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Kinetic model and parameters study of lignocellulosic biomass oxidative pyrolysis

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  • Ding, Yanming
  • Huang, Biqing
  • Wu, Chuanbao
  • He, Qize
  • Lu, Kaihua

Abstract

The oxidative pyrolysis of lignocellulosic biomass was investigated based on thermogravimetric experiment compared with the purely non-oxidative pyrolysis. An updated oxidative kinetic model is proposed by importing three oxidative proportion parameters (λ1, λ2, λ3) for hemicellulose, cellulose and lignin as the direct extension of previous three-component parallel non-oxidative pyrolysis model. The total of extra 23 oxidative kinetic parameters was obtained by the Shuffled Complex Evolution method and they were applied to further predict the mass distribution of the above three main components. The predicted results proved the oxidative mechanism of biomass: the first stage is caused by the decomposition of hemicellulose and cellulose and partially decomposition of lignin, and the second stage is resulted from both the decomposition of the remaining lignin and char combustion.

Suggested Citation

  • Ding, Yanming & Huang, Biqing & Wu, Chuanbao & He, Qize & Lu, Kaihua, 2019. "Kinetic model and parameters study of lignocellulosic biomass oxidative pyrolysis," Energy, Elsevier, vol. 181(C), pages 11-17.
    • Handle: RePEc:eee:energy:v:181:y:2019:i:c:p:11-17
    DOI: 10.1016/j.energy.2019.05.148
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    References listed on IDEAS

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    Cited by:

    1. Xu, Li & Li, Shengcai & Sun, Wanghu & Ma, Xin & Cao, Shuchao, 2020. "Combustion behaviors and characteristic parameters determination of sassafras wood under different heating conditions," Energy, Elsevier, vol. 203(C).
    2. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    3. Mooktzeng Lim & Ee Sann Tan, 2023. "Techno-Economic Feasibility Study for Organic and Plastic Waste Pyrolysis Pilot Plant in Malaysia," Sustainability, MDPI, vol. 15(19), pages 1-16, September.
    4. Li, Bin & Song, Mengge & Xie, Xing & Wei, Juntao & Xu, Deliang & Ding, Kuan & Huang, Yong & Zhang, Shu & Hu, Xun & Zhang, Shihong & Liu, Dongjing, 2023. "Oxidative fast pyrolysis of biomass in a quartz tube fluidized bed reactor: Effect of oxygen equivalence ratio," Energy, Elsevier, vol. 270(C).
    5. Ding, Yanming & Huang, Biqing & Li, Kaiyuan & Du, Wenzhou & Lu, Kaihua & Zhang, Yansong, 2020. "Thermal interaction analysis of isolated hemicellulose and cellulose by kinetic parameters during biomass pyrolysis," Energy, Elsevier, vol. 195(C).
    6. Chen, Hao & Liu, Xiliang & Jia, Ninghong & Tian, Xiaofeng & Duncan, Ian & Yang, Ran & Yang, Shenglai, 2020. "The impact of the oil character and quartz sands on the thermal behavior and kinetics of crude oil," Energy, Elsevier, vol. 210(C).

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