IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v31y2006i12p1715-1725.html
   My bibliography  Save this article

CO2 capture from air and co-production of H2 via the Ca(OH)2–CaCO3 cycle using concentrated solar power–Thermodynamic analysis

Author

Listed:
  • Nikulshina, V.
  • Hirsch, D.
  • Mazzotti, M.
  • Steinfeld, A.

Abstract

The thermodynamics of a solar thermochemical cycle for the capture of CO2 from air are analyzed. The cycle encompasses 3 reactors: an aerosol-type carbonator for capturing CO2 from air using a spray of Ca(OH)2 aqueous solution, a solar calciner for thermally decomposing CaCO3 into CaO using concentrated solar energy, and a conventional slaker for regenerating Ca(OH)2. Two approaches are examined: (1) a closed-material cycle that delivers pure CO2; and (2) an open-material cycle that, additionally, co-produces hydrogen. The 2nd approach features the same components as those of the closed-material cycle, except that the calciner co-produces CaO and syngas by the combined CaCO3-decomposion and CH4-reforming processes, and syngas is further processed to separate streams of H2 and CO2. Its thermodynamic efficiency, defined as the ratio of ΔG298K∘|H2+0.5O2→H2O for the H2 produced to the thermal energy input (solar energy+heating value of CH4) is 22.7%. The solar chemical reactor technology for the calcination and for the combined calcination-reforming is presented.

