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Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides

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  • Güleç, Fatih
  • Meredith, Will
  • Sun, Cheng-Gong
  • Snape, Colin E.

Abstract

Chemical looping combustion (CLC) of n-hexadecane and n-heptane with copper and manganese oxides (CuO and Mn2O3) has been investigated in a fixed bed reactor to reveal the extent to which low temperature CLC can potentially be applicable to hydrocarbons. The effects of fuel to oxygen carrier ratio, fuel feed flow rate, and fuel residence time on the extent of combustion are reported. Methane did not combust, while near complete conversion was achieved for both n-hexadecane and n-heptane with excess oxygen carrier for CuO. For Mn2O3, complete reduction to Mn3O4 occurred, but the extent of combustion was controlled by the much slower reduction to MnO. Although the extent of cracking is relatively small in the absence of cracking catalysts, for the mechanism to be selective for higher hydrocarbons suggests that the reaction with oxygen involves radicals or carbocations arising from bond scission. Sintering of pure CuO occurred after repeated cycles, but this can easily be avoided using a support, such as alumina. The fact that higher hydrocarbons can be combusted selectively at 500 °C and below, offers the possibility of using CLC to remove these hydrocarbons and potentially other organics from hot gas streams.

Suggested Citation

  • Güleç, Fatih & Meredith, Will & Sun, Cheng-Gong & Snape, Colin E., 2019. "Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides," Energy, Elsevier, vol. 173(C), pages 658-666.
    • Handle: RePEc:eee:energy:v:173:y:2019:i:c:p:658-666
    DOI: 10.1016/j.energy.2019.02.099
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    References listed on IDEAS

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    1. Han, Lu & Bollas, George M., 2016. "Chemical-looping combustion in a reverse-flow fixed bed reactor," Energy, Elsevier, vol. 102(C), pages 669-681.
    2. Mishra, Navneet & Bhui, Barnali & Vairakannu, Prabu, 2019. "Comparative evaluation of performance of high and low ash coal fuelled chemical looping combustion integrated combined cycle power generating systems," Energy, Elsevier, vol. 169(C), pages 305-318.
    3. Zhu, Lin & He, Yangdong & Li, Luling & Wu, Pengbin, 2018. "Tech-economic assessment of second-generation CCS: Chemical looping combustion," Energy, Elsevier, vol. 144(C), pages 915-927.
    4. Khakpoor, Nima & Mostafavi, Ehsan & Mahinpey, Nader & De la Hoz Siegler, Hector, 2019. "Oxygen transport capacity and kinetic study of ilmenite ores for methane chemical-looping combustion," Energy, Elsevier, vol. 169(C), pages 329-337.
    5. Frick, Volkmar & Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2015. "Screening of supported and unsupported Mn–Si oxygen carriers for CLOU (chemical-looping with oxygen uncoupling)," Energy, Elsevier, vol. 93(P1), pages 544-554.
    6. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
    7. Moldenhauer, Patrick & Rydén, Magnus & Mattisson, Tobias & Younes, Mourad & Lyngfelt, Anders, 2014. "The use of ilmenite as oxygen carrier with kerosene in a 300W CLC laboratory reactor with continuous circulation," Applied Energy, Elsevier, vol. 113(C), pages 1846-1854.
    8. Han, Lu & Bollas, George M., 2016. "Dynamic optimization of fixed bed chemical-looping combustion processes," Energy, Elsevier, vol. 112(C), pages 1107-1119.
    9. Medrano, J.A. & Hamers, H.P. & Williams, G. & van Sint Annaland, M. & Gallucci, F., 2015. "NiO/CaAl2O4 as active oxygen carrier for low temperature chemical looping applications," Applied Energy, Elsevier, vol. 158(C), pages 86-96.
    10. Zhang, Xiaosong & Han, Wei & Hong, Hui & Jin, Hongguang, 2009. "A chemical intercooling gas turbine cycle with chemical-looping combustion," Energy, Elsevier, vol. 34(12), pages 2131-2136.
    11. Jiménez Álvaro, Ángel & Urdiales Montesino, Álvaro & Sánchez Orgaz, Susana & González Fernández, Celina, 2017. "Thermodynamic analysis of a dual power-hydrogen production system based on chemical-looping combustion," Energy, Elsevier, vol. 137(C), pages 1075-1085.
    12. Spinelli, Maurizio & Peltola, Petteri & Bischi, Aldo & Ritvanen, Jouni & Hyppänen, Timo & Romano, Matteo C., 2016. "Process integration of chemical looping combustion with oxygen uncoupling in a coal-fired power plant," Energy, Elsevier, vol. 103(C), pages 646-659.
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