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Screening of antioxidant additives for biodiesel fuels

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  • Varatharajan, K.
  • Pushparani, D.S.

Abstract

One of the major issues associated with the use of biodiesel is to maintain the fuel at specified standards for a longer period. Biodiesel is more prone to oxidization than a mineral diesel, and it starts turning rancid within a week or less, and complete degradation occurs after a period of 4 weeks. The final products of oxidation alter the physical and chemical properties of fuel which results in the formation of insoluble gums that can plug fuel filters. This instability of biodiesel is a long-standing issue, and it has not as yet been satisfactorily resolved. As the use of biodiesel has increased massively, this oxidation issue could become a significant barrier to market expansion. One very promising and cost-effective approach to improving the stability of biodiesel is that the addition of appropriate antioxidants to the biodiesel fuels. Antioxidants perform better or worse in different biodiesel fuels, and there is no unique inhibitor that suit for every kind of biodiesel fuels. To screen the antioxidants for a specific biodiesel, it is necessary to understand the chemistry of antioxidants and the key factors that influence their effectiveness against biodiesel oxidation. Most of the published studies had been carried out solely with some common antioxidants, and still, hundreds of antioxidants are out there for testing. This article provides an insight into the factors to be considered for the selection of antioxidants to improve the storage stability of biodiesel fuels.

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  • Varatharajan, K. & Pushparani, D.S., 2018. "Screening of antioxidant additives for biodiesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2017-2028.
    • Handle: RePEc:eee:rensus:v:82:y:2018:i:p3:p:2017-2028
    DOI: 10.1016/j.rser.2017.07.020
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    References listed on IDEAS

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    Cited by:

    1. Youssef Kassem & Hüseyin Çamur & Ebaa Alassi, 2020. "Biodiesel Production from Four Residential Waste Frying Oils: Proposing Blends for Improving the Physicochemical Properties of Methyl Biodiesel," Energies, MDPI, vol. 13(16), pages 1-25, August.
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    4. José María Encinar & Sergio Nogales & Juan Félix González, 2020. "The effect of BHA on oxidative stability of biodiesel from different sources," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(6), pages 1193-1201, December.
    5. Li, Ruizhi & Wang, Shuang & Zhang, Huicong & Li, Fashe & Sui, Meng, 2022. "Synthesis, antioxidant properties, and oil solubility of a novel ionic liquid [UIM0Y2][C6H2(OH)3COO] in biodiesel," Renewable Energy, Elsevier, vol. 197(C), pages 545-551.
    6. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    7. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    8. Rodrigues, Jailson Silva & do Valle, Camila Peixoto & Uchoa, Antonia Flávia Justino & Ramos, Denise Moreira & da Ponte, Flávio Albuquerque Ferreira & Rios, Maria Alexsandra de Sousa & de Queiroz Malve, 2020. "Comparative study of synthetic and natural antioxidants on the oxidative stability of biodiesel from Tilapia oil," Renewable Energy, Elsevier, vol. 156(C), pages 1100-1106.
    9. Sergio Nogales-Delgado & José María Encinar & Juan Félix González, 2019. "Safflower Biodiesel: Improvement of its Oxidative Stability by Using BHA and TBHQ," Energies, MDPI, vol. 12(10), pages 1-13, May.
    10. Paparao, Jami & Soundarya, N. & Murugan, S., 2023. "Advancing green technology: Experimental study on low heat rejection engine utilizing bio-based antioxidant-doped biodiesel-diesel blends and oxy-hydrogen gas," Energy, Elsevier, vol. 283(C).
    11. Govindasamy, Mohan & Ramalingam, Senthil & Dhairiyasamy, Ratchagaraja & Rajendran, Silambarasan, 2022. "Investigation on thermal and storage stability of the Calophyllum inophyllum ester with natural leaf extract as antioxidant additive," Energy, Elsevier, vol. 253(C).
    12. Karishma, Shaik Mullan & Rajak, Upendra & Naik, B. Kiran & Dasore, Abhishek & Konijeti, Ramakrishna, 2022. "Performance and emission characteristics assessment of compression ignition engine fuelled with the blends of novel antioxidant catechol-daok biodiesel," Energy, Elsevier, vol. 245(C).
    13. Sergio Nogales-Delgado & Agustina Guiberteau Cabanillas & Juan Pedro Moro & José María Encinar Martín, 2023. "Use of Propyl Gallate in Cardoon Biodiesel to Keep Its Main Properties during Oxidation," Clean Technol., MDPI, vol. 5(2), pages 1-15, May.
    14. Nogueira, Tiago Rocha & de Mesquita Figueredo, Igor & Tavares Luna, Francisco Murilo & Cavalcante, Célio Loureiro & Evangelista de Ávila dos Santos, João & Sousa Lima, Mary Anne & Josino da Silva, Thi, 2020. "Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant," Renewable Energy, Elsevier, vol. 159(C), pages 767-774.
    15. Javier Sáez-Bastante & Miguel Carmona-Cabello & Elena Villarreal-Ornelas & Ricardo Trejo-Calzada & Sara Pinzi & M. Pilar Dorado, 2023. "Feasibility of the Production of Argemone pleiacantha Ultrasound-Assisted Biodiesel for Temperate and Tropical Marginal Areas," Energies, MDPI, vol. 16(6), pages 1-14, March.
    16. Sergio Nogales-Delgado & Nuria Sánchez & José María Encinar, 2020. "Valorization of Cynara Cardunculus L. Oil as the Basis of a Biorefinery for Biodiesel and Biolubricant Production," Energies, MDPI, vol. 13(19), pages 1-19, September.
    17. Chen, Tao & Hu, Run-Ze & Yao, Xiao-Hui & Yang, Qiang & Shuai, Shi-Min & Wang, Jun & Xu, Ming & Zhang, Dong-Yang & Fu, Yu-Jie & Li, Long & Zhao, Wei-Guo, 2020. "Effect of Pyrola extract on the stability of palm biodiesel upon exposure to copper," Renewable Energy, Elsevier, vol. 149(C), pages 1282-1289.
    18. Hwai Chyuan Ong & M. Mofijur & A.S. Silitonga & D. Gumilang & Fitranto Kusumo & T.M.I. Mahlia, 2020. "Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils," Energies, MDPI, vol. 13(6), pages 1-14, March.

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