elsevier, vol. 149(C), pages 804-813.
    8. Wang, Shurong & Dai, Gongxin & Ru, Bin & Zhao, Yuan & Wang, Xiaoliu & Xiao, Gang & Luo, Zhongyang, 2017. "Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose," Energy, Elsevier, vol. 120(C), pages 864-871.
    9. Chen, Wei-Hsin & Kuo, Po-Chih & Liu, Shih-Hsien & Wu, Wei, 2014. "Thermal characterization of oil palm fiber and eucalyptus in torrefaction," Energy, Elsevier, vol. 71(C), pages 40-48.
    10. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    11. Chen, Yun-Chun & Chen, Wei-Hsin & Lin, Bo-Jhih & Chang, Jo-Shu & Ong, Hwai Chyuan, 2016. "Impact of torrefaction on the composition, structure and reactivity of a microalga residue," Applied Energy, Elsevier, vol. 181(C), pages 110-119.
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