IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v263y2023ipds0360544222028213.html
   My bibliography  Save this article

On the CAMD method based on PC-SAFT for working fluid design of a high-temperature organic Rankine cycle

Author

Listed:
  • Wang, Enhua
  • Mao, Jingwen
  • Zhang, Bo
  • Wang, Yongzhen

Abstract

Working fluid is of great importance on the performance of organic Rankine cycle (ORC). Novel working fluids can be designed based on the computer-aided molecular design (CAMD) method. In this study, a working fluid design approach using CAMD for a high-temperature ORC is investigated. First, the molecular structures of 129 working fluids are obtained. Then, the thermodynamic performances are determined using the group-contribution PC-SAFT and the results of the top 10 working fluids are analysed. Finally, the feasibility of three correlations for a quick selection of the working fluid is estimated and the relation between the PC-SAFT parameters and the ORC performance is discussed. The results indicate that a high prediction accuracy on the net power of ORC is achieved by PC-SAFT Equation of State with a deviation of less than 5%. However, certain deviations exist for the PC-SAFT parameters when the group contribution method is used. Meanwhile, the PC-SAFT parameters of the top 20 working fluids distribute in a large space and the conventional two-stage optimization algorithm may ignore some suboptimal working fluids. With regard to the high-temperature ORC for exhaust heat recovery, the designed top 5 working fluids are toluene, ethynyl cyclohexane, benzene, propenyl cyclopentane, vinyl cyclohexane. It is better to select the suitable working fluid from a candidate set containing the top 10–20 fluids such that the negative impact of the uncertainties originated from the group-contribution PC-SAFT method is avoided.

