IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v138y2017icp883-889.html
   My bibliography  Save this article

Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage

Author

Listed:
  • Yanik, Mahir Ozan
  • Yigit, Ekrem Akif
  • Akansu, Yahya Erkan
  • Sahmetlioglu, Ertugrul

Abstract

In this study, supercapacitors based on magnetic conductive polymer-graphene nanocomposites were investigated. The graphene was synthesized from graphite oxide and graphite by Hummers and electrochemical exfoliation method, respectively. The graphene was characterized using Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction. The nanocomposite was obtained by mixing graphene with polypyrrole or magnetic polypyrrole. The conductive ink consisted of the nanocomposite, solvent and binder. The supercapacitor electrodes were manufactured with the conductive ink by using copper foil. Supercapacitor cells were composed of the separator (PTFE) and electrolyte (ionic liquid materials or acids). The cells were characterized by measurement of the specific capacitance and charge-discharge characteristics. Cyclic Voltammogram (CV) plots and scan rate studies showed a good cell structure and charge-discharge characteristics. So far, 255 F/g specific capacitance values have been achieved. Electrochemical impedance spectroscopy analysis showed a healthy cell performance and a fast capacitor response.

Suggested Citation

  • Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
  • Handle: RePEc:eee:energy:v:138:y:2017:i:c:p:883-889
    DOI: 10.1016/j.energy.2017.07.022
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217311970
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2017.07.022?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bavio, M.A. & Acosta, G.G. & Kessler, T. & Visintin, A., 2017. "Flexible symmetric and asymmetric supercapacitors based in nanocomposites of carbon cloth/polyaniline - carbon nanotubes," Energy, Elsevier, vol. 130(C), pages 22-28.
    2. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.
    3. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    4. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Y. & Qiao, X. & Zhang, C. & Zhou, Xiangyang, 2018. "Self-discharge of a hybrid supercapacitor with incorporated galvanic cell components," Energy, Elsevier, vol. 159(C), pages 1035-1045.
    2. Ensafi, Ali A. & Ahmadi, Najmeh & Rezaei, Behzad & Abdolmaleki, Amir & Mahmoudian, Manzar, 2018. "A new quaternary nanohybrid composite electrode for a high-performance supercapacitor," Energy, Elsevier, vol. 164(C), pages 707-721.
    3. Christinelli, W.A. & da Trindade, L.G. & Trench, A.B. & Quintans, C.S. & Paranhos, C.M. & Pereira, E.C., 2017. "High-performance energy storage of poly (o-methoxyaniline) film using an ionic liquid as electrolyte," Energy, Elsevier, vol. 141(C), pages 1829-1835.
    4. Scalia, Alberto & Bella, Federico & Lamberti, Andrea & Gerbaldi, Claudio & Tresso, Elena, 2019. "Innovative multipolymer electrolyte membrane designed by oxygen inhibited UV-crosslinking enables solid-state in plane integration of energy conversion and storage devices," Energy, Elsevier, vol. 166(C), pages 789-795.
    5. Khalaj, Maryam & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Golkhatmi, Sanaz Zarabi, 2019. "Synthesis of novel graphene/Co3O4/polypyrrole ternary nanocomposites as electrochemically enhanced supercapacitor electrodes," Energy, Elsevier, vol. 188(C).
    6. Cheng, Jie & Hu, Sheng-Chun & Sun, Guo-Tao & Kang, Kang & Zhu, Ming-Qiang & Geng, Zeng-Chao, 2021. "Comparison of activated carbons prepared by one-step and two-step chemical activation process based on cotton stalk for supercapacitors application," Energy, Elsevier, vol. 215(PB).
    7. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    2. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    3. Pourjavadi, Ali & Doroudian, Mohadeseh & Ahadpour, Amirkhashayar & Pourbadiei, Behzad, 2018. "Preparation of flexible and free-standing graphene-based current collector via a new and facile self-assembly approach: Leading to a high performance porous graphene/polyaniline supercapacitor," Energy, Elsevier, vol. 152(C), pages 178-189.
