IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v10y2020i6p1193-1201.html
   My bibliography  Save this article

The effect of BHA on oxidative stability of biodiesel from different sources

Author

Listed:
  • José María Encinar
  • Sergio Nogales
  • Juan Félix González

Abstract

The use of biodiesel is important, as it is a more sustainable energy source, obtained in many cases from vegetable oils and wastes such as fried used oils. In that way, there are plenty of advantages derived from its use, such as higher flash and combustion points. On the other hand, the oxidative stability of these samples is shorter, not complying with the European standards. That is the reason why the use of antioxidants, such as butylated hydroxyanisole (BHA), is vital to comply with the standards and make biodiesel marketable. The aim of this research work was to study the effect of BHA at different concentrations (up to 2000 ppm, depending on the kind of sample) on several biodiesel samples derived from several vegetable oils (rapeseed, seed, and used fried oils). The results obtained pointed out the improvement of the induction point for all the samples as BHA concentration increased. Moreover, there was an influence of the raw material composition (concerning fatty acid profile) on the induction point of the biodiesel obtained and the subsequent optimum concentration of BHA. Thus, the fatty acid profile was different depending on the sample, and the higher amount of methyl linoleate of seed and used fried biodiesel was important, which implied shorter induction points in these samples. As a consequence, for the latter, higher amounts of BHA (around 1400 ppm) were needed. As a conclusion, all the samples studied showed suitable oxidative stability values (over 8 hours) with the use of BHA (at variable optimum concentrations). © 2020 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • José María Encinar & Sergio Nogales & Juan Félix González, 2020. "The effect of BHA on oxidative stability of biodiesel from different sources," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(6), pages 1193-1201, December.
    • Handle: RePEc:wly:greenh:v:10:y:2020:i:6:p:1193-1201
    DOI: 10.1002/ghg.2038
    as

