IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v222y2021ics0360544221001638.html
   My bibliography  Save this article

Effect of microstructure and contact interfaces of cobalt MOFs-derived carbon matrix composite electrode materials on lithium storage performance

Author

Listed:
  • Zheng, Guoxu
  • Wang, Dongxing
  • Tian, Shiyi
  • Ren, Mingyuan
  • Song, Mingxin

Abstract

Transition metal oxide materials have attracted the attention of researchers due to their advantages, but their development is hindered by structural instability, a small specific surface area and low electrical conductivity [1,2]. Porous carbon materials are often used in combination with transition metal oxide materials since they can produce a synergistic effect [3]. However, the interfacial properties of electrode materials have an important influence on the energy storage characteristics. In this paper, two types of composites were prepared by using three-dimensional graphene foam (3DGF) and three-dimensional porous carbon (3DPC) as the carbon matrix and Co-MOFs as the precursor. The effect of microstructure and contact interfaces on electrochemical properties was analyzed. Besides, non-equilibrium energy band models were established according to the metal semiconductor contact theory and molecular orbital theory, and the carbon-semiconductor and electrode-electrolyte contact interfaces were studied from the energy storage perspective based on the non-equilibrium carrier concentration distribution during battery cycling. Compared with the precursor conversion type (Pcver) 3DGF/Co3O4, the precursor continuation type (Pctin) 3DPC/Co/CoO had better interface compatibility since the energy band at the semiconductor side of the electrode-electrolyte interface bent more slightly. What’s more, the porous channel structure of the Pctin type 3DPC/Co/CoO electrode material endowed it with better cycle stability and more diversified lithium insertion modes. In summary, the Pctin type composite could improve the cycle stability of the electrode and the lithium intercalation model. This study provided insights into the structure design and interface analysis of electrode materials under the non-equilibrium state.