Suggested Citation

  • Nikulshina, V. & Hirsch, D. & Mazzotti, M. & Steinfeld, A., 2006. "CO2 capture from air and co-production of H2 via the Ca(OH)2–CaCO3 cycle using concentrated solar power–Thermodynamic analysis," Energy, Elsevier, vol. 31(12), pages 1715-1725.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:12:p:1715-1725
    DOI: 10.1016/j.energy.2005.09.014
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544205001891
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2005.09.014?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Steinfeld, A. & Brack, M. & Meier, A. & Weidenkaff, A. & Wuillemin, D., 1998. "A solar chemical reactor for co-production of zinc and synthesis gas," Energy, Elsevier, vol. 23(10), pages 803-814.
    2. Steinfeld, A. & Thompson, G., 1994. "Solar combined thermochemical processes for CO2 mitigation in the iron, cement, and syngas industries," Energy, Elsevier, vol. 19(10), pages 1077-1081.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. André, Laurie & Abanades, Stéphane & Flamant, Gilles, 2016. "Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 703-715.
    2. Alvarez Rivero, M. & Rodrigues, D. & Pinheiro, C.I.C. & Cardoso, J.P. & Mendes, L.F., 2022. "Solid–gas reactors driven by concentrated solar energy with potential application to calcium looping: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    3. Renforth, P. & Jenkins, B.G. & Kruger, T., 2013. "Engineering challenges of ocean liming," Energy, Elsevier, vol. 60(C), pages 442-452.
    4. Azarabadi, Habib & Lackner, Klaus S., 2019. "A sorbent-focused techno-economic analysis of direct air capture," Applied Energy, Elsevier, vol. 250(C), pages 959-975.
    5. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Ni, Meng, 2009. "A review of biomass-derived fuel processors for fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1301-1313, August.
    6. Matthews, L. & Lipiński, W., 2012. "Thermodynamic analysis of solar thermochemical CO2 capture via carbonation/calcination cycle with heat recovery," Energy, Elsevier, vol. 45(1), pages 900-907.
    7. Krekel, Daniel & Samsun, Remzi Can & Peters, Ralf & Stolten, Detlef, 2018. "The separation of CO2 from ambient air – A techno-economic assessment," Applied Energy, Elsevier, vol. 218(C), pages 361-381.
    8. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    9. Sharma, Ajit & Lee, Byeong-Kyu, 2017. "Energy savings and reduction of CO2 emission using Ca(OH)2 incorporated zeolite as an additive for warm and hot mix asphalt production," Energy, Elsevier, vol. 136(C), pages 142-150.
    10. Liu, Yinan & Deng, Shuai & Zhao, Ruikai & He, Junnan & Zhao, Li, 2017. "Energy-saving pathway exploration of CCS integrated with solar energy: A review of innovative concepts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 652-669.
    11. Li, Canbing & Shi, Haiqing & Cao, Yijia & Kuang, Yonghong & Zhang, Yongjun & Gao, Dan & Sun, Liang, 2015. "Modeling and optimal operation of carbon capture from the air driven by intermittent and volatile wind power," Energy, Elsevier, vol. 87(C), pages 201-211.
    12. Li, Yingjie & Zhao, Changsui & Chen, Huichao & Ren, Qiangqiang & Duan, Lunbo, 2011. "CO2 capture efficiency and energy requirement analysis of power plant using modified calcium-based sorbent looping cycle," Energy, Elsevier, vol. 36(3), pages 1590-1598.
    13. Rahaman, Muhammad Syukri Abd & Cheng, Li-Hua & Xu, Xin-Hua & Zhang, Lin & Chen, Huan-Lin, 2011. "A review of carbon dioxide capture and utilization by membrane integrated microalgal cultivation processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4002-4012.
    14. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Halmann, M. & Frei, A. & Steinfeld, A., 2007. "Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation," Energy, Elsevier, vol. 32(12), pages 2420-2427.
    2. Sarker, M.R.I. & Mandal, Soumya & Tuly, Sumaiya Sadika, 2018. "Numerical study on the influence of vortex flow and recirculating flow into a solid particle solar receiver," Renewable Energy, Elsevier, vol. 129(PA), pages 409-418.
    3. Halmann, M. & Steinfeld, A., 2006. "Production of lime, hydrogen, and methanol by the thermo-neutral combined calcination of limestone with partial oxidation of natural gas or coal," Energy, Elsevier, vol. 31(10), pages 1533-1541.
    4. Cesare Caputo & Ondřej Mašek, 2021. "SPEAR (Solar Pyrolysis Energy Access Reactor): Theoretical Design and Evaluation of a Small-Scale Low-Cost Pyrolysis Unit for Implementation in Rural Communities," Energies, MDPI, vol. 14(8), pages 1-27, April.
    5. Epstein, Michael & Ehrensberger, Koebi & Yogev, Amnon, 2004. "Ferro-reduction of ZnO using concentrated solar energy," Energy, Elsevier, vol. 29(5), pages 745-756.
    6. Kräupl, Stefan & Wieckert, Christian, 2007. "Economic evaluation of the solar carbothermic reduction of ZnO by using a single sensitivity analysis and a Monte-Carlo risk analysis," Energy, Elsevier, vol. 32(7), pages 1134-1147.
    7. Palumbo, R. & Keunecke, M. & Möller, S. & Steinfeld, A., 2004. "Reflections on the design of solar thermal chemical reactors: thoughts in transformation," Energy, Elsevier, vol. 29(5), pages 727-744.
    8. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    9. Halmann, M. & Steinfeld, A., 2006. "Fuel saving, carbon dioxide emission avoidance, and syngas production by tri-reforming of flue gases from coal- and gas-fired power stations, and by the carbothermic reduction of iron oxide," Energy, Elsevier, vol. 31(15), pages 3171-3185.
    10. Cabeza, Luisa F. & Solé, Aran & Fontanet, Xavier & Barreneche, Camila & Jové, Aleix & Gallas, Manuel & Prieto, Cristina & Fernández, A. Inés, 2017. "Thermochemical energy storage by consecutive reactions for higher efficient concentrated solar power plants (CSP): Proof of concept," Applied Energy, Elsevier, vol. 185(P1), pages 836-845.
    11. Adrián García & Rut Sanchis & Francisco J. Llopis & Isabel Vázquez & María Pilar Pico & María Luisa López & Inmaculada Álvarez-Serrano & Benjamín Solsona, 2020. "Ni Supported on Natural Clays as a Catalyst for the Transformation of Levulinic Acid into γ-Valerolactone without the Addition of Molecular Hydrogen," Energies, MDPI, vol. 13(13), pages 1-19, July.
    12. Yadav, Deepak & Banerjee, Rangan, 2016. "A review of solar thermochemical processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 497-532.
    13. Halmann, M. & Frei, A. & Steinfeld, A., 2002. "Thermo-neutral production of metals and hydrogen or methanol by the combined reduction of the oxides of zinc or iron with partial oxidation of hydrocarbons," Energy, Elsevier, vol. 27(12), pages 1069-1084.
    14. Sarker, M.R.I. & Saha, Manabendra & Rahman, Md Sazan & Beg, R.A., 2016. "Recirculating metallic particles for the efficiency enhancement of concentrated solar receivers," Renewable Energy, Elsevier, vol. 96(PA), pages 850-862.
    15. Alvarez Rivero, M. & Rodrigues, D. & Pinheiro, C.I.C. & Cardoso, J.P. & Mendes, L.F., 2022. "Solid–gas reactors driven by concentrated solar energy with potential application to calcium looping: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    16. Kodama, T. & Shimizu, T. & Satoh, T. & Shimizu, K.-I., 2003. "Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst," Energy, Elsevier, vol. 28(11), pages 1055-1068.
    17. Wieckert, Christian & Palumbo, Robert & Frommherz, Ulrich, 2004. "A two-cavity reactor for solar chemical processes: heat transfer model and application to carbothermic reduction of ZnO," Energy, Elsevier, vol. 29(5), pages 771-787.
    18. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    19. Kodama, T & Ohtake, H & Matsumoto, S & Aoki, A & Shimizu, T & Kitayama, Y, 2000. "Thermochemical methane reforming using a reactive WO3/W redox system," Energy, Elsevier, vol. 25(5), pages 411-425.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:31:y:2006:i:12:p:1715-1725. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.