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Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes

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  • Golkhatmi, Sanaz Zarabi
  • Sedghi, Arman
  • Miankushki, Hoda Nourmohammadi
  • Khalaj, Maryam

Abstract

Recently, hybrid supercapacitors have attracted tremendous attention as promising energy storage and conversion devices due to their excellent energy density and high power density. In the present work, a novel pioneering hybrid ternary nanocomposite of NiO/Gr/PPy was synthesized by a low-cost co-precipitation method, followed by heat treatment and in-situ chemical polymerization. The as-synthesized nanocomposite was drop-cast on a modified Cu current collector to enhance the supercapacitive performance and stability in the electrolyte. The results of electrochemical characterization in 6 M KOH revealed the high specific capacitance and energy density of 970.85 F g−1 and 33.71 Wh kg−1 at 1 A g−1, respectively. This can be attributed to the synergic effect and hybrid performance of NiO, Gr, and PPy. Moreover, a full symmetric cell was assembled by using this hybrid ternary nanocomposite and evaluated in TEA-BF4/AN. The results showed the high specific capacitance and energy density of 66.17 F g−1 and 36.76 Wh kg−1 within the 2 V potential window, respectively.

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  • Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).
    • Handle: RePEc:eee:energy:v:214:y:2021:i:c:s0360544220320570
    DOI: 10.1016/j.energy.2020.118950
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    References listed on IDEAS

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    2. Ponce, M. Federico & Mamani, Arminda & Jerez, Florencia & Castilla, Josué & Ramos, Pamela B. & Acosta, Gerardo G. & Sardella, M. Fabiana & Bavio, Marcela A., 2022. "Activated carbon from olive tree pruning residue for symmetric solid-state supercapacitor," Energy, Elsevier, vol. 260(C).
    3. Sun, Bingkang & Zhang, Xiaoyun & Fan, Xing & Wang, Ruiyu & Bai, Hongcun & Wei, Xianyong, 2022. "Interface modification based on MnO2@N-doped activated carbon composites for flexible solid-state asymmetric supercapacitors," Energy, Elsevier, vol. 249(C).

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