Suggested Citation

  • Wang, Enhua & Mao, Jingwen & Zhang, Bo & Wang, Yongzhen, 2023. "On the CAMD method based on PC-SAFT for working fluid design of a high-temperature organic Rankine cycle," Energy, Elsevier, vol. 263(PD).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pd:s0360544222028213
    DOI: 10.1016/j.energy.2022.125935
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222028213
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.125935?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Marshall, Z.M. & Duquette, J., 2022. "A techno-economic evaluation of low global warming potential heat pump assisted organic Rankine cycle systems for data center waste heat recovery," Energy, Elsevier, vol. 242(C).
    2. Lion, Simone & Michos, Constantine N. & Vlaskos, Ioannis & Rouaud, Cedric & Taccani, Rodolfo, 2017. "A review of waste heat recovery and Organic Rankine Cycles (ORC) in on-off highway vehicle Heavy Duty Diesel Engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 691-708.
    3. Scaccabarozzi, Roberto & Tavano, Michele & Invernizzi, Costante Mario & Martelli, Emanuele, 2018. "Comparison of working fluids and cycle optimization for heat recovery ORCs from large internal combustion engines," Energy, Elsevier, vol. 158(C), pages 396-416.
    4. Wang, Enhua & Zhang, Mengru & Meng, Fanxiao & Zhang, Hongguang, 2022. "Zeotropic working fluid selection for an organic Rankine cycle bottoming with a marine engine," Energy, Elsevier, vol. 243(C).
    5. Wei Zhao & Ning Xie & Wei Zhang & Jingpeng Yue & Lingbao Wang & Xianbiao Bu & Huashan Li, 2021. "Performance characteristics and working fluid selection for high-temperature organic Rankine cycle driven by solar parabolic trough collector [Categorization and analysis of heat sources for organi," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 16(4), pages 1135-1149.
    6. Zhang, Bo & Wang, Enhua & Meng, Fanxiao & Zhang, Fujun & Zhao, Changlu, 2020. "Prediction accuracy of thermodynamic properties using PC-SAFT for high-temperature organic Rankine cycle with siloxanes," Energy, Elsevier, vol. 204(C).
    7. Shu, Gequn & Li, Xiaoning & Tian, Hua & Liang, Xingyu & Wei, Haiqiao & Wang, Xu, 2014. "Alkanes as working fluids for high-temperature exhaust heat recovery of diesel engine using organic Rankine cycle," Applied Energy, Elsevier, vol. 119(C), pages 204-217.
    8. Yang, Fufang & Yang, Fubin & Liu, Qiang & Chu, Qingfu & Yang, Zhen & Duan, Yuanyuan, 2022. "Thermodynamic analysis of working fluids: What is the highest performance of the sub- and trans-critical organic Rankine cycles?," Energy, Elsevier, vol. 241(C).
    9. Uusitalo, Antti & Honkatukia, Juha & Turunen-Saaresti, Teemu, 2017. "Evaluation of a small-scale waste heat recovery organic Rankine cycle," Applied Energy, Elsevier, vol. 192(C), pages 146-158.
    10. Schilling, Johannes & Eichler, Katharina & Kölsch, Benedikt & Pischinger, Stefan & Bardow, André, 2019. "Integrated design of working fluid and organic Rankine cycle utilizing transient exhaust gases of heavy-duty vehicles," Applied Energy, Elsevier, vol. 255(C).
    11. Pili, Roberto & Bojer Jørgensen, Søren & Haglind, Fredrik, 2022. "Multi-objective optimization of organic Rankine cycle systems considering their dynamic performance," Energy, Elsevier, vol. 246(C).
    12. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    13. Cignitti, Stefano & Andreasen, Jesper G. & Haglind, Fredrik & Woodley, John M. & Abildskov, Jens, 2017. "Integrated working fluid-thermodynamic cycle design of organic Rankine cycle power systems for waste heat recovery," Applied Energy, Elsevier, vol. 203(C), pages 442-453.
    14. Zinsalo, Joël M. & Lamarche, Louis & Raymond, Jasmin, 2022. "Performance analysis and working fluid selection of an Organic Rankine Cycle Power Plant coupled to an Enhanced Geothermal System," Energy, Elsevier, vol. 245(C).
    15. Lukawski, Maciej Z. & DiPippo, Ronald & Tester, Jefferson W., 2018. "Molecular property methods for assessing efficiency of organic Rankine cycles," Energy, Elsevier, vol. 142(C), pages 108-120.
    16. Liu, Wei & Meinel, Dominik & Wieland, Christoph & Spliethoff, Hartmut, 2014. "Investigation of hydrofluoroolefins as potential working fluids in organic Rankine cycle for geothermal power generation," Energy, Elsevier, vol. 67(C), pages 106-116.