    Download full text from publisher

    File URL: https://doi.org/10.1002/ghg.2038
    Download Restriction: no
    File URL: https://libkey.io/10.1002/ghg.2038?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Varatharajan, K. & Pushparani, D.S., 2018. "Screening of antioxidant additives for biodiesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2017-2028.
    2. Sergio Nogales-Delgado & José María Encinar & Juan Félix González, 2019. "Safflower Biodiesel: Improvement of its Oxidative Stability by Using BHA and TBHQ," Energies, MDPI, vol. 12(10), pages 1-13, May.
    3. Marina Corral Bobadilla & Rubén Lostado Lorza & Rubén Escribano García & Fátima Somovilla Gómez & Eliseo P. Vergara González, 2017. "An Improvement in Biodiesel Production from Waste Cooking Oil by Applying Thought Multi-Response Surface Methodology Using Desirability Functions," Energies, MDPI, vol. 10(1), pages 1-20, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sergio Nogales-Delgado & José María Encinar & Juan Félix González, 2019. "Safflower Biodiesel: Improvement of its Oxidative Stability by Using BHA and TBHQ," Energies, MDPI, vol. 12(10), pages 1-13, May.
    2. Sergio Nogales-Delgado & Agustina Guiberteau Cabanillas & Juan Pedro Moro & José María Encinar Martín, 2023. "Use of Propyl Gallate in Cardoon Biodiesel to Keep Its Main Properties during Oxidation," Clean Technol., MDPI, vol. 5(2), pages 1-15, May.
    3. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    4. Youssef Kassem & Hüseyin Çamur & Ebaa Alassi, 2020. "Biodiesel Production from Four Residential Waste Frying Oils: Proposing Blends for Improving the Physicochemical Properties of Methyl Biodiesel," Energies, MDPI, vol. 13(16), pages 1-25, August.
    5. Sergio Nogales-Delgado & Nuria Sánchez & José María Encinar, 2020. "Valorization of Cynara Cardunculus L. Oil as the Basis of a Biorefinery for Biodiesel and Biolubricant Production," Energies, MDPI, vol. 13(19), pages 1-19, September.
    6. Javier Sáez-Bastante & Miguel Carmona-Cabello & Elena Villarreal-Ornelas & Ricardo Trejo-Calzada & Sara Pinzi & M. Pilar Dorado, 2023. "Feasibility of the Production of Argemone pleiacantha Ultrasound-Assisted Biodiesel for Temperate and Tropical Marginal Areas," Energies, MDPI, vol. 16(6), pages 1-14, March.
    7. Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
    8. Govindasamy, Mohan & Ramalingam, Senthil & Dhairiyasamy, Ratchagaraja & Rajendran, Silambarasan, 2022. "Investigation on thermal and storage stability of the Calophyllum inophyllum ester with natural leaf extract as antioxidant additive," Energy, Elsevier, vol. 253(C).
    9. Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.
    10. Nogueira, Tiago Rocha & de Mesquita Figueredo, Igor & Tavares Luna, Francisco Murilo & Cavalcante, Célio Loureiro & Evangelista de Ávila dos Santos, João & Sousa Lima, Mary Anne & Josino da Silva, Thi, 2020. "Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant," Renewable Energy, Elsevier, vol. 159(C), pages 767-774.
    11. Li, Ruizhi & Wang, Shuang & Zhang, Huicong & Li, Fashe & Sui, Meng, 2022. "Synthesis, antioxidant properties, and oil solubility of a novel ionic liquid [UIM0Y2][C6H2(OH)3COO] in biodiesel," Renewable Energy, Elsevier, vol. 197(C), pages 545-551.
    12. Marina Corral Bobadilla & Roberto Fernández Martínez & Rubén Lostado Lorza & Fátima Somovilla Gómez & Eliseo P. Vergara González, 2018. "Optimizing Biodiesel Production from Waste Cooking Oil Using Genetic Algorithm-Based Support Vector Machines," Energies, MDPI, vol. 11(11), pages 1-19, November.
    13. Rodrigues, Jailson Silva & do Valle, Camila Peixoto & Uchoa, Antonia Flávia Justino & Ramos, Denise Moreira & da Ponte, Flávio Albuquerque Ferreira & Rios, Maria Alexsandra de Sousa & de Queiroz Malve, 2020. "Comparative study of synthetic and natural antioxidants on the oxidative stability of biodiesel from Tilapia oil," Renewable Energy, Elsevier, vol. 156(C), pages 1100-1106.
    14. Sáez-Bastante, J. & Carmona-Cabello, M. & Pinzi, S. & Dorado, M.P., 2020. "Recycling of kebab restoration grease for bioenergy production through acoustic cavitation," Renewable Energy, Elsevier, vol. 155(C), pages 1147-1155.
    15. Girardi, Julio Cezar & Bariccatti, Reinaldo Aparecido & Savada, Felipe Yassuo & Borsato, Dionísio & Melegari de Souza, Samuel Nelson & Amaral, Camila Zeni & Prior, Maritane, 2020. "Response surface methodology for the optimization of oxidative stability through the use of natural additives," Renewable Energy, Elsevier, vol. 159(C), pages 346-355.
    16. Paparao, Jami & Soundarya, N. & Murugan, S., 2023. "Advancing green technology: Experimental study on low heat rejection engine utilizing bio-based antioxidant-doped biodiesel-diesel blends and oxy-hydrogen gas," Energy, Elsevier, vol. 283(C).
    17. Karishma, Shaik Mullan & Rajak, Upendra & Naik, B. Kiran & Dasore, Abhishek & Konijeti, Ramakrishna, 2022. "Performance and emission characteristics assessment of compression ignition engine fuelled with the blends of novel antioxidant catechol-daok biodiesel," Energy, Elsevier, vol. 245(C).
    18. Francisco Anguebes-Franseschi & Mohamed Abatal & Ali Bassam & Mauricio A. Escalante Soberanis & Oscar May Tzuc & Lauro Bucio-Galindo & Atl Victor Cordova Quiroz & Claudia Alejandra Aguilar Ucan & Migu, 2018. "Esterification Optimization of Crude African Palm Olein Using Response Surface Methodology and Heterogeneous Acid Catalysis," Energies, MDPI, vol. 11(1), pages 1-15, January.
    19. Hwai Chyuan Ong & M. Mofijur & A.S. Silitonga & D. Gumilang & Fitranto Kusumo & T.M.I. Mahlia, 2020. "Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils," Energies, MDPI, vol. 13(6), pages 1-14, March.
    20. Kumar, Vijay & Choudhary, Akhilesh Kumar, 2024. "Prediction of the Performance and emission characteristics of diesel engine using diphenylamine Antioxidant and ceria nanoparticle additives with biodiesel based on machine learning," Energy, Elsevier, vol. 301(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:10:y:2020:i:6:p:1193-1201. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.