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Prediction accuracy of thermodynamic properties using PC-SAFT for high-temperature organic Rankine cycle with siloxanes

Author

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  • Zhang, Bo
  • Wang, Enhua
  • Meng, Fanxiao
  • Zhang, Fujun
  • Zhao, Changlu

Abstract

High-temperature organic Rankine cycle (ORC) with a heat source temperature over 250 °C can be used as the bottom cycle to form a combined cycle with a heat engine such as gas turbine or internal combustion engine. The accurate calculation of thermo-physical properties of the working fluid is of great significance for the performance prediction of an ORC system. PC-SAFT Equation of State (EoS) based on statistical theory can be used to estimate the thermo-physical properties of different working fluids and even to develop new working fluids. However, its accuracy needs to be investigated comprehensively. In this study, the prediction accuracy for the thermal properties based on PC-SAFT for linear and cyclic siloxanes is evaluated and the influence of the uncertainties on the performance of a high-temperature ORC is estimated. First, a program based on the PC-SAFT is developed to compute the properties of 8 siloxanes (MM, MDM, MD2M, MD3M, MD4M, D4, D5, D6). Then, the parameters of the EoS are fitted. Next, the accuracies of PC-SAFT along with the saturation lines and in the superheated regions are determined and compared with the results of Peng-Robinson (PR) EoS. Finally, the ORC performance is estimated using PC-SAFT. The results indicate that the accuracy of PC-SAFT is better than PR EoS. Only the deviation for the compressibility factor in the superheated region is slightly higher than PR. When PC-SAFT is used for the performance prediction of ORC system, the prediction accuracy increases apparently with the increase of molecular chain length. The deviations of the thermal efficiency by PC-SAFT relative to that of Refprop are basically less than 8% for the siloxanes except MM.