    17. Schilling, J. & Entrup, M. & Hopp, M. & Gross, J. & Bardow, A., 2021. "Towards optimal mixtures of working fluids: Integrated design of processes and mixtures for Organic Rankine Cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    18. Xu, Jinliang & Yu, Chao, 2014. "Critical temperature criterion for selection of working fluids for subcritical pressure Organic Rankine cycles," Energy, Elsevier, vol. 74(C), pages 719-733.
    19. Vivian, Jacopo & Manente, Giovanni & Lazzaretto, Andrea, 2015. "A general framework to select working fluid and configuration of ORCs for low-to-medium temperature heat sources," Applied Energy, Elsevier, vol. 156(C), pages 727-746.
    20. van Kleef, Luuk M.T. & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2019. "Multi-objective thermo-economic optimization of organic Rankine cycle (ORC) power systems in waste-heat recovery applications using computer-aided molecular design techniques," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    21. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    22. Siddiqi, M. Aslam & Atakan, Burak, 2012. "Alkanes as fluids in Rankine cycles in comparison to water, benzene and toluene," Energy, Elsevier, vol. 45(1), pages 256-263.
    23. Nami, Hossein & Ertesvåg, Ivar S. & Agromayor, Roberto & Riboldi, Luca & Nord, Lars O., 2018. "Gas turbine exhaust gas heat recovery by organic Rankine cycles (ORC) for offshore combined heat and power applications - Energy and exergy analysis," Energy, Elsevier, vol. 165(PB), pages 1060-1071.
    24. Yamada, Noboru & Mohamad, Md Nor Anuar & Kien, Trinh Trung, 2012. "Study on thermal efficiency of low- to medium-temperature organic Rankine cycles using HFO−1234yf," Renewable Energy, Elsevier, vol. 41(C), pages 368-375.
    25. Martin T. White & Abdulnaser I. Sayma, 2018. "A Generalised Assessment of Working Fluids and Radial Turbines for Non-Recuperated Subcritical Organic Rankine Cycles," Energies, MDPI, vol. 11(4), pages 1-26, March.
    26. Liang, Zheng & Liang, Yingzong & Luo, Xianglong & Chen, Jianyong & Yang, Zhi & Wang, Chao & Chen, Ying, 2022. "Superstructure-based mixed-integer nonlinear programming framework for hybrid heat sources driven organic Rankine cycle optimization," Applied Energy, Elsevier, vol. 307(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Chonghui & Xing, Lingli & Su, Wen & Lin, Xinxing, 2023. "Performance prediction and design of CO2 mixtures with the PR-VDW model and molecular groups for the transcritical power cycle," Energy, Elsevier, vol. 282(C).
    2. Ping, Xu & Yang, Fubin & Zhang, Hongguang & Zhang, Jian & Xing, Chengda & Yan, Yinlian & Yang, Anren & Wang, Yan, 2023. "Information theory-based dynamic feature capture and global multi-objective optimization approach for organic Rankine cycle (ORC) considering road environment," Applied Energy, Elsevier, vol. 348(C).
    3. Wang, Jingyu & Tian, Hua & Wang, Xuan & Li, Ligeng & Sun, Rui & Bian, Xingyan & Shu, Gequn & Liang, Xingyu, 2024. "Process design methodology for rankine cycle based on heat matching," Renewable and Sustainable Energy Reviews, Elsevier, vol. 193(C).
    4. Wang, Chenfang & Liu, Shihao & Zhan, Shuming & Ou, Mengmeng & Wei, Jiangjun & Cheng, Xiaozhang & Zhuge, Weilin & Zhang, Yangjun, 2024. "Transcritical dual-loop Rankine cycle waste heat recovery system for China VI emission standards natural gas engine," Energy, Elsevier, vol. 292(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fanxiao, Meng & Enhua, Wang & Bo, Zhang, 2021. "Possibility of optimal efficiency prediction of an organic Rankine cycle based on molecular property method for high-temperature exhaust gases," Energy, Elsevier, vol. 222(C).
    2. Zhang, Bo & Wang, Enhua & Meng, Fanxiao & Zhang, Fujun & Zhao, Changlu, 2020. "Prediction accuracy of thermodynamic properties using PC-SAFT for high-temperature organic Rankine cycle with siloxanes," Energy, Elsevier, vol. 204(C).
    3. Zhan, Taotao & Chen, Yuhang & Dong, Ao & He, Maogang & Zhang, Ying, 2023. "Intrinsic-group-contribution PC-SAFT and its application in performance analysis of high-temperature organic Rankine cycle with siloxanes and alkanes," Energy, Elsevier, vol. 278(PA).