    4. Xu, Le & Zhao, Yan & Lian, Jiabiao & Xu, Yuanguo & Bao, Jian & Qiu, Jingxia & Xu, Li & Xu, Hui & Hua, Mingqing & Li, Huaming, 2017. "Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density," Energy, Elsevier, vol. 123(C), pages 296-304.
    5. Christinelli, W.A. & da Trindade, L.G. & Trench, A.B. & Quintans, C.S. & Paranhos, C.M. & Pereira, E.C., 2017. "High-performance energy storage of poly (o-methoxyaniline) film using an ionic liquid as electrolyte," Energy, Elsevier, vol. 141(C), pages 1829-1835.
    6. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    7. Wang, Keliang & Cao, Yuhe & Wang, Xiaomin & Kharel, Parashu Ram & Gibbons, William & Luo, Bing & Gu, Zhengrong & Fan, Qihua & Metzger, Lloyd, 2016. "Nickel catalytic graphitized porous carbon as electrode material for high performance supercapacitors," Energy, Elsevier, vol. 101(C), pages 9-15.
    8. Rivera-Lugo, Yazmín Y. & Salazar-Gastélum, Moisés I. & López-Rosas, Deisly M. & Reynoso-Soto, Edgar A. & Pérez-Sicairos, Sergio & Velraj, Samgopiraj & Flores-Hernández, José R. & Félix-Navarro, Rosa M, 2018. "Effect of template, reaction time and platinum concentration in the synthesis of PtCu/CNT catalyst for PEMFC applications," Energy, Elsevier, vol. 148(C), pages 561-570.
    9. Wang, Y. & Qiao, X. & Zhang, C. & Zhou, Xiangyang, 2018. "Self-discharge of a hybrid supercapacitor with incorporated galvanic cell components," Energy, Elsevier, vol. 159(C), pages 1035-1045.
    10. Lee, Seung-Hwan & Kim, Jong-Myon, 2018. "Punched H2Ti12O25 anode and activated carbon cathode for high energy/high power hybrid supercapacitors," Energy, Elsevier, vol. 150(C), pages 816-821.
    11. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).
    12. Rath, Tanmoy & Pramanik, Nilkamal & Kumar, Sandeep, 2017. "High electrochemical performance flexible solid-state supercapacitor based on Co-doped reduced graphene oxide and silk fibroin composites," Energy, Elsevier, vol. 141(C), pages 1982-1988.
    13. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    14. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    15. Mohd Nor, Najah Syahirah & Deraman, Mohamad & Omar, Ramli & Awitdrus, & Farma, Rakhmawati & Basri, Nur Hamizah & Mohd Dolah, Besek Nurdiana & Mamat, Nurul Fatin & Yatim, Baharudin & Md Daud, Mohd Nori, 2015. "Influence of gamma irradiation exposure on the performance of supercapacitor electrodes made from oil palm empty fruit bunches," Energy, Elsevier, vol. 79(C), pages 183-194.
    16. He, Yapeng & Wang, Xue & Zhang, Panpan & Huang, Hui & Li, Xiaobo & Shui, Yuan & Chen, Buming & Guo, Zhongcheng, 2019. "A versatile integrated rechargeable lead dioxide-polyaniline system with energy storage mechanism transformation," Energy, Elsevier, vol. 183(C), pages 358-367.
    17. Jiang, Zhuosheng & Zhai, Shengli & Huang, Mingzhi & Songsiriritthigul, Prayoon & Aung, Su Htike & Oo, Than Zaw & Luo, Min & Chen, Fuming, 2021. "3D carbon nanocones/metallic MoS2 nanosheet electrodes towards flexible supercapacitors for wearable electronics," Energy, Elsevier, vol. 227(C).
    18. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    19. Lamiel, Charmaine & Nguyen, Van Hoa & Hussain, Iftikhar & Shim, Jae-Jin, 2017. "Enhancement of electrochemical performance of nickel cobalt layered double hydroxide@nickel foam with potassium ferricyanide auxiliary electrolyte," Energy, Elsevier, vol. 140(P1), pages 901-911.
    20. Kumar, Rajesh & Joanni, Ednan & Savu, Raluca & Pereira, Matheus S. & Singh, Rajesh K. & Constantino, Carlos J.L. & Kubota, Lauro T. & Matsuda, Atsunori & Moshkalev, Stanislav A., 2019. "Fabrication and electrochemical evaluation of micro-supercapacitors prepared by direct laser writing on free-standing graphite oxide paper," Energy, Elsevier, vol. 179(C), pages 676-684.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:138:y:2017:i:c:p:883-889. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.