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Investigation of hydrofluoroolefins as potential working fluids in organic Rankine cycle for geothermal power generation

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  • Liu, Wei
  • Meinel, Dominik
  • Wieland, Christoph
  • Spliethoff, Hartmut

Abstract

Recently, HFOs (hydrofluoroolefins) are presented as a group of the fourth generation refrigerants with zero ODP (Ozone Depletion Potential) and a very low GWP (Global Warming Potential). This paper presents a study on eight different HFOs and their potential applications in ORC (Organic Rankine Cycle) for geothermal power generation. The thermodynamic properties are calculated based on Peng–Robinson equation of state, and are used for simulating a standard ORC for geothermal heat sources with different temperatures. System efficiency, which involves both heat transfer efficiency and thermal efficiency, is considered to be the main criterion to evaluate the ORC system performance. An innovative term, i.e. the optimal heat source temperature is proposed for the determination of thermodynamic performances of each investigated working fluid in combination with the pinch point analysis. Based on the system efficiencies of all HFOs, some of them are selected in a series of case studies for comparison with other relevant ORC fluids. As a conclusion, some of the presented HFOs show promising performances in terms of system efficiency especially for low-to medium temperature geothermal ORC power generation (120 °C ≤ ths ≤ 150 °C).

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  • Liu, Wei & Meinel, Dominik & Wieland, Christoph & Spliethoff, Hartmut, 2014. "Investigation of hydrofluoroolefins as potential working fluids in organic Rankine cycle for geothermal power generation," Energy, Elsevier, vol. 67(C), pages 106-116.
    • Handle: RePEc:eee:energy:v:67:y:2014:i:c:p:106-116
    DOI: 10.1016/j.energy.2013.11.081
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    Cited by:

