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Production of lime, hydrogen, and methanol by the thermo-neutral combined calcination of limestone with partial oxidation of natural gas or coal

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  • Halmann, M.
  • Steinfeld, A.

Abstract

The cement and lime industries are major contributors to the anthropogenic CO2 emissions to the atmosphere. By combining the CO2-releasing calcination of CaCO3 with the CO2-consuming dry-reforming of CH4, and by further combining these endothermic reactions with the exothermic partial oxidation of CH4, a single thermo-neutral process can be designed for co-producing CaO and syngas in an authothermal reactor. Syngas can be further processed to H2, methanol, or Fischer–Tropsch chemicals. The conditions for thermo-neutrality are determined by thermo chemical equilibrium calculations. Such combined processes could achieve considerable CO2 emission avoidance as well as fuel saving relative to the conventional production of CaO and syngas. A preliminary evaluation indicates favorable economics for the co-production of CaO and hydrogen or methanol from CaCO3+O2+H2O and natural gas (NG) or coal.

Suggested Citation

  • Halmann, M. & Steinfeld, A., 2006. "Production of lime, hydrogen, and methanol by the thermo-neutral combined calcination of limestone with partial oxidation of natural gas or coal," Energy, Elsevier, vol. 31(10), pages 1533-1541.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:10:p:1533-1541
    DOI: 10.1016/j.energy.2005.05.012
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    References listed on IDEAS

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    1. Leites, I.L. & Sama, D.A. & Lior, N., 2003. "The theory and practice of energy saving in the chemical industry: some methods for reducing thermodynamic irreversibility in chemical technology processes," Energy, Elsevier, vol. 28(1), pages 55-97.
    2. Halmann, M. & Frei, A. & Steinfeld, A., 2002. "Thermo-neutral production of metals and hydrogen or methanol by the combined reduction of the oxides of zinc or iron with partial oxidation of hydrocarbons," Energy, Elsevier, vol. 27(12), pages 1069-1084.
    3. Steinfeld, A. & Thompson, G., 1994. "Solar combined thermochemical processes for CO2 mitigation in the iron, cement, and syngas industries," Energy, Elsevier, vol. 19(10), pages 1077-1081.
    4. Werder, Miriam & Steinfeld, Aldo, 2000. "Life cycle assessment of the conventional and solar thermal production of zinc and synthesis gas," Energy, Elsevier, vol. 25(5), pages 395-409.
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    Cited by:

    1. Zhang, Bo & Ji, Changwei & Wang, Shuofeng & Liu, Xiaolong, 2014. "Combustion and emissions characteristics of a spark-ignition engine fueled with hydrogen–methanol blends under lean and various loads conditions," Energy, Elsevier, vol. 74(C), pages 829-835.
    2. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    3. Su, Li-Wang & Li, Xiang-Rong & Sun, Zuo-Yu, 2013. "Flow chart of methanol in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 541-550.
    4. Halmann, M. & Frei, A. & Steinfeld, A., 2007. "Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation," Energy, Elsevier, vol. 32(12), pages 2420-2427.
    5. Su, Li-Wang & Li, Xiang-Rong & Sun, Zuo-Yu, 2013. "The consumption, production and transportation of methanol in China: A review," Energy Policy, Elsevier, vol. 63(C), pages 130-138.

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