IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v28y2003i11p1055-1068.html
   My bibliography  Save this article

Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst

Author

Listed:
  • Kodama, T.
  • Shimizu, T.
  • Satoh, T.
  • Shimizu, K.-I.

Abstract

A two-step cyclic steam reforming of methane by a WO3/ZrO2 redox catalyst was performed to produce CO-rich syngas and hydrogen. The two-step cyclic processes could be repeated using a redox system of WO3 below 1273 K. The produced CO-rich syngas had the H2/CO ratios of about two, which was suitable for methanol production. This endothermic syngas-production process will be used as a solar thermochemical process for converting concentrated solar radiation to chemical liquid fuel of methanol in the sun-belt regions. The solar syngas-production process using the WO3/ZrO2 catalyst was demonstrated in a laboratory scale under direct irradiation of the catalyst by a solar-simulated, high-flux visible light.

Suggested Citation

  • Kodama, T. & Shimizu, T. & Satoh, T. & Shimizu, K.-I., 2003. "Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst," Energy, Elsevier, vol. 28(11), pages 1055-1068.
    • Handle: RePEc:eee:energy:v:28:y:2003:i:11:p:1055-1068
    DOI: 10.1016/S0360-5442(03)00093-8
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544203000938
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/S0360-5442(03)00093-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Steinfeld, A. & Brack, M. & Meier, A. & Weidenkaff, A. & Wuillemin, D., 1998. "A solar chemical reactor for co-production of zinc and synthesis gas," Energy, Elsevier, vol. 23(10), pages 803-814.
    2. Kodama, T & Ohtake, H & Matsumoto, S & Aoki, A & Shimizu, T & Kitayama, Y, 2000. "Thermochemical methane reforming using a reactive WO3/W redox system," Energy, Elsevier, vol. 25(5), pages 411-425.
    3. Steinfeld, A. & Kuhn, P. & Karni, J., 1993. "High-temperature solar thermochemistry: Production of iron and synthesis gas by Fe3O4-reduction with methane," Energy, Elsevier, vol. 18(3), pages 239-249.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. LeValley, Trevor L. & Richard, Anthony R. & Fan, Maohong, 2015. "Development of catalysts for hydrogen production through the integration of steam reforming of methane and high temperature water gas shift," Energy, Elsevier, vol. 90(P1), pages 748-758.
    2. Rosha, Pali & Mohapatra, Saroj Kumar & Mahla, Sunil Kumar & Dhir, Amit, 2019. "Hydrogen enrichment of biogas via dry and autothermal-dry reforming with pure nickel (Ni) nanoparticle," Energy, Elsevier, vol. 172(C), pages 733-739.
    3. Habib, Mohamed A. & Salaudeen, Shakirudeen A. & Nemitallah, Medhat A. & Ben-Mansour, R. & Mokheimer, Esmail M.A., 2016. "Numerical investigation of syngas oxy-combustion inside a LSCF-6428 oxygen transport membrane reactor," Energy, Elsevier, vol. 96(C), pages 654-665.
    4. Zhao, Kun & He, Fang & Huang, Zhen & Wei, Guoqiang & Zheng, Anqing & Li, Haibin & Zhao, Zengli, 2016. "Perovskite-type oxides LaFe1−xCoxO3 for chemical looping steam methane reforming to syngas and hydrogen co-production," Applied Energy, Elsevier, vol. 168(C), pages 193-203.
    5. Lee, Jun Sung & Han, Gi Bo & Kang, Misook, 2012. "Low temperature steam reforming of ethanol for carbon monoxide-free hydrogen production over mesoporous Sn-incorporated SBA-15 catalysts," Energy, Elsevier, vol. 44(1), pages 248-256.
    6. Ma, Q. & Luo, L. & Wang, R.Z. & Sauce, G., 2009. "A review on transportation of heat energy over long distance: Exploratory development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1532-1540, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Halmann, M. & Frei, A. & Steinfeld, A., 2007. "Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation," Energy, Elsevier, vol. 32(12), pages 2420-2427.
