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Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte

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  • Tamilarasan, P.
  • Ramaprabhu, S.

Abstract

Herein, we report, the fabrication of a mechanically stable, flexible graphene based all-solid-state supercapacitor with ionic liquid incorporated polyacrylonitrile (PAN/[BMIM][TFSI]) electrolyte for electric vehicles (EVs). The PAN/[BMIM][TFSI] electrolyte shows high ionic conductivity (2.42 mS/cm at 28 °C) with high thermal stability. Solid-like layered phase of ionic liquid is observed on the surface of pores of PAN membrane along with liquid phase which made it possible to hold 400 wt% of mobile phase. This phase formation is facilitated by the ionic interaction of CN moieties with the electrolyte ions. A supercapacitor device, comprised PAN/[BMIM][TFSI] electrolyte and graphene as electrode, is fabricated and the performance is demonstrated. Several parameters of the device, like, energy storage and discharge capacity, internal power dissipation, operating temperature, safe operation and mechanical stability, meet the requirements of future EVs. In addition, a good cyclic stability is observed even after 1000 cycles.

Suggested Citation

  • Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    • Handle: RePEc:eee:energy:v:51:y:2013:i:c:p:374-381
    DOI: 10.1016/j.energy.2012.11.037
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    as
    1. San Martin, J.I. & Zamora, I. & San Martin, J.J. & Aperribay, V. & Torres, E. & Eguia, P., 2010. "Influence of the rated power in the performance of different proton exchange membrane (PEM) fuel cells," Energy, Elsevier, vol. 35(5), pages 1898-1907.
    2. Hamut, H.S. & Dincer, I. & Naterer, G.F., 2012. "Exergy analysis of a TMS (thermal management system) for range-extended EVs (electric vehicles)," Energy, Elsevier, vol. 46(1), pages 117-125.
    3. Smith, William J., 2010. "Can EV (electric vehicles) address Ireland’s CO2 emissions from transport?," Energy, Elsevier, vol. 35(12), pages 4514-4521.
    4. Neef, H.-J., 2009. "International overview of hydrogen and fuel cell research," Energy, Elsevier, vol. 34(3), pages 327-333.
    5. Berry, Gene D. & Pasternak, Alan D. & Rambach, Glenn D. & Ray Smith, J. & Schock, Robert N., 1996. "Hydrogen as a future transportation fuel," Energy, Elsevier, vol. 21(4), pages 289-303.
    6. Karandikar, Parashuram Balwant & Talange, Dhananjay Balu & Mhaskar, Uday Prakashrao & Bansal, Ramesh, 2012. "Development, modeling and characterization of aqueous metal oxide based supercapacitor," Energy, Elsevier, vol. 40(1), pages 131-138.
    7. Kim, Kyeong Hyun & Park, Young Min & Kim, Haekyoung, 2010. "Fabrication and evaluation of the thin NiFe supported solid oxide fuel cell by co-firing method," Energy, Elsevier, vol. 35(12), pages 5385-5390.
    Full references (including those not matched with items on IDEAS)

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    3. Singh, Manoj K. & Suleman, Mohd & Kumar, Yogesh & Hashmi, S.A., 2015. "A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: A high rate performance," Energy, Elsevier, vol. 80(C), pages 465-473.
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    6. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    7. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
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    9. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
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