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Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage

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  • Yanik, Mahir Ozan
  • Yigit, Ekrem Akif
  • Akansu, Yahya Erkan
  • Sahmetlioglu, Ertugrul

Abstract

In this study, supercapacitors based on magnetic conductive polymer-graphene nanocomposites were investigated. The graphene was synthesized from graphite oxide and graphite by Hummers and electrochemical exfoliation method, respectively. The graphene was characterized using Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction. The nanocomposite was obtained by mixing graphene with polypyrrole or magnetic polypyrrole. The conductive ink consisted of the nanocomposite, solvent and binder. The supercapacitor electrodes were manufactured with the conductive ink by using copper foil. Supercapacitor cells were composed of the separator (PTFE) and electrolyte (ionic liquid materials or acids). The cells were characterized by measurement of the specific capacitance and charge-discharge characteristics. Cyclic Voltammogram (CV) plots and scan rate studies showed a good cell structure and charge-discharge characteristics. So far, 255 F/g specific capacitance values have been achieved. Electrochemical impedance spectroscopy analysis showed a healthy cell performance and a fast capacitor response.

Suggested Citation

  • Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
    • Handle: RePEc:eee:energy:v:138:y:2017:i:c:p:883-889
    DOI: 10.1016/j.energy.2017.07.022
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    1. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
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    4. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.
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    1. Wang, Y. & Qiao, X. & Zhang, C. & Zhou, Xiangyang, 2018. "Self-discharge of a hybrid supercapacitor with incorporated galvanic cell components," Energy, Elsevier, vol. 159(C), pages 1035-1045.
    2. Ensafi, Ali A. & Ahmadi, Najmeh & Rezaei, Behzad & Abdolmaleki, Amir & Mahmoudian, Manzar, 2018. "A new quaternary nanohybrid composite electrode for a high-performance supercapacitor," Energy, Elsevier, vol. 164(C), pages 707-721.
    3. Christinelli, W.A. & da Trindade, L.G. & Trench, A.B. & Quintans, C.S. & Paranhos, C.M. & Pereira, E.C., 2017. "High-performance energy storage of poly (o-methoxyaniline) film using an ionic liquid as electrolyte," Energy, Elsevier, vol. 141(C), pages 1829-1835.
    4. Scalia, Alberto & Bella, Federico & Lamberti, Andrea & Gerbaldi, Claudio & Tresso, Elena, 2019. "Innovative multipolymer electrolyte membrane designed by oxygen inhibited UV-crosslinking enables solid-state in plane integration of energy conversion and storage devices," Energy, Elsevier, vol. 166(C), pages 789-795.
    5. Khalaj, Maryam & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Golkhatmi, Sanaz Zarabi, 2019. "Synthesis of novel graphene/Co3O4/polypyrrole ternary nanocomposites as electrochemically enhanced supercapacitor electrodes," Energy, Elsevier, vol. 188(C).
    6. Cheng, Jie & Hu, Sheng-Chun & Sun, Guo-Tao & Kang, Kang & Zhu, Ming-Qiang & Geng, Zeng-Chao, 2021. "Comparison of activated carbons prepared by one-step and two-step chemical activation process based on cotton stalk for supercapacitors application," Energy, Elsevier, vol. 215(PB).
    7. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).

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