IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v31y2006i10p1533-1541.html
   My bibliography  Save this article

Production of lime, hydrogen, and methanol by the thermo-neutral combined calcination of limestone with partial oxidation of natural gas or coal

Author

Listed:
  • Halmann, M.
  • Steinfeld, A.

Abstract

The cement and lime industries are major contributors to the anthropogenic CO2 emissions to the atmosphere. By combining the CO2-releasing calcination of CaCO3 with the CO2-consuming dry-reforming of CH4, and by further combining these endothermic reactions with the exothermic partial oxidation of CH4, a single thermo-neutral process can be designed for co-producing CaO and syngas in an authothermal reactor. Syngas can be further processed to H2, methanol, or Fischer–Tropsch chemicals. The conditions for thermo-neutrality are determined by thermo chemical equilibrium calculations. Such combined processes could achieve considerable CO2 emission avoidance as well as fuel saving relative to the conventional production of CaO and syngas. A preliminary evaluation indicates favorable economics for the co-production of CaO and hydrogen or methanol from CaCO3+O2+H2O and natural gas (NG) or coal.

Suggested Citation

  • Halmann, M. & Steinfeld, A., 2006. "Production of lime, hydrogen, and methanol by the thermo-neutral combined calcination of limestone with partial oxidation of natural gas or coal," Energy, Elsevier, vol. 31(10), pages 1533-1541.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:10:p:1533-1541
    DOI: 10.1016/j.energy.2005.05.012
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544205001271
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2005.05.012?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Leites, I.L. & Sama, D.A. & Lior, N., 2003. "The theory and practice of energy saving in the chemical industry: some methods for reducing thermodynamic irreversibility in chemical technology processes," Energy, Elsevier, vol. 28(1), pages 55-97.
    2. Halmann, M. & Frei, A. & Steinfeld, A., 2002. "Thermo-neutral production of metals and hydrogen or methanol by the combined reduction of the oxides of zinc or iron with partial oxidation of hydrocarbons," Energy, Elsevier, vol. 27(12), pages 1069-1084.
    3. Steinfeld, A. & Thompson, G., 1994. "Solar combined thermochemical processes for CO2 mitigation in the iron, cement, and syngas industries," Energy, Elsevier, vol. 19(10), pages 1077-1081.
    4. Werder, Miriam & Steinfeld, Aldo, 2000. "Life cycle assessment of the conventional and solar thermal production of zinc and synthesis gas," Energy, Elsevier, vol. 25(5), pages 395-409.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Bo & Ji, Changwei & Wang, Shuofeng & Liu, Xiaolong, 2014. "Combustion and emissions characteristics of a spark-ignition engine fueled with hydrogen–methanol blends under lean and various loads conditions," Energy, Elsevier, vol. 74(C), pages 829-835.
    2. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    3. Su, Li-Wang & Li, Xiang-Rong & Sun, Zuo-Yu, 2013. "Flow chart of methanol in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 541-550.
    4. Halmann, M. & Frei, A. & Steinfeld, A., 2007. "Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation," Energy, Elsevier, vol. 32(12), pages 2420-2427.
    5. Su, Li-Wang & Li, Xiang-Rong & Sun, Zuo-Yu, 2013. "The consumption, production and transportation of methanol in China: A review," Energy Policy, Elsevier, vol. 63(C), pages 130-138.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Halmann, M. & Steinfeld, A., 2006. "Fuel saving, carbon dioxide emission avoidance, and syngas production by tri-reforming of flue gases from coal- and gas-fired power stations, and by the carbothermic reduction of iron oxide," Energy, Elsevier, vol. 31(15), pages 3171-3185.
    2. Halmann, M. & Frei, A. & Steinfeld, A., 2007. "Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation," Energy, Elsevier, vol. 32(12), pages 2420-2427.
