IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v253y2022ics0360544222010209.html
   My bibliography  Save this article

Investigation on thermal and storage stability of the Calophyllum inophyllum ester with natural leaf extract as antioxidant additive

Author

Listed:
  • Govindasamy, Mohan
  • Ramalingam, Senthil
  • Dhairiyasamy, Ratchagaraja
  • Rajendran, Silambarasan

Abstract

Biodiesel is a renewable and non-toxic fuel used in compression ignition engines as a blend with diesel without modifying the engine. It has a drawback of poor oxidation, thermal stability and long-term storage stability, preventing widespread use as a commercial fuel. The leaf extract with antioxidant properties will improve biofuel's stability by inhibiting the free radical formation or absorbing the free radicals. Natural antioxidants derived from natural products are the recent innovation in antioxidants. The present work analyses leaf extract's effect as additive with Calophyllum inophyllum methyl ester on thermal stability, storage stability, and oxidation stability. The addition of leaf extract has shown a significant improvement in thermal stability and reduced residual formation. 20 ml of the additive with biodiesel has improved the induction period of the B20 up to 9.2 h. On storage, the peroxide value, acid number, and viscosity have increased significantly due to oxidation, acid formation, and long-chain organic compounds, respectively. The additive addition has reduced the peroxide value, acid number, and viscosity by quenching the free radicals formed during biodiesel's oxidation.

Suggested Citation

  • Govindasamy, Mohan & Ramalingam, Senthil & Dhairiyasamy, Ratchagaraja & Rajendran, Silambarasan, 2022. "Investigation on thermal and storage stability of the Calophyllum inophyllum ester with natural leaf extract as antioxidant additive," Energy, Elsevier, vol. 253(C).
    • Handle: RePEc:eee:energy:v:253:y:2022:i:c:s0360544222010209
    DOI: 10.1016/j.energy.2022.124117
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222010209
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.124117?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Arumugam, A. & Ponnusami, V., 2019. "Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview," Renewable Energy, Elsevier, vol. 131(C), pages 459-471.
    2. Dimitrios N Tziourtzioumis & Anastassios M Stamatelos, 2017. "Experimental Investigation of the Effect of Biodiesel Blends on a DI Diesel Engine’s Injection and Combustion," Energies, MDPI, vol. 10(7), pages 1-15, July.
    3. Jain, Siddharth & Sharma, M.P., 2010. "Stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 667-678, February.
    4. Varatharajan, K. & Pushparani, D.S., 2018. "Screening of antioxidant additives for biodiesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2017-2028.
    5. Belachew Tesfa & Fengshou Gu & Rakesh Mishra & Andrew Ball, 2014. "Emission Characteristics of a CI Engine Running with a Range of Biodiesel Feedstocks," Energies, MDPI, vol. 7(1), pages 1-17, January.
    6. Rashed, M.M. & Masjuki, H.H. & Kalam, M.A. & Alabdulkarem, Abdullah & Rahman, M.M. & Imdadul, H.K. & Rashedul, H.K., 2016. "Study of the oxidation stability and exhaust emission analysis of Moringa olifera biodiesel in a multi-cylinder diesel engine with aromatic amine antioxidants," Renewable Energy, Elsevier, vol. 94(C), pages 294-303.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    2. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Altarazi, Yazan S.M. & Abu Talib, Abd Rahim & Gires, Ezanee & Yu, Jianglong & Lucas, John & Yusaf, Talal, 2021. "Performance and exhaust emissions rate of small-scale turbojet engine running on dual biodiesel blends using Gasturb," Energy, Elsevier, vol. 232(C).
    4. Dwivedi, Gaurav & Jain, Siddharth & Sharma, M.P., 2011. "Impact analysis of biodiesel on engine performance—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4633-4641.
    5. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    6. Siddharth Jain, 2023. "An Assessment of the Operation and Emission Characteristics of a Diesel Engine Powered by a New Biofuel Prepared Using In Situ Transesterification of a Dry Spirogyra Algae–Jatropha Powder Mixture," Energies, MDPI, vol. 16(3), pages 1-16, February.
    7. Teoh, Y.H. & How, H.G. & Masjuki, H.H. & Nguyen, H.-T. & Kalam, M.A. & Alabdulkarem, A., 2019. "Investigation on particulate emissions and combustion characteristics of a common-rail diesel engine fueled with Moringa oleifera biodiesel-diesel blends," Renewable Energy, Elsevier, vol. 136(C), pages 521-534.
    8. Khounani, Zahra & Hosseinzadeh-Bandbafha, Homa & Nizami, Abdul-Sattar & Sulaiman, Alawi & Goli, Sayed Amir Hossein & Tavassoli-Kafrani, Elham & Ghaffari, Akram & Rajaeifar, Mohammad Ali & Kim, Ki-Hyun, 2020. "Unlocking the potential of walnut husk extract in the production of waste cooking oil-based biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. José María Encinar & Sergio Nogales & Juan Félix González, 2020. "The effect of BHA on oxidative stability of biodiesel from different sources," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(6), pages 1193-1201, December.
    10. Paparao, Jami & Soundarya, N. & Murugan, S., 2023. "Advancing green technology: Experimental study on low heat rejection engine utilizing bio-based antioxidant-doped biodiesel-diesel blends and oxy-hydrogen gas," Energy, Elsevier, vol. 283(C).
    11. Karishma, Shaik Mullan & Rajak, Upendra & Naik, B. Kiran & Dasore, Abhishek & Konijeti, Ramakrishna, 2022. "Performance and emission characteristics assessment of compression ignition engine fuelled with the blends of novel antioxidant catechol-daok biodiesel," Energy, Elsevier, vol. 245(C).
    12. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    13. Youssef Kassem & Hüseyin Çamur & Ebaa Alassi, 2020. "Biodiesel Production from Four Residential Waste Frying Oils: Proposing Blends for Improving the Physicochemical Properties of Methyl Biodiesel," Energies, MDPI, vol. 13(16), pages 1-25, August.
    14. Goel, Varun & Kumar, Naresh & Singh, Paramvir, 2018. "Impact of modified parameters on diesel engine characteristics using biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2716-2729.
    15. Jain, Siddharth & Sharma, M.P., 2011. "Thermal stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 438-448, January.
    16. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    17. Tomasz Janusz Teleszewski & Andrzej Gajewski, 2020. "The Latest Method for Surface Tension Determination: Experimental Validation," Energies, MDPI, vol. 13(14), pages 1-10, July.
    18. Enrico Mattarelli & Carlo Alberto Rinaldini & Tommaso Savioli, 2015. "Combustion Analysis of a Diesel Engine Running on Different Biodiesel Blends," Energies, MDPI, vol. 8(4), pages 1-11, April.
    19. Jakeria, M.R. & Fazal, M.A. & Haseeb, A.S.M.A., 2014. "Influence of different factors on the stability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 154-163.
    20. Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:253:y:2022:i:c:s0360544222010209. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.