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Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst

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  • Kodama, T.
  • Shimizu, T.
  • Satoh, T.
  • Shimizu, K.-I.

Abstract

A two-step cyclic steam reforming of methane by a WO3/ZrO2 redox catalyst was performed to produce CO-rich syngas and hydrogen. The two-step cyclic processes could be repeated using a redox system of WO3 below 1273 K. The produced CO-rich syngas had the H2/CO ratios of about two, which was suitable for methanol production. This endothermic syngas-production process will be used as a solar thermochemical process for converting concentrated solar radiation to chemical liquid fuel of methanol in the sun-belt regions. The solar syngas-production process using the WO3/ZrO2 catalyst was demonstrated in a laboratory scale under direct irradiation of the catalyst by a solar-simulated, high-flux visible light.

Suggested Citation

  • Kodama, T. & Shimizu, T. & Satoh, T. & Shimizu, K.-I., 2003. "Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst," Energy, Elsevier, vol. 28(11), pages 1055-1068.
    • Handle: RePEc:eee:energy:v:28:y:2003:i:11:p:1055-1068
    DOI: 10.1016/S0360-5442(03)00093-8
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    References listed on IDEAS

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    1. Steinfeld, A. & Brack, M. & Meier, A. & Weidenkaff, A. & Wuillemin, D., 1998. "A solar chemical reactor for co-production of zinc and synthesis gas," Energy, Elsevier, vol. 23(10), pages 803-814.
    2. Kodama, T & Ohtake, H & Matsumoto, S & Aoki, A & Shimizu, T & Kitayama, Y, 2000. "Thermochemical methane reforming using a reactive WO3/W redox system," Energy, Elsevier, vol. 25(5), pages 411-425.
    3. Steinfeld, A. & Kuhn, P. & Karni, J., 1993. "High-temperature solar thermochemistry: Production of iron and synthesis gas by Fe3O4-reduction with methane," Energy, Elsevier, vol. 18(3), pages 239-249.
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    Cited by:

    1. LeValley, Trevor L. & Richard, Anthony R. & Fan, Maohong, 2015. "Development of catalysts for hydrogen production through the integration of steam reforming of methane and high temperature water gas shift," Energy, Elsevier, vol. 90(P1), pages 748-758.
    2. Rosha, Pali & Mohapatra, Saroj Kumar & Mahla, Sunil Kumar & Dhir, Amit, 2019. "Hydrogen enrichment of biogas via dry and autothermal-dry reforming with pure nickel (Ni) nanoparticle," Energy, Elsevier, vol. 172(C), pages 733-739.
    3. Habib, Mohamed A. & Salaudeen, Shakirudeen A. & Nemitallah, Medhat A. & Ben-Mansour, R. & Mokheimer, Esmail M.A., 2016. "Numerical investigation of syngas oxy-combustion inside a LSCF-6428 oxygen transport membrane reactor," Energy, Elsevier, vol. 96(C), pages 654-665.
    4. Zhao, Kun & He, Fang & Huang, Zhen & Wei, Guoqiang & Zheng, Anqing & Li, Haibin & Zhao, Zengli, 2016. "Perovskite-type oxides LaFe1−xCoxO3 for chemical looping steam methane reforming to syngas and hydrogen co-production," Applied Energy, Elsevier, vol. 168(C), pages 193-203.
    5. Lee, Jun Sung & Han, Gi Bo & Kang, Misook, 2012. "Low temperature steam reforming of ethanol for carbon monoxide-free hydrogen production over mesoporous Sn-incorporated SBA-15 catalysts," Energy, Elsevier, vol. 44(1), pages 248-256.
    6. Ma, Q. & Luo, L. & Wang, R.Z. & Sauce, G., 2009. "A review on transportation of heat energy over long distance: Exploratory development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1532-1540, August.

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