    3. Yadav, Deepak & Banerjee, Rangan, 2016. "A review of solar thermochemical processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 497-532.
    4. Toghyani, Mahboubeh & Rahimi, Amir, 2015. "Exergy analysis of an industrial unit of catalyst regeneration based on the results of modeling and simulation," Energy, Elsevier, vol. 91(C), pages 1049-1056.
    5. Hong, Gui-Bing & Ma, Chih-Ming & Chen, Hua-Wei & Chuang, Kai-Jen & Chang, Chang-Tang & Su, Te-Li, 2011. "Energy flow analysis in pulp and paper industry," Energy, Elsevier, vol. 36(5), pages 3063-3068.
    6. Yadav, Deepak & Banerjee, Rangan, 2022. "Thermodynamic and economic analysis of the solar carbothermal and hydrometallurgy routes for zinc production," Energy, Elsevier, vol. 247(C).
    7. Voicu-Teodor Muica & Alexandru Ozunu & Zoltàn Török, 2021. "Comparative Life Cycle Impact Assessment between the Productions of Zinc from Conventional Concentrates versus Waelz Oxides Obtained from Slags," Sustainability, MDPI, vol. 13(2), pages 1-17, January.
    8. Khoa, T.D. & Shuhaimi, M. & Hashim, H. & Panjeshahi, M.H., 2010. "Optimal design of distillation column using three dimensional exergy analysis curves," Energy, Elsevier, vol. 35(12), pages 5309-5319.
    9. Enrico Sciubba, 2014. "A Critical Interpretation and Quantitative Extension of the Sama-Szargut Second Law Rules in an Extended Exergy Perspective," Energies, MDPI, vol. 7(8), pages 1-17, August.
    10. Geuzebroek, F.H. & Schneiders, L.H.J.M. & Kraaijveld, G.J.C. & Feron, P.H.M., 2004. "Exergy analysis of alkanolamine-based CO2 removal unit with AspenPlus," Energy, Elsevier, vol. 29(9), pages 1241-1248.
    11. Flórez-Orrego, Daniel & de Oliveira Junior, Silvio, 2016. "On the efficiency, exergy costs and CO2 emission cost allocation for an integrated syngas and ammonia production plant," Energy, Elsevier, vol. 117(P2), pages 341-360.
    12. Ertesvåg, Ivar S. & Madejski, Paweł & Ziółkowski, Paweł & Mikielewicz, Dariusz, 2023. "Exergy analysis of a negative CO2 emission gas power plant based on water oxy-combustion of syngas from sewage sludge gasification and CCS," Energy, Elsevier, vol. 278(C).
    13. Ghannadzadeh, Ali & Thery-Hetreux, Raphaële & Baudouin, Olivier & Baudet, Philippe & Floquet, Pascal & Joulia, Xavier, 2012. "General methodology for exergy balance in ProSimPlus® process simulator," Energy, Elsevier, vol. 44(1), pages 38-59.
    14. Ertesvåg, Ivar S. & Kvamsdal, Hanne M. & Bolland, Olav, 2005. "Exergy analysis of a gas-turbine combined-cycle power plant with precombustion CO2 capture," Energy, Elsevier, vol. 30(1), pages 5-39.
    15. Sanjay,, 2011. "Investigation of effect of variation of cycle parameters on thermodynamic performance of gas-steam combined cycle," Energy, Elsevier, vol. 36(1), pages 157-167.
    16. Flórez-Orrego, Daniel & de Oliveira Junior, Silvio, 2017. "Modeling and optimization of an industrial ammonia synthesis unit: An exergy approach," Energy, Elsevier, vol. 137(C), pages 234-250.
    17. Halmann, M. & Frei, A. & Steinfeld, A., 2002. "Thermo-neutral production of metals and hydrogen or methanol by the combined reduction of the oxides of zinc or iron with partial oxidation of hydrocarbons," Energy, Elsevier, vol. 27(12), pages 1069-1084.
    18. Reddick, Christopher & Sorin, Mikhail & Rheault, Fernand, 2014. "Energy savings in CO2 (carbon dioxide) capture using ejectors for waste heat upgrading," Energy, Elsevier, vol. 65(C), pages 200-208.
    19. van der Ham, L.V. & Gross, J. & Kjelstrup, S., 2011. "Two performance indicators for the characterization of the entropy production in a process unit," Energy, Elsevier, vol. 36(6), pages 3727-3732.
    20. Chen, Shiyi & Lior, Noam & Xiang, Wenguo, 2015. "Coal gasification integration with solid oxide fuel cell and chemical looping combustion for high-efficiency power generation with inherent CO2 capture," Applied Energy, Elsevier, vol. 146(C), pages 298-312.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:31:y:2006:i:10:p:1533-1541. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.