IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v130y2017icp22-28.html
   My bibliography  Save this article

Flexible symmetric and asymmetric supercapacitors based in nanocomposites of carbon cloth/polyaniline - carbon nanotubes

Author

Listed:
  • Bavio, M.A.
  • Acosta, G.G.
  • Kessler, T.
  • Visintin, A.

Abstract

This paper describes the construction of flexible symmetric and asymmetric supercapacitors made of carbon cloth, polyaniline and carbon nanotubes. The electrode materials (nanostructures of polyaniline-carbon nanotubes, PANI-CNT) were supported on carbon cloth acting as current collector. PANI-CNT nanostructures were synthesized through an oxidative polymerization process in the monomer (aniline) acid solution with the presence of a surfactant and the addition of multi-walled CNT. The CNT were used with and without pretreatment. The cells electrolyte was H2SO4 0.5 M and the selected potential range was 1 V. In order to test their behavior, the different cells configurations were evaluated by electrochemical techniques. Polyaniline nanostructures and polyaniline-carbon nanotubes nanocomposites were used to make the negative and/or positive electrodes of the cell. The cathode in the asymmetric supercapacitors was always carbon cloth/carbon black. The behavior of the arrayed supercapacitors was evaluated by cyclic voltammetry, between 0.0 and 1.0 V at different scan rates (10–100 mVs−1), as well as with galvanostatic charge/discharge runs at current densities between 0.3 and 6.7 mAcm−2. At a constant current density of 0.3 mA cm−2, a specific capacitance value of 1275 Fg−1 was obtained for a symmetric assembly using both electrodes prepared with polyaniline and carbon nanotubes nanocomposites. When the set was asymmetric, being the positive electrode made of polyaniline and carbon nanotubes nanocomposites, the specific capacitance value was 1566 Fg−1. For the latter array, the specific power and energy density values were 125 Wkg−1 and 217 Whkg−1 at 0.25 Ag−1, and 2502 Wkg−1 and 71 Whkg−1 at 5.0 Ag−1. These results suggest a good energy transfer capacity. Moreover, symmetric and asymmetric supercapacitors demonstrated a high stability over 1000 cycles obtaining a capacitance retention of more than 85%.