    2. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    3. Halmann, M. & Frei, A. & Steinfeld, A., 2002. "Thermo-neutral production of metals and hydrogen or methanol by the combined reduction of the oxides of zinc or iron with partial oxidation of hydrocarbons," Energy, Elsevier, vol. 27(12), pages 1069-1084.
    4. Kodama, T & Ohtake, H & Matsumoto, S & Aoki, A & Shimizu, T & Kitayama, Y, 2000. "Thermochemical methane reforming using a reactive WO3/W redox system," Energy, Elsevier, vol. 25(5), pages 411-425.
    5. Sarker, M.R.I. & Mandal, Soumya & Tuly, Sumaiya Sadika, 2018. "Numerical study on the influence of vortex flow and recirculating flow into a solid particle solar receiver," Renewable Energy, Elsevier, vol. 129(PA), pages 409-418.
    6. Chen, Wei-Hsin & Hsu, Chih-Liang & Du, Shan-Wen, 2015. "Thermodynamic analysis of the partial oxidation of coke oven gas for indirect reduction of iron oxides in a blast furnace," Energy, Elsevier, vol. 86(C), pages 758-771.
    7. Lu, Chunqiang & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Lei & Zheng, Min & Fan, Bingbing & He, Fang & Wang, Hua, 2020. "Improved activity of magnetite oxygen carrier for chemical looping steam reforming by ultrasonic treatment," Applied Energy, Elsevier, vol. 261(C).
    8. Liu, Xiangyu & Zhang, Hao & Hong, Hui & Jin, Hongguang, 2020. "Experimental study on honeycomb reactor using methane via chemical looping cycle for solar syngas," Applied Energy, Elsevier, vol. 268(C).
    9. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    10. Cabeza, Luisa F. & Solé, Aran & Fontanet, Xavier & Barreneche, Camila & Jové, Aleix & Gallas, Manuel & Prieto, Cristina & Fernández, A. Inés, 2017. "Thermochemical energy storage by consecutive reactions for higher efficient concentrated solar power plants (CSP): Proof of concept," Applied Energy, Elsevier, vol. 185(P1), pages 836-845.
    11. Zhang, Haotian & Sun, Zhuxing & Hu, Yun Hang, 2021. "Steam reforming of methane: Current states of catalyst design and process upgrading," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    12. Sarker, M.R.I. & Saha, Manabendra & Rahman, Md Sazan & Beg, R.A., 2016. "Recirculating metallic particles for the efficiency enhancement of concentrated solar receivers," Renewable Energy, Elsevier, vol. 96(PA), pages 850-862.
    13. Aoki, A. & Ohtake, H. & Shimizu, T. & Kitayama, Y. & Kodama, T., 2000. "Reactive metal-oxide redox system for a two-step thermochemical conversion of coal and water to CO and H2," Energy, Elsevier, vol. 25(3), pages 201-218.
    14. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    15. Shuai, Yong & Zhang, Hao & Guene Lougou, Bachirou & Jiang, Boshu & Mustafa, Azeem & Wang, Chi-Hwa & Wang, Fuqiang & Zhao, Jiupeng, 2021. "Solar-driven thermochemical redox cycles of ZrO2 supported NiFe2O4 for CO2 reduction into chemical energy," Energy, Elsevier, vol. 223(C).
    16. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.
    17. Nadgouda, Sourabh G. & Guo, Mengqing & Tong, Andrew & Fan, L.-S., 2019. "High purity syngas and hydrogen coproduction using copper-iron oxygen carriers in chemical looping reforming process," Applied Energy, Elsevier, vol. 235(C), pages 1415-1426.
    18. Cesare Caputo & Ondřej Mašek, 2021. "SPEAR (Solar Pyrolysis Energy Access Reactor): Theoretical Design and Evaluation of a Small-Scale Low-Cost Pyrolysis Unit for Implementation in Rural Communities," Energies, MDPI, vol. 14(8), pages 1-27, April.
    19. Epstein, Michael & Ehrensberger, Koebi & Yogev, Amnon, 2004. "Ferro-reduction of ZnO using concentrated solar energy," Energy, Elsevier, vol. 29(5), pages 745-756.
    20. Liu, Xiangyu & Hong, Hui & Zhang, Hao & Cao, Yali & Qu, Wanjun & Jin, Hongguang, 2020. "Solar methanol by hybridizing natural gas chemical looping reforming with solar heat," Applied Energy, Elsevier, vol. 277(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:28:y:2003:i:11:p:1055-1068. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.