IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v51y2013icp374-381.html
   My bibliography  Save this article

Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte

Author

Listed:
  • Tamilarasan, P.
  • Ramaprabhu, S.

Abstract

Herein, we report, the fabrication of a mechanically stable, flexible graphene based all-solid-state supercapacitor with ionic liquid incorporated polyacrylonitrile (PAN/[BMIM][TFSI]) electrolyte for electric vehicles (EVs). The PAN/[BMIM][TFSI] electrolyte shows high ionic conductivity (2.42 mS/cm at 28 °C) with high thermal stability. Solid-like layered phase of ionic liquid is observed on the surface of pores of PAN membrane along with liquid phase which made it possible to hold 400 wt% of mobile phase. This phase formation is facilitated by the ionic interaction of CN moieties with the electrolyte ions. A supercapacitor device, comprised PAN/[BMIM][TFSI] electrolyte and graphene as electrode, is fabricated and the performance is demonstrated. Several parameters of the device, like, energy storage and discharge capacity, internal power dissipation, operating temperature, safe operation and mechanical stability, meet the requirements of future EVs. In addition, a good cyclic stability is observed even after 1000 cycles.

Suggested Citation

  • Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    • Handle: RePEc:eee:energy:v:51:y:2013:i:c:p:374-381
    DOI: 10.1016/j.energy.2012.11.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544212008985
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2012.11.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hamut, H.S. & Dincer, I. & Naterer, G.F., 2012. "Exergy analysis of a TMS (thermal management system) for range-extended EVs (electric vehicles)," Energy, Elsevier, vol. 46(1), pages 117-125.
    2. Neef, H.-J., 2009. "International overview of hydrogen and fuel cell research," Energy, Elsevier, vol. 34(3), pages 327-333.
    3. Berry, Gene D. & Pasternak, Alan D. & Rambach, Glenn D. & Ray Smith, J. & Schock, Robert N., 1996. "Hydrogen as a future transportation fuel," Energy, Elsevier, vol. 21(4), pages 289-303.
    4. Kim, Kyeong Hyun & Park, Young Min & Kim, Haekyoung, 2010. "Fabrication and evaluation of the thin NiFe supported solid oxide fuel cell by co-firing method," Energy, Elsevier, vol. 35(12), pages 5385-5390.
    5. San Martin, J.I. & Zamora, I. & San Martin, J.J. & Aperribay, V. & Torres, E. & Eguia, P., 2010. "Influence of the rated power in the performance of different proton exchange membrane (PEM) fuel cells," Energy, Elsevier, vol. 35(5), pages 1898-1907.
    6. Smith, William J., 2010. "Can EV (electric vehicles) address Ireland’s CO2 emissions from transport?," Energy, Elsevier, vol. 35(12), pages 4514-4521.
    7. Karandikar, Parashuram Balwant & Talange, Dhananjay Balu & Mhaskar, Uday Prakashrao & Bansal, Ramesh, 2012. "Development, modeling and characterization of aqueous metal oxide based supercapacitor," Energy, Elsevier, vol. 40(1), pages 131-138.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    2. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.
    3. Singh, Manoj K. & Suleman, Mohd & Kumar, Yogesh & Hashmi, S.A., 2015. "A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: A high rate performance," Energy, Elsevier, vol. 80(C), pages 465-473.
    4. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    5. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    6. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    7. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    8. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    9. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    10. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
    11. Jagadale, Ajay D. & Kumbhar, Vijay S. & Bulakhe, Ravindra N. & Lokhande, Chandrakant D., 2014. "Influence of electrodeposition modes on the supercapacitive performance of Co3O4 electrodes," Energy, Elsevier, vol. 64(C), pages 234-241.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    2. Ma, Li-Juan & Wang, Jianfeng & Han, Min & Jia, Jianfeng & Wu, Hai-Shun & Zhang, Xiang, 2019. "Adsorption of multiple H2 molecules on the complex TiC6H6: An unusual combination of chemisorption and physisorption," Energy, Elsevier, vol. 171(C), pages 315-325.
