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Novel Co3O4 decorated with rGO nanocatalyst to boost microwave-assisted biodiesel production and as nano-additive to enhance the performance-emission characteristics of diesel engine

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  • Maleki, Basir
  • Kalanakoppal Venkatesh, Yatish
  • Esmaeili, Hossein
  • Haddadi, Masoumeh
  • Mithun Prakash, Ravikumar
  • Balakrishna, Geetha R.

Abstract

In this study, a novel Co3O4 decorated with rGO nanocatalyst was utilized in synergy with microwave heating as a novel approach for the generation of biodiesel. In this process, 98.04 % biodiesel yield was achieved by adopting response surface methodology algorithm under MEOH/oil molar ratio of 12.75:1, Co3O4@rGO loading of 1.53 wt%, microwave time of 7.17 min, and stirring speed of 512 rpm. The catalyst can be reused for seven times with biodiesel yields beyond 85 %. Co3O4@rGO was used as a nano-additive in the diesel engine to investigate the emission and performance of biodiesel blended with diesel. The Co3O4@rGO nanoparticles were dispersed into the B20 fuel with concentrations of 50 and 100 ppm. The outcomes discovered that the brake thermal efficiency of B20Co3O4@rGO50 is 1.22 % greater than B20, and the brake specific fuel consumption is declined by 5.05 %. The emissions from the diesel engine i.e. CO (29.88 %) and UHC (16.38 %) were significantly lowered compared to B20. The emission of NOx for B20Co3O4@rGO100 is 7.4 % lower than B20 and greater than conventional petrodiesel. Owing to its remarkable stability, excellent biodiesel yield, effective utilization in diesel engine, and high catalytic activity, the Co3O4@rGO is strongly proposed for industrial biodiesel generation utilizing microwave radiation.

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  • Maleki, Basir & Kalanakoppal Venkatesh, Yatish & Esmaeili, Hossein & Haddadi, Masoumeh & Mithun Prakash, Ravikumar & Balakrishna, Geetha R., 2024. "Novel Co3O4 decorated with rGO nanocatalyst to boost microwave-assisted biodiesel production and as nano-additive to enhance the performance-emission characteristics of diesel engine," Energy, Elsevier, vol. 289(C).
    • Handle: RePEc:eee:energy:v:289:y:2024:i:c:s0360544223033388
    DOI: 10.1016/j.energy.2023.129944
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    References listed on IDEAS

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    1. Maleki, Basir & Ashraf Talesh, S. Siamak, 2024. "Sustainable biodiesel production from wild oak (Quercus brantii Lindl) oil as a novel and potential feedstock via highly efficient Co@CuO nanocatalyst: RSM optimization and CI engine assessment," Renewable Energy, Elsevier, vol. 224(C).
    2. Sannagoudar Basanagoudar, Arun & Maleki, Basir & Prakash Ravikumar, Mithun & Mounesh, & Kuppe, Pramoda & Kalanakoppal Venkatesh, Yatish, 2024. "Exploitation of Annona reticulata leaf extract for the synthesis of CeO2 nanoparticles as catalyst for the production of biodiesel using seed oil thereof," Energy, Elsevier, vol. 298(C).

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