Suggested Citation

  • Zhang, Bo & Wang, Enhua & Meng, Fanxiao & Zhang, Fujun & Zhao, Changlu, 2020. "Prediction accuracy of thermodynamic properties using PC-SAFT for high-temperature organic Rankine cycle with siloxanes," Energy, Elsevier, vol. 204(C).
    • Handle: RePEc:eee:energy:v:204:y:2020:i:c:s0360544220310872
    DOI: 10.1016/j.energy.2020.117980
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    as
    1. Wang, Enhua & Yu, Zhibin & Zhang, Hongguang & Yang, Fubin, 2017. "A regenerative supercritical-subcritical dual-loop organic Rankine cycle system for energy recovery from the waste heat of internal combustion engines," Applied Energy, Elsevier, vol. 190(C), pages 574-590.
    2. Martelli, Emanuele & Capra, Federico & Consonni, Stefano, 2015. "Numerical optimization of Combined Heat and Power Organic Rankine Cycles – Part A: Design optimization," Energy, Elsevier, vol. 90(P1), pages 310-328.
    3. Wieland, Christoph & Meinel, Dominik & Eyerer, Sebastian & Spliethoff, Hartmut, 2016. "Innovative CHP concept for ORC and its benefit compared to conventional concepts," Applied Energy, Elsevier, vol. 183(C), pages 478-490.
    4. Lai, Ngoc Anh & Wendland, Martin & Fischer, Johann, 2011. "Working fluids for high-temperature organic Rankine cycles," Energy, Elsevier, vol. 36(1), pages 199-211.
    5. Fernández, F.J. & Prieto, M.M. & Suárez, I., 2011. "Thermodynamic analysis of high-temperature regenerative organic Rankine cycles using siloxanes as working fluids," Energy, Elsevier, vol. 36(8), pages 5239-5249.
    6. Imran, Muhammad & Haglind, Fredrik & Asim, Muhammad & Zeb Alvi, Jahan, 2018. "Recent research trends in organic Rankine cycle technology: A bibliometric approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 552-562.
    7. Uusitalo, Antti & Honkatukia, Juha & Turunen-Saaresti, Teemu, 2017. "Evaluation of a small-scale waste heat recovery organic Rankine cycle," Applied Energy, Elsevier, vol. 192(C), pages 146-158.
    8. White, M.T. & Oyewunmi, O.A. & Chatzopoulou, M.A. & Pantaleo, A.M. & Haslam, A.J. & Markides, C.N., 2018. "Computer-aided working-fluid design, thermodynamic optimisation and thermoeconomic assessment of ORC systems for waste-heat recovery," Energy, Elsevier, vol. 161(C), pages 1181-1198.
    9. Schilling, Johannes & Eichler, Katharina & Kölsch, Benedikt & Pischinger, Stefan & Bardow, André, 2019. "Integrated design of working fluid and organic Rankine cycle utilizing transient exhaust gases of heavy-duty vehicles," Applied Energy, Elsevier, vol. 255(C).
    10. Cignitti, Stefano & Andreasen, Jesper G. & Haglind, Fredrik & Woodley, John M. & Abildskov, Jens, 2017. "Integrated working fluid-thermodynamic cycle design of organic Rankine cycle power systems for waste heat recovery," Applied Energy, Elsevier, vol. 203(C), pages 442-453.
    11. Angelino, Gianfranco & Colonna di Paliano, Piero, 1998. "Multicomponent Working Fluids For Organic Rankine Cycles (ORCs)," Energy, Elsevier, vol. 23(6), pages 449-463.
    12. Ho, Tony & Mao, Samuel S. & Greif, Ralph, 2012. "Increased power production through enhancements to the Organic Flash Cycle (OFC)," Energy, Elsevier, vol. 45(1), pages 686-695.
    13. Frutiger, Jérôme & Andreasen, Jesper & Liu, Wei & Spliethoff, Hartmut & Haglind, Fredrik & Abildskov, Jens & Sin, Gürkan, 2016. "Working fluid selection for organic Rankine cycles – Impact of uncertainty of fluid properties," Energy, Elsevier, vol. 109(C), pages 987-997.
    14. Xu, Bin & Rathod, Dhruvang & Yebi, Adamu & Filipi, Zoran & Onori, Simona & Hoffman, Mark, 2019. "A comprehensive review of organic rankine cycle waste heat recovery systems in heavy-duty diesel engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 145-170.
    15. Capra, Federico & Martelli, Emanuele, 2015. "Numerical optimization of combined heat and power Organic Rankine Cycles – Part B: Simultaneous design & part-load optimization," Energy, Elsevier, vol. 90(P1), pages 329-343.
    16. van Kleef, Luuk M.T. & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2019. "Multi-objective thermo-economic optimization of organic Rankine cycle (ORC) power systems in waste-heat recovery applications using computer-aided molecular design techniques," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    17. Spinelli, Andrea & Cammi, Giorgia & Conti, Camilla Cecilia & Gallarini, Simone & Zocca, Marta & Cozzi, Fabio & Gaetani, Paolo & Dossena, Vincenzo & Guardone, Alberto, 2019. "Experimental observation and thermodynamic modeling of non-ideal expanding flows of siloxane MDM vapor for ORC applications," Energy, Elsevier, vol. 168(C), pages 285-294.
    18. Lai, Ngoc Anh & Fischer, Johann, 2012. "Efficiencies of power flash cycles," Energy, Elsevier, vol. 44(1), pages 1017-1027.
    19. Nami, Hossein & Ertesvåg, Ivar S. & Agromayor, Roberto & Riboldi, Luca & Nord, Lars O., 2018. "Gas turbine exhaust gas heat recovery by organic Rankine cycles (ORC) for offshore combined heat and power applications - Energy and exergy analysis," Energy, Elsevier, vol. 165(PB), pages 1060-1071.
    20. Martin T. White & Abdulnaser I. Sayma, 2018. "A Generalised Assessment of Working Fluids and Radial Turbines for Non-Recuperated Subcritical Organic Rankine Cycles," Energies, MDPI, vol. 11(4), pages 1-26, March.
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