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Comparison of working fluids and cycle optimization for heat recovery ORCs from large internal combustion engines

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  • Scaccabarozzi, Roberto
  • Tavano, Michele
  • Invernizzi, Costante Mario
  • Martelli, Emanuele

Abstract

This paper addresses the optimal working fluid selection for organic Rankine cycle recovering heat from heavy-duty internal combustion engines. Four cases are considered featuring two different engine exhaust temperatures (245 °C vs 354 °C) and two scenarios (maximum recovery of mechanical power vs. cogeneration of low-temperature heat). The analysis includes both pure fluids, including recently synthesized refrigerants, and binary mixtures. To perform a fair comparison between the different fluids, a computationally efficient cycle optimization approach, able to determine the maximum achievable efficiency for each working fluid, is adopted. The approach combines the evolutionary optimization algorithm PGS-COM with a rigorous heat integration methodology. The most efficient fluids are HCFO-1233zde, HFE-245fa2, HFO-1336mzz, HFE-347mcc, HFE-245cb2 and Novec 649 for the engine with lower temperature exhausts (reaching an ORC mechanical efficiency of 18.6–19.9%), and cyclopentane, ammonia, HCFO-1233zde, HFE-245fa2, HFO-1366mzz for the engine with higher temperature (reaching 23.76–22.70% efficiency). Compared to pure fluids, the use of optimized binary mixtures does not appear to lead a considerable efficiency gain.

Suggested Citation

  • Scaccabarozzi, Roberto & Tavano, Michele & Invernizzi, Costante Mario & Martelli, Emanuele, 2018. "Comparison of working fluids and cycle optimization for heat recovery ORCs from large internal combustion engines," Energy, Elsevier, vol. 158(C), pages 396-416.
  • Handle: RePEc:eee:energy:v:158:y:2018:i:c:p:396-416
    DOI: 10.1016/j.energy.2018.06.017
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    References listed on IDEAS

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