    4. Li, Xiaoya & Xu, Bin & Tian, Hua & Shu, Gequn, 2021. "Towards a novel holistic design of organic Rankine cycle (ORC) systems operating under heat source fluctuations and intermittency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    5. Xu, Weicong & Zhao, Li & Mao, Samuel S. & Deng, Shuai, 2020. "Towards novel low temperature thermodynamic cycle: A critical review originated from organic Rankine cycle," Applied Energy, Elsevier, vol. 270(C).
    6. Schilling, J. & Entrup, M. & Hopp, M. & Gross, J. & Bardow, A., 2021. "Towards optimal mixtures of working fluids: Integrated design of processes and mixtures for Organic Rankine Cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    7. Liao, Gaoliang & E, Jiaqiang & Zhang, Feng & Chen, Jingwei & Leng, Erwei, 2020. "Advanced exergy analysis for Organic Rankine Cycle-based layout to recover waste heat of flue gas," Applied Energy, Elsevier, vol. 266(C).
    8. White, M.T. & Oyewunmi, O.A. & Chatzopoulou, M.A. & Pantaleo, A.M. & Haslam, A.J. & Markides, C.N., 2018. "Computer-aided working-fluid design, thermodynamic optimisation and thermoeconomic assessment of ORC systems for waste-heat recovery," Energy, Elsevier, vol. 161(C), pages 1181-1198.
    9. Hoang, Anh Tuan, 2018. "Waste heat recovery from diesel engines based on Organic Rankine Cycle," Applied Energy, Elsevier, vol. 231(C), pages 138-166.
    10. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    11. Yan, Yinlian & Yang, Fubin & Zhang, Hongguang & Pan, Yachao & Ping, Xu & Ge, Zhong, 2023. "Study on performance evaluation framework and design/ selection guidelines of working fluids for subcritical organic Rankine cycle from molecular structure perspective," Energy, Elsevier, vol. 282(C).
    12. Liu, Peng & Shu, Gequn & Tian, Hua & Wang, Xuan & Yu, Zhigang, 2018. "Alkanes based two-stage expansion with interheating Organic Rankine cycle for multi-waste heat recovery of truck diesel engine," Energy, Elsevier, vol. 147(C), pages 337-350.
    13. Juan J. García-Pabón & Dario Méndez-Méndez & Juan M. Belman-Flores & Juan M. Barroso-Maldonado & Ali Khosravi, 2021. "A Review of Recent Research on the Use of R1234yf as an Environmentally Friendly Fluid in the Organic Rankine Cycle," Sustainability, MDPI, vol. 13(11), pages 1-21, May.
    14. Hærvig, J. & Sørensen, K. & Condra, T.J., 2016. "Guidelines for optimal selection of working fluid for an organic Rankine cycle in relation to waste heat recovery," Energy, Elsevier, vol. 96(C), pages 592-602.
    15. Chintala, Venkateswarlu & Kumar, Suresh & Pandey, Jitendra K., 2018. "A technical review on waste heat recovery from compression ignition engines using organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 493-509.
    16. Xu, Weicong & Zhao, Ruikai & Deng, Shuai & Zhao, Li & Mao, Samuel S., 2021. "Is zeotropic working fluid a promising option for organic Rankine cycle: A quantitative evaluation based on literature data," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    17. Wang, Dabiao & Dai, Xiaoye & Wu, Zhihua & Zhao, Wu & Wang, Puwei & Hu, Busong & Shi, Lin, 2020. "Design and testing of a 340 kW Organic Rankine Cycle system for Low Pressure Saturated Steam heat source," Energy, Elsevier, vol. 210(C).
    18. Giuffrida, Antonio, 2018. "A theoretical study on the performance of a scroll expander in an organic Rankine cycle with hydrofluoroolefins (HFOs) in place of R245fa," Energy, Elsevier, vol. 161(C), pages 1172-1180.
    19. Morais, Pedro Henrique da Silva & Lodi, Andressa & Aoki, Adriana Cristine & Modesto, Marcelo, 2020. "Energy, exergetic and economic analyses of a combined solar-biomass-ORC cooling cogeneration systems for a Brazilian small plant," Renewable Energy, Elsevier, vol. 157(C), pages 1131-1147.
    20. Peter Collings & Zhibin Yu, 2017. "Numerical Analysis of an Organic Rankine Cycle with Adjustable Working Fluid Composition, a Volumetric Expander and a Recuperator," Energies, MDPI, vol. 10(4), pages 1-21, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:263:y:2023:i:pd:s0360544222028213. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.