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Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants

Author

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  • Serqueira, Dalyelli S.
  • Pereira, Jian F.S.
  • Squissato, André L.
  • Rodrigues, Mônica A.
  • Lima, Renata C.
  • Faria, Anízio M.
  • Richter, Eduardo M.
  • Munoz, Rodrigo A.A.

Abstract

This work investigates the oxidative stability and corrosivity of residual cooking oil (RCO) methyl biodiesel exposed to metallic coupons (copper and carbon steel) under simulated storage conditions (static immersion for 90 days within closed vessels) and the effect of antioxidants (tert-butylhydroquinone, curcumin, propylgallate, and butyl-hydroxyanisole) on biodiesel and metallic surfaces. The induction period measured during the experiment showed that all antioxidants retarded biodiesel degradation due to their antioxidant properties. Scanning-electron microscopy and X-ray diffraction of the metallic surfaces revealed the presence of oxides due to the corrosion by biodiesel in absence of antioxidants. Nevertheless, the presence of carbonaceous solids over the metallic surfaces was found which evidences the anticorrosive properties of the antioxidants, confirmed by X-Ray spectroscopy that showed increase in the content of carbon and oxygen on the surfaces. Measurements of corrosion rate also confirmed the anticorrosive action of all antioxidants. Hence, this work shows the dual properties of antioxidants acting as free radical scavengers in the RCO biodiesel as well as corrosive inhibitors, with a special performance of propylgallate, probably due to the presence of more hydroxyl groups in its structure that also may facilitate its interaction with the metallic surface.

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  • Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.
  • Handle: RePEc:eee:renene:v:164:y:2021:i:c:p:1485-1495
    DOI: 10.1016/j.renene.2020.10.097
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    4. Nina Bruun & Juho Lehmusto & Fiseha Tesfaye & Jarl Hemming & Leena Hupa, 2022. "Amino Acids Reduce Mild Steel Corrosion in Used Cooking Oils," Sustainability, MDPI, vol. 14(7), pages 1-14, March.
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    6. Katriina Sirviö & Jonna Kaivosoja & Carolin Nuortila & Huaying Wang-Alho & Seppo Niemi & Teemu Ovaska, 2023. "B20 Fuel Compatibility with Steels in Case of Fuel Contamination," Energies, MDPI, vol. 16(16), pages 1-9, August.

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