Suggested Citation

  • Bavio, M.A. & Acosta, G.G. & Kessler, T. & Visintin, A., 2017. "Flexible symmetric and asymmetric supercapacitors based in nanocomposites of carbon cloth/polyaniline - carbon nanotubes," Energy, Elsevier, vol. 130(C), pages 22-28.
  • Handle: RePEc:eee:energy:v:130:y:2017:i:c:p:22-28
    DOI: 10.1016/j.energy.2017.04.135
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217307028
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2017.04.135?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kuzmenko, Volodymyr & Naboka, Olga & Haque, Mazharul & Staaf, Henrik & Göransson, Gert & Gatenholm, Paul & Enoksson, Peter, 2015. "Sustainable carbon nanofibers/nanotubes composites from cellulose as electrodes for supercapacitors," Energy, Elsevier, vol. 90(P2), pages 1490-1496.
    2. Lee, Seul-Yi & Kim, Ji-Il & Park, Soo-Jin, 2014. "Activated carbon nanotubes/polyaniline composites as supercapacitor electrodes," Energy, Elsevier, vol. 78(C), pages 298-303.
    3. Song, Ziyou & Hou, Jun & Hofmann, Heath & Li, Jianqiu & Ouyang, Minggao, 2017. "Sliding-mode and Lyapunov function-based control for battery/supercapacitor hybrid energy storage system used in electric vehicles," Energy, Elsevier, vol. 122(C), pages 601-612.
    4. Tehrani, Z. & Thomas, D.J. & Korochkina, T. & Phillips, C.O. & Lupo, D. & Lehtimäki, S. & O'Mahony, J. & Gethin, D.T., 2017. "Large-area printed supercapacitor technology for low-cost domestic green energy storage," Energy, Elsevier, vol. 118(C), pages 1313-1321.
    5. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kumar, Rajesh & Joanni, Ednan & Savu, Raluca & Pereira, Matheus S. & Singh, Rajesh K. & Constantino, Carlos J.L. & Kubota, Lauro T. & Matsuda, Atsunori & Moshkalev, Stanislav A., 2019. "Fabrication and electrochemical evaluation of micro-supercapacitors prepared by direct laser writing on free-standing graphite oxide paper," Energy, Elsevier, vol. 179(C), pages 676-684.
    2. Ponce, M. Federico & Mamani, Arminda & Jerez, Florencia & Castilla, Josué & Ramos, Pamela B. & Acosta, Gerardo G. & Sardella, M. Fabiana & Bavio, Marcela A., 2022. "Activated carbon from olive tree pruning residue for symmetric solid-state supercapacitor," Energy, Elsevier, vol. 260(C).
    3. Jiang, Zhuosheng & Zhai, Shengli & Huang, Mingzhi & Songsiriritthigul, Prayoon & Aung, Su Htike & Oo, Than Zaw & Luo, Min & Chen, Fuming, 2021. "3D carbon nanocones/metallic MoS2 nanosheet electrodes towards flexible supercapacitors for wearable electronics," Energy, Elsevier, vol. 227(C).
    4. Pourjavadi, Ali & Doroudian, Mohadeseh & Ahadpour, Amirkhashayar & Pourbadiei, Behzad, 2018. "Preparation of flexible and free-standing graphene-based current collector via a new and facile self-assembly approach: Leading to a high performance porous graphene/polyaniline supercapacitor," Energy, Elsevier, vol. 152(C), pages 178-189.
    5. Wang, Y. & Qiao, X. & Zhang, C. & Zhou, Xiangyang, 2018. "Self-discharge of a hybrid supercapacitor with incorporated galvanic cell components," Energy, Elsevier, vol. 159(C), pages 1035-1045.
    6. Ensafi, Ali A. & Ahmadi, Najmeh & Rezaei, Behzad & Abdolmaleki, Amir & Mahmoudian, Manzar, 2018. "A new quaternary nanohybrid composite electrode for a high-performance supercapacitor," Energy, Elsevier, vol. 164(C), pages 707-721.
    7. Lamiel, Charmaine & Nguyen, Van Hoa & Hussain, Iftikhar & Shim, Jae-Jin, 2017. "Enhancement of electrochemical performance of nickel cobalt layered double hydroxide@nickel foam with potassium ferricyanide auxiliary electrolyte," Energy, Elsevier, vol. 140(P1), pages 901-911.
    8. Scalia, Alberto & Bella, Federico & Lamberti, Andrea & Gerbaldi, Claudio & Tresso, Elena, 2019. "Innovative multipolymer electrolyte membrane designed by oxygen inhibited UV-crosslinking enables solid-state in plane integration of energy conversion and storage devices," Energy, Elsevier, vol. 166(C), pages 789-795.
    9. He, Yapeng & Wang, Xue & Zhang, Panpan & Huang, Hui & Li, Xiaobo & Shui, Yuan & Chen, Buming & Guo, Zhongcheng, 2019. "A versatile integrated rechargeable lead dioxide-polyaniline system with energy storage mechanism transformation," Energy, Elsevier, vol. 183(C), pages 358-367.
    10. Lee, Seung-Hwan & Kim, Jong-Myon, 2018. "Punched H2Ti12O25 anode and activated carbon cathode for high energy/high power hybrid supercapacitors," Energy, Elsevier, vol. 150(C), pages 816-821.
    11. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).
    12. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
    13. Rath, Tanmoy & Pramanik, Nilkamal & Kumar, Sandeep, 2017. "High electrochemical performance flexible solid-state supercapacitor based on Co-doped reduced graphene oxide and silk fibroin composites," Energy, Elsevier, vol. 141(C), pages 1982-1988.