Suggested Citation

  • Zheng, Guoxu & Wang, Dongxing & Tian, Shiyi & Ren, Mingyuan & Song, Mingxin, 2021. "Effect of microstructure and contact interfaces of cobalt MOFs-derived carbon matrix composite electrode materials on lithium storage performance," Energy, Elsevier, vol. 222(C).
    • Handle: RePEc:eee:energy:v:222:y:2021:i:c:s0360544221001638
    DOI: 10.1016/j.energy.2021.119914
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221001638
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.119914?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Atyabi, Seyed Ali & Afshari, Ebrahim & Wongwises, Somchai & Yan, Wen-Mon & Hadjadj, Abdellah & Shadloo, Mostafa Safdari, 2019. "Effects of assembly pressure on PEM fuel cell performance by taking into accounts electrical and thermal contact resistances," Energy, Elsevier, vol. 179(C), pages 490-501.
    2. Havaej, P., 2019. "A numerical investigation of the performance of Polymer Electrolyte Membrane fuel cell with the converging-diverging flow field using two-phase flow modeling," Energy, Elsevier, vol. 182(C), pages 656-672.
    3. Zhang, Kaiyu & Wang, Yibai & Tang, Haibin & Li, Yong & Wang, Baojun & York, Thomas M. & Yang, Lijun, 2020. "Two-dimensional analytical investigation into energy conversion and efficiency maximization of magnetohydrodynamic swirling flow actuators," Energy, Elsevier, vol. 209(C).
    4. Ojha, Gunendra Prasad & Pant, Bishweshwar & Muthurasu, Alagan & Chae, Su-Hyeong & Park, Soo-Jin & Kim, Taewoo & Kim, Hak-Yong, 2019. "Three-dimensionally assembled manganese oxide ultrathin nanowires: Prospective electrode material for asymmetric supercapacitors," Energy, Elsevier, vol. 188(C).
    5. Mirzaeian, Mojtaba & Abbas, Qaisar & Gibson, Des & Mazur, Michal, 2019. "Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications," Energy, Elsevier, vol. 173(C), pages 809-819.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Olabi, Abdul Ghani & Abbas, Qaisar & Al Makky, Ahmed & Abdelkareem, Mohammad Ali, 2022. "Supercapacitors as next generation energy storage devices: Properties and applications," Energy, Elsevier, vol. 248(C).
    2. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    3. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    4. Wang, Qianqian & Tang, Fumin & Li, Bing & Dai, Haifeng & Zheng, Jim P. & Zhang, Cunman & Ming, Pingwen, 2022. "Investigation of the thermal responses under gas channel and land inside proton exchange membrane fuel cell with assembly pressure," Applied Energy, Elsevier, vol. 308(C).
    5. Saka, Kenan & Orhan, Mehmet Fatih, 2022. "Analysis of stack operating conditions for a polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 258(C).
    6. Dou, Shumei & Li, Ping & Tan, Dan & Li, Huiqin & Ren, Lijun & Wei, Fenyan, 2021. "Synthesis and capacitance performances of Ni–Mn-Oxides as electrode materials for high-performance supercapacitors," Energy, Elsevier, vol. 227(C).
    7. Abdollahipour, Armin & Sayyaadi, Hoseyn, 2022. "A novel electrochemical refrigeration system based on the combined proton exchange membrane fuel cell-electrolyzer," Applied Energy, Elsevier, vol. 316(C).
    8. Xiong, Kangning & Wu, Wei & Wang, Shuangfeng & Zhang, Lin, 2021. "Modeling, design, materials and fabrication of bipolar plates for proton exchange membrane fuel cell: A review," Applied Energy, Elsevier, vol. 301(C).
    9. Ye, Lingfeng & Qiu, Diankai & Peng, Linfa & Lai, Xinmin, 2022. "Microstructures and electrical conductivity properties of compressed gas diffusion layers using X-ray tomography," Applied Energy, Elsevier, vol. 326(C).
    10. Isaac C. Okereke & Mohammed S. Ismail & Derek B. Ingham & Kevin Hughes & Lin Ma & Mohamed Pourkashanian, 2023. "Single- and Double-Sided Coated Gas Diffusion Layers Used in Polymer Electrolyte Fuel Cells: A Numerical Study," Energies, MDPI, vol. 16(11), pages 1-16, May.
    11. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).
    12. Atyabi, Seyed Ali & Afshari, Ebrahim & Zohravi, Elnaz & Udemu, Chinonyelum M., 2021. "Three-dimensional simulation of different flow fields of proton exchange membrane fuel cell using a multi-phase coupled model with cooling channel," Energy, Elsevier, vol. 234(C).
    13. Abdel-Basset, Mohamed & Mohamed, Reda & El-Fergany, Attia & Chakrabortty, Ripon K. & Ryan, Michael J., 2021. "Adaptive and efficient optimization model for optimal parameters of proton exchange membrane fuel cells: A comprehensive analysis," Energy, Elsevier, vol. 233(C).
    14. Yang, Rui & Wang, Junxiang & Wu, Zhanghua & Huang, Bangdou & Luo, Ercang, 2023. "Performance analysis of thermoacoustic plasma MHD generation," Energy, Elsevier, vol. 263(PA).
    15. Guo, Xinru & Zhang, Houcheng, 2020. "Performance analyses of a combined system consisting of high-temperature polymer electrolyte membrane fuel cells and thermally regenerative electrochemical cycles," Energy, Elsevier, vol. 193(C).
    16. Mojtaba Mirzaeian & Nazym Akhanova & Maratbek Gabdullin & Zhanar Kalkozova & Aida Tulegenova & Shyryn Nurbolat & Khabibulla Abdullin, 2020. "Improvement of the Pseudocapacitive Performance of Cobalt Oxide-Based Electrodes for Electrochemical Capacitors," Energies, MDPI, vol. 13(19), pages 1-16, October.
    17. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    18. Olabi, Abdul Ghani & Abbas, Qaisar & Shinde, Pragati A. & Abdelkareem, Mohammad Ali, 2023. "Rechargeable batteries: Technological advancement, challenges, current and emerging applications," Energy, Elsevier, vol. 266(C).
    19. Pan, Mingzhang & Li, Chao & Liao, Jinyang & Lei, Han & Pan, Chengjie & Meng, Xianpan & Huang, Haozhong, 2020. "Design and modeling of PEM fuel cell based on different flow fields," Energy, Elsevier, vol. 207(C).
    20. Han, Chaoling & Chen, Zhenqian, 2021. "Study on the synergism of thermal transport and electrochemical of PEMFC based on N, P co-doped graphene substrate electrode," Energy, Elsevier, vol. 214(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:222:y:2021:i:c:s0360544221001638. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.