    1. Chaitanya Prasad, G.S. & Suresh Kumar, C. & Srinivasa Murthy, S. & Venkatarathnam, G., 2015. "Performance of an organic Rankine cycle with multicomponent mixtures," Energy, Elsevier, vol. 88(C), pages 690-696.
    2. Wang, Dabiao & Ma, Yuezheng & Tian, Ran & Duan, Jie & Hu, Busong & Shi, Lin, 2018. "Thermodynamic evaluation of an ORC system with a Low Pressure Saturated Steam heat source," Energy, Elsevier, vol. 149(C), pages 375-385.
    3. Brown, J. Steven & Brignoli, Riccardo & Daubman, Samantha, 2014. "Methodology for estimating thermodynamic parameters and performance of working fluids for organic Rankine cycles," Energy, Elsevier, vol. 73(C), pages 818-828.
    4. Dawo, Fabian & Fleischmann, Jonas & Kaufmann, Florian & Schifflechner, Christopher & Eyerer, Sebastian & Wieland, Christoph & Spliethoff, Hartmut, 2021. "R1224yd(Z), R1233zd(E) and R1336mzz(Z) as replacements for R245fa: Experimental performance, interaction with lubricants and environmental impact," Applied Energy, Elsevier, vol. 288(C).
    5. Reyes-Antonio, Claudio Antonio & Iglesias-Silva, Gustavo Arturo & Rubio-Maya, Carlos & Fuentes-Cortés, Luis Fabián, 2024. "Multi-objective design of off-grid low-enthalpy geothermal generation systems considering partial-load operations," Energy, Elsevier, vol. 294(C).
    6. Manente, Giovanni & Lazzaretto, Andrea & Bonamico, Eleonora, 2017. "Design guidelines for the choice between single and dual pressure layouts in organic Rankine cycle (ORC) systems," Energy, Elsevier, vol. 123(C), pages 413-431.
    7. Mustapić, N. & Kralj, Toni & Vujanović, Milan, 2024. "Split flow principle implementation for advanced subcritical double stage organic rankine cycle configuration for geothermal power production," Energy, Elsevier, vol. 303(C).
    8. Nenad Mustapić & Vladislav Brkić & Željko Duić & Toni Kralj, 2022. "Thermodynamic Optimization of Advanced Organic Rankine Cycle Configurations for Geothermal Energy Applications," Energies, MDPI, vol. 15(19), pages 1-36, September.
    9. Wang, Enhua & Mao, Jingwen & Zhang, Bo & Wang, Yongzhen, 2023. "On the CAMD method based on PC-SAFT for working fluid design of a high-temperature organic Rankine cycle," Energy, Elsevier, vol. 263(PD).
    10. Dario Méndez-Méndez & Vicente Pérez-García & Juan M. Belman-Flores & José M. Riesco-Ávila & Juan M. Barroso-Maldonado, 2022. "Internal Heat Exchanger Influence in Operational Cost and Environmental Impact of an Experimental Installation Using Low GWP Refrigerant for HVAC Conditions," Sustainability, MDPI, vol. 14(10), pages 1-19, May.
    11. Zhai, Huixing & An, Qingsong & Shi, Lin & Lemort, Vincent & Quoilin, Sylvain, 2016. "Categorization and analysis of heat sources for organic Rankine cycle systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 790-805.
    12. Juan J. García-Pabón & Dario Méndez-Méndez & Juan M. Belman-Flores & Juan M. Barroso-Maldonado & Ali Khosravi, 2021. "A Review of Recent Research on the Use of R1234yf as an Environmentally Friendly Fluid in the Organic Rankine Cycle," Sustainability, MDPI, vol. 13(11), pages 1-21, May.
    13. Mondejar, M.E. & Andreasen, J.G. & Pierobon, L. & Larsen, U. & Thern, M. & Haglind, F., 2018. "A review of the use of organic Rankine cycle power systems for maritime applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 126-151.
    14. Wang, Dabiao & Dai, Xiaoye & Wu, Zhihua & Zhao, Wu & Wang, Puwei & Hu, Busong & Shi, Lin, 2020. "Design and testing of a 340 kW Organic Rankine Cycle system for Low Pressure Saturated Steam heat source," Energy, Elsevier, vol. 210(C).
    15. Yang, Jingye & Ye, Zhenhong & Yu, Binbin & Ouyang, Hongsheng & Chen, Jiangping, 2019. "Simultaneous experimental comparison of low-GWP refrigerants as drop-in replacements to R245fa for Organic Rankine cycle application: R1234ze(Z), R1233zd(E), and R1336mzz(E)," Energy, Elsevier, vol. 173(C), pages 721-731.
    16. Zhang, Xinxin & Li, Yingzhen, 2024. "Recommended operating conditions and performance evaluation of commonly used hydrofluoroolefin (HFO) and hydrochlorofluoroolefin (HCFO) refrigerants in organic Rankine cycle," Energy, Elsevier, vol. 299(C).
    17. Habka, Muhsen & Ajib, Salman, 2015. "Evaluation of mixtures performances in Organic Rankine Cycle when utilizing the geothermal water with and without cogeneration," Applied Energy, Elsevier, vol. 154(C), pages 567-576.
    18. Frutiger, Jérôme & Andreasen, Jesper & Liu, Wei & Spliethoff, Hartmut & Haglind, Fredrik & Abildskov, Jens & Sin, Gürkan, 2016. "Working fluid selection for organic Rankine cycles – Impact of uncertainty of fluid properties," Energy, Elsevier, vol. 109(C), pages 987-997.
    19. Eyerer, Sebastian & Dawo, Fabian & Kaindl, Johannes & Wieland, Christoph & Spliethoff, Hartmut, 2019. "Experimental investigation of modern ORC working fluids R1224yd(Z) and R1233zd(E) as replacements for R245fa," Applied Energy, Elsevier, vol. 240(C), pages 946-963.
    20. Al-Sayyab, Ali Khalid Shaker & Mota-Babiloni, Adrián & Navarro-Esbrí, Joaquín, 2023. "Performance evaluation of modified compound organic Rankine-vapour compression cycle with two cooling levels, heating, and power generation," Applied Energy, Elsevier, vol. 334(C).
    21. Dominika Matuszewska & Piotr Olczak, 2020. "Evaluation of Using Gas Turbine to Increase Efficiency of the Organic Rankine Cycle (ORC)," Energies, MDPI, vol. 13(6), pages 1-21, March.
    22. Giuffrida, Antonio, 2018. "A theoretical study on the performance of a scroll expander in an organic Rankine cycle with hydrofluoroolefins (HFOs) in place of R245fa," Energy, Elsevier, vol. 161(C), pages 1172-1180.

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