    14. Tan Thong, Pham & Sadhasivam, T. & Kim, Nam-In & Kim, Yoong Ahm & Roh, Sung-Hee & Jung, Ho-Young, 2021. "Highly conductive current collector for enhancing conductivity and power supply of flexible thin-film Zn–MnO2 battery," Energy, Elsevier, vol. 221(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Christinelli, W.A. & da Trindade, L.G. & Trench, A.B. & Quintans, C.S. & Paranhos, C.M. & Pereira, E.C., 2017. "High-performance energy storage of poly (o-methoxyaniline) film using an ionic liquid as electrolyte," Energy, Elsevier, vol. 141(C), pages 1829-1835.
    2. Celiktas, Melih Soner & Alptekin, Fikret Muge, 2019. "Conversion of model biomass to carbon-based material with high conductivity by using carbonization," Energy, Elsevier, vol. 188(C).
    3. Jhoan Alejandro Montenegro-Oviedo & Carlos Andres Ramos-Paja & Martha Lucia Orozco-Gutierrez & Edinson Franco-Mejía & Sergio Ignacio Serna-Garcés, 2023. "Adaptive Controller for Bus Voltage Regulation on a DC Microgrid Using a Sepic/Zeta Battery Charger/Discharger," Mathematics, MDPI, vol. 11(4), pages 1-30, February.
    4. Mpho J. Lencwe & Shyama P. Chowdhury & Thomas O. Olwal, 2018. "A Multi-Stage Approach to a Hybrid Lead Acid Battery and Supercapacitor System for Transport Vehicles," Energies, MDPI, vol. 11(11), pages 1-16, October.
    5. Xu, Le & Zhao, Yan & Lian, Jiabiao & Xu, Yuanguo & Bao, Jian & Qiu, Jingxia & Xu, Li & Xu, Hui & Hua, Mingqing & Li, Huaming, 2017. "Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density," Energy, Elsevier, vol. 123(C), pages 296-304.
    6. Parwal, Arvind & Fregelius, Martin & Temiz, Irinia & Göteman, Malin & Oliveira, Janaina G. de & Boström, Cecilia & Leijon, Mats, 2018. "Energy management for a grid-connected wave energy park through a hybrid energy storage system," Applied Energy, Elsevier, vol. 231(C), pages 399-411.
    7. Xu, Ying & Ren, Li & Zhang, Zhongping & Tang, Yuejin & Shi, Jing & Xu, Chen & Li, Jingdong & Pu, Dongsheng & Wang, Zhuang & Liu, Huajun & Chen, Lei, 2018. "Analysis of the loss and thermal characteristics of a SMES (Superconducting Magnetic Energy Storage) magnet with three practical operating conditions," Energy, Elsevier, vol. 143(C), pages 372-384.
    8. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    9. Pedrayes, Joaquín F. & Melero, Manuel G. & Cano, Jose M. & Norniella, Joaquín G. & Duque, Salvador B. & Rojas, Carlos H. & Orcajo, Gonzalo A., 2021. "Lambert W function based closed-form expressions of supercapacitor electrical variables in constant power applications," Energy, Elsevier, vol. 218(C).
    10. Horn, Michael & MacLeod, Jennifer & Liu, Meinan & Webb, Jeremy & Motta, Nunzio, 2019. "Supercapacitors: A new source of power for electric cars?," Economic Analysis and Policy, Elsevier, vol. 61(C), pages 93-103.
    11. Hou, Jun & Song, Ziyou & Park, Hyeongjun & Hofmann, Heath & Sun, Jing, 2018. "Implementation and evaluation of real-time model predictive control for load fluctuations mitigation in all-electric ship propulsion systems," Applied Energy, Elsevier, vol. 230(C), pages 62-77.
    12. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    13. Lo, An-Ya & Jheng, Yu & Huang, Tsao-Cheng & Tseng, Chuan-Ming, 2015. "Study on RuO2/CMK-3/CNTs composites for high power and high energy density supercapacitor," Applied Energy, Elsevier, vol. 153(C), pages 15-21.
    14. Mian, Shahid Hassan & Nazir, Muhammad Saqib & Ahmad, Iftikhar & Khan, Safdar Abbas, 2023. "Optimized nonlinear controller for fuel cell, supercapacitor, battery, hybrid photoelectrochemical and photovoltaic cells based hybrid electric vehicles," Energy, Elsevier, vol. 283(C).
    15. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    16. Jing, Wenlong & Lai, Chean Hung & Wong, Wallace S.H. & Wong, M.L. Dennis, 2018. "A comprehensive study of battery-supercapacitor hybrid energy storage system for standalone PV power system in rural electrification," Applied Energy, Elsevier, vol. 224(C), pages 340-356.
    17. Wang, Yue & Zeng, Xiaohua & Song, Dafeng & Yang, Nannan, 2019. "Optimal rule design methodology for energy management strategy of a power-split hybrid electric bus," Energy, Elsevier, vol. 185(C), pages 1086-1099.
    18. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    19. Ammar Armghan & Muhammad Kashif Azeem & Hammad Armghan & Ming Yang & Fayadh Alenezi & Mudasser Hassan, 2021. "Dynamical Operation Based Robust Nonlinear Control of DC Microgrid Considering Renewable Energy Integration," Energies, MDPI, vol. 14(13), pages 1-23, July.
    20. Sun, Huaping & Geng, Yong & Hu, Lingxiang & Shi, Longyu & Xu, Tong, 2018. "Measuring China's new energy vehicle patents: A social network analysis approach," Energy, Elsevier, vol. 153(C), pages 685-693.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:130:y:2017:i:c:p:22-28. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.