    3. Wang, Shuofeng & Ji, Changwei & Zhang, Jian & Zhang, Bo, 2011. "Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen–oxygen mixtures," Energy, Elsevier, vol. 36(10), pages 5832-5837.
    4. Ghosh, P.C. & Vasudeva, U., 2011. "Analysis of 3000T class submarines equipped with polymer electrolyte fuel cells," Energy, Elsevier, vol. 36(5), pages 3138-3147.
    5. Vudumu, Shravan K. & Koylu, Umit O., 2011. "Computational modeling, validation, and utilization for predicting the performance, combustion and emission characteristics of hydrogen IC engines," Energy, Elsevier, vol. 36(1), pages 647-655.
    6. Yilmaz, Ceyhun & Kanoglu, Mehmet, 2014. "Thermodynamic evaluation of geothermal energy powered hydrogen production by PEM water electrolysis," Energy, Elsevier, vol. 69(C), pages 592-602.
    7. Varga, Bogdan Ovidiu, 2013. "Electric vehicles, primary energy sources and CO2 emissions: Romanian case study," Energy, Elsevier, vol. 49(C), pages 61-70.
    8. Liu, Wen & Hu, Weihao & Lund, Henrik & Chen, Zhe, 2013. "Electric vehicles and large-scale integration of wind power – The case of Inner Mongolia in China," Applied Energy, Elsevier, vol. 104(C), pages 445-456.
    9. Díaz-González, Francisco & Sumper, Andreas & Gomis-Bellmunt, Oriol & Villafáfila-Robles, Roberto, 2012. "A review of energy storage technologies for wind power applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2154-2171.
    10. Xu, Le & Zhao, Yan & Lian, Jiabiao & Xu, Yuanguo & Bao, Jian & Qiu, Jingxia & Xu, Li & Xu, Hui & Hua, Mingqing & Li, Huaming, 2017. "Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density," Energy, Elsevier, vol. 123(C), pages 296-304.
    11. Pöschl, Martina & Ward, Shane & Owende, Philip, 2010. "Evaluation of energy efficiency of various biogas production and utilization pathways," Applied Energy, Elsevier, vol. 87(11), pages 3305-3321, November.
    12. Chen, Guihua & Wang, Yong & Sunarso, Jaka & Liang, Fengli & Wang, Huanping, 2016. "A new scandium and niobium co-doped cobalt-free perovskite cathode for intermediate-temperature solid oxide fuel cells," Energy, Elsevier, vol. 95(C), pages 137-143.
    13. Bossink, Bart A.G., 2017. "Demonstrating sustainable energy: A review based model of sustainable energy demonstration projects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1349-1362.
    14. Rabiee, Abdorreza & Khorramdel, Hossein & Aghaei, Jamshid, 2013. "A review of energy storage systems in microgrids with wind turbines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 316-326.
    15. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    16. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    17. Hirsch, Adam & Parag, Yael & Guerrero, Josep, 2018. "Microgrids: A review of technologies, key drivers, and outstanding issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 402-411.
    18. Ghosh, Sampad & Withanage, Sajeevi S. & Chamlagain, Bhim & Khondaker, Saiful I. & Harish, Sivasankaran & Saha, Bidyut Baran, 2020. "Low pressure sulfurization and characterization of multilayer MoS2 for potential applications in supercapacitors," Energy, Elsevier, vol. 203(C).
    19. Graabak, Ingeborg & Wu, Qiuwei & Warland, Leif & Liu, Zhaoxi, 2016. "Optimal planning of the Nordic transmission system with 100% electric vehicle penetration of passenger cars by 2050," Energy, Elsevier, vol. 107(C), pages 648-660.
    20. Zhaohua Wang & Xiaoyang Dong, 2016. "Determinants and policy implications of residents’ new energy vehicle purchases: the evidence from China," Natural Hazards: Journal of the International Society for the Prevention and Mitigation of Natural Hazards, Springer;International Society for the Prevention and Mitigation of Natural Hazards, vol. 82(1), pages 155-173, May.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:51:y:2013:i:c:p:374-381. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.