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Oxidative fast pyrolysis of biomass in a quartz tube fluidized bed reactor: Effect of oxygen equivalence ratio

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  • Li, Bin
  • Song, Mengge
  • Xie, Xing
  • Wei, Juntao
  • Xu, Deliang
  • Ding, Kuan
  • Huang, Yong
  • Zhang, Shu
  • Hu, Xun
  • Zhang, Shihong
  • Liu, Dongjing

Abstract

The effect of oxygen equivalence ratio (ER) on oxidative fast pyrolysis of pine sawdust was investigated in a quartz tube fluidized bed reactor. The results showed that the introduction of oxygen into fluidizing gas would mainly oxidize the biochar, thus provided the largest contribution to heat demand during biomass pyrolysis towards autothermal operation. The increase of ER from 0 to 11.15% decreased the biochar yield from 21.03 to 9.5 wt%. The enthalpy for fast pyrolysis of pine sawdust was about 1084.49 kJ/kg, and a theoretical ER to achieve autothermal pyrolysis was thus calculated as ∼3.92%. The addition of oxygen indeed changed the formation and distribution of bio-oil. With ER of 6.47%, although the bio-oil yield decreased slightly, the light compounds in bio-oil (e.g., linear alcohols/carbonyls/acids, furan compounds and cyclopentanones/cyclohexanones) were largely consumed, while the heavy compounds (e.g., phenols/aromatic hydrocarbons and anhydrosugars) were mostly retained with the formation of anhydrosugars being promoted.

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  • Li, Bin & Song, Mengge & Xie, Xing & Wei, Juntao & Xu, Deliang & Ding, Kuan & Huang, Yong & Zhang, Shu & Hu, Xun & Zhang, Shihong & Liu, Dongjing, 2023. "Oxidative fast pyrolysis of biomass in a quartz tube fluidized bed reactor: Effect of oxygen equivalence ratio," Energy, Elsevier, vol. 270(C).
    • Handle: RePEc:eee:energy:v:270:y:2023:i:c:s036054422300381x
    DOI: 10.1016/j.energy.2023.126987
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    1. Li, Bin & Zhao, Lijun & Xie, Xing & Lin, Dan & Xu, Huibin & Wang, Shuang & Xu, Zhixiang & Wang, Junfeng & Huang, Yong & Zhang, Shu & Hu, Xun & Liu, Dongjing, 2021. "Volatile-char interactions during biomass pyrolysis: Effect of char preparation temperature," Energy, Elsevier, vol. 215(PB).
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    6. Magoua Mbeugang, Christian Fabrice & Li, Bin & Lin, Dan & Xie, Xing & Wang, Shuaijun & Wang, Shuang & Zhang, Shu & Huang, Yong & Liu, Dongjing & Wang, Qian, 2021. "Hydrogen rich syngas production from sorption enhanced gasification of cellulose in the presence of calcium oxide," Energy, Elsevier, vol. 228(C).
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    Cited by:

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    2. Muniyappan, Dineshkumar & Pereira Junior, Amaro Olimpio & M, Angkayarkan Vinayakaselvi & Ramanathan, Anand, 2023. "Synergistic recovery of renewable hydrocarbon resources via microwave co-pyrolysis of biomass residue and plastic waste over spent toner catalyst towards sustainable solid waste management," Energy, Elsevier, vol. 278(C).
    3. Muhammad Usman & Shuo Cheng & Sasipa Boonyubol & Jeffrey S. Cross, 2023. "Evaluating Green Solvents for Bio-Oil Extraction: Advancements, Challenges, and Future Perspectives," Energies, MDPI, vol. 16(15), pages 1-45, August.
    4. Li, Bin & Huang, Huimin & Xie, Xing & Wei, Juntao & Zhang, Shu & Hu, Xun & Zhang, Shihong & Liu, Dongjing, 2023. "Volatile-char interactions during biomass pyrolysis: Effects of AAEMs removal and KOH addition in char," Renewable Energy, Elsevier, vol. 219(P1).
    5. Leng, Lijian & Li, Tanghao & Zhan, Hao & Rizwan, Muhammad & Zhang, Weijin & Peng, Haoyi & Yang, Zequn & Li, Hailong, 2023. "Machine learning-aided prediction of nitrogen heterocycles in bio-oil from the pyrolysis of biomass," Energy, Elsevier, vol. 278(PB).
    6. Ran, Shuai & Zhang, Xin & Jiang, Yue & Gao, Ying & Xu, Hui & Yang, Hui Ying & Xu, Jiayu & Wang, Yuang & Guo, Yuan & Zhang, Hong & Lyu, Yinong, 2023. "Methods for enhancing the properties of products from food waste via hydrothermal carbonation (HTC): Gradient-enzymatic-pretreatment-nitrogen-migration-strategy," Energy, Elsevier, vol. 282(C).
    7. Kim, D. & Hadigheh, S.A., 2024. "Oxidative pyrolysis of biosolid: Air concentration effects on biochar formation and kinetics," Renewable Energy, Elsevier, vol